CO<sub>2</sub>环加成用离子液体/金属有机框架催化材料研究进展

刘爽; 兰健文; 李正鹏; 杨旭; 程杨

doi:10.12434/j.issn.2097-2547.20250284

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CO₂环加成用离子液体/金属有机框架催化材料研究进展

更新时间：2025-12-15

- CO₂环加成用离子液体/金属有机框架催化材料研究进展
- Research progress on ionic liquid/metal-organic framework catalytic materials for CO₂ cycloaddition
- 低碳化学与化工 2025: 1-8.
- 作者机构：
  
  辽宁工业大学化学与环境工程学院，辽宁锦州 121000
- 作者简介：
  
  刘爽（2000—），硕士研究生，研究方向为能源化学与纳米催化，E-mail：1928369924@qq.com。
  兰健文（1992—），博士，讲师，硕士研究生导师，研究方向为功能化多孔金属-有机骨架材料的设计与合成及CO2气体吸附转化，E-mail：lanjwen@126.com。
- 基金信息：
  
  辽宁省教育厅基本科研项目(JYTMS20230855;JYTMS20230856)
- DOI：10.12434/j.issn.2097-2547.20250284
  中图分类号： TE65;X-1
- 收稿：2025-06-25，
  
  修回：2025-08-15，
  
  网络出版：2025-12-15，
- 稿件说明：
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刘爽,兰健文,李正鹏等.CO₂环加成用离子液体/金属有机框架催化材料研究进展[J].低碳化学与化工,

LIU Shuang,LAN Jianwen,LI Zhengpeng YANG Xu,et al.Research progress on ionic liquid/metal-organic framework catalytic materials for CO₂ cycloaddition[J].Low-Carbon Chemistry and Chemical Engineering,
刘爽,兰健文,李正鹏等.CO₂环加成用离子液体/金属有机框架催化材料研究进展[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20250284.

LIU Shuang,LAN Jianwen,LI Zhengpeng YANG Xu,et al.Research progress on ionic liquid/metal-organic framework catalytic materials for CO₂ cycloaddition[J].Low-Carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20250284.

摘要

为了应对全球气候变化挑战及实现“碳中和”目标，碳捕集、利用与封存（CCUS）技术已成为缓解温室气体排放的关键途径。其中，将CO

捕集并转化为环状碳酸酯，具有显著的经济与环境优势，被认为是极具工业应用前景的碳捕集与利用技术之一。综述了CO

与环氧化物的环加成反应机理，点明了传统催化体系回收性差、缺少亲核基团等方面的局限性，重点阐述了离子液体/金属有机框架（IL/MOF）复合材料的合成方法：原位封存法、前修饰法和后修饰法，分析了IL/MOF复合材料催化性能，并指出了目前其存在的稳定性差、活性组分易流失等不足。未来研究应聚应焦于构建微孔-介孔MOF载体，充分利用多级孔的结构优势，使IL/MOF复合材料催化性能进一步提升，并开发出适用于低浓度CO

混合气体化学转化的绿色、低能耗且高效的IL/MOF复合材料，满足实际工业化应用的需求。

Abstract

In order to address the global climate change challenge and achieve the “carbon neutrality” goal

carbon capture

utilization and storage (CCUS) technology has become a key approach to mitigate greenhouse gas emissions. Among them

capturing and converting CO

into cyclic carbonates has significant economic and environmental advantages and is considered one of the most promising carbon capt

ure and utilization technologies for industrial application. The mechanism of CO

cycloaddition reaction with epoxides was reviewed

and the limitations of traditional catalytic systems

such as poor recyclability and lack of nucleophilic groups were pointed out. The synthesis methods of ionic liquid/metal-organic framework (IL/MOF) composite materials were emphasized

including in-situ encapsulation

pre-modification

and post-modification. The catalytic performances of IL/MOF composite materials were analyzed and the current challenges of poor stability

easy loss of active components and so on were pointed out. Future research should focus on constructing micro-mesoporous MOF carriers to fully utilize the structural advantages of multi-level pores

further improving the catalytic performances of IL/MOF composite materials

and developing green

low-energy and efficient IL/MOF composite materials suitable for the chemical conversion of low-concentration CO

mixed gases to meet the needs of practical industrial applications.

关键词

Keywords

references

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Research progress on ionic liquid/metal-organic framework catalytic materials for CO2 cycloaddition

DOI：10.12434/j.issn.2097-2547.20250284

摘要

Abstract

关键词

Keywords

references

CO₂环加成用离子液体/金属有机框架催化材料研究进展

Research progress on ionic liquid/metal-organic framework catalytic materials for CO₂ cycloaddition