Ni/CeO<sub>2</sub>基催化剂构筑及其CO<sub>2</sub>甲烷化催化性能研究进展

胡译之; 彭揚; 张义焕; 张荣斌; 冯刚; 叶闰平

doi:10.12434/j.issn.2097-2547.20240175

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Ni/CeO₂基催化剂构筑及其CO₂甲烷化催化性能研究进展

二氧化碳化工与催化转化

- Ni/CeO₂基催化剂构筑及其CO₂甲烷化催化性能研究进展
- Research progress on construction of Ni/CeO₂-based catalysts and their catalytic performances of CO₂ methanation
- 低碳化学与化工 2024, 49(8): 74-88.
- 作者机构：
  
  南昌大学化学化工学院，江西南昌 330031
- 作者简介：
  
  胡译之（2000—），硕士研究生，研究方向为工业催化，E-mail：15907032795@163.com。
  张荣斌（1969—），博士，教授，研究方向为工业催化，E-mail：rbzhang@ncu.edu.cn；
  冯刚（1982—），博士，教授，研究方向为工业催化，E-mail：fenggang@ncu.edu.cn；
  叶闰平（1990—），博士，教授，研究方向为多相催化，E-mail：rye@ncu.edu.cn。
- 基金信息：
  
  江西省杰出青年自然科学基金(20232ACB213001);重庆市自然科学基金(CSTB2022NSCQ-MSX0231);江西省大学生创新创业训练计划(S202210403020);国家自然科学基金(22005296);江西省自然科学基金(20232ACB203004;20224BAB213015);江西省双高计划项目和江西省“双千计划”(jxsq2023101072);江西省“双高计划”
- DOI：10.12434/j.issn.2097-2547.20240175
  中图分类号： TQ426.94
- 纸质出版日期：2024-08-25，
  
  收稿日期：2024-04-24，
  
  修回日期：2024-05-21，
- 稿件说明：
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胡译之,彭揚,张义焕等.Ni/CeO₂基催化剂构筑及其CO₂甲烷化催化性能研究进展[J].低碳化学与化工,2024,49(08):74-88.

HU Yizhi,PENG Yang,ZHANG Yihuan,et al.Research progress on construction of Ni/CeO₂-based catalysts and their catalytic performances of CO₂ methanation[J].Low-carbon Chemistry and Chemical Engineering,2024,49(08):74-88.
胡译之,彭揚,张义焕等.Ni/CeO₂基催化剂构筑及其CO₂甲烷化催化性能研究进展[J].低碳化学与化工,2024,49(08):74-88. DOI： 10.12434/j.issn.2097-2547.20240175.

HU Yizhi,PENG Yang,ZHANG Yihuan,et al.Research progress on construction of Ni/CeO₂-based catalysts and their catalytic performances of CO₂ methanation[J].Low-carbon Chemistry and Chemical Engineering,2024,49(08):74-88. DOI： 10.12434/j.issn.2097-2547.20240175.

摘要

加氢制甲烷（即“CO

甲烷化”）是实现碳中和目标的重要途径。CeO

由于具有丰富的表面氧空位和优异的储氧性能被认为是重要的催化剂载体之一，过渡金属Ni也因为具有优异的催化性能和低廉的价格被广泛应用于催化剂的研究，CeO

和金属Ni结合形成的Ni/CeO

基催化剂在CO

甲烷化反应中展现了良好的应用前景。阐述了Ni/CeO

基催化剂催化CO

甲烷化的机理，介绍了Ni/CeO

基催化剂制备方法，重点总结了活性中心特征、载体性质、助剂类型和金属-载体相互作用等影响Ni/CeO

基催化CO

甲烷化催化性能的因素，并总结了改性Ni/CeO

基催化剂的催化性能。分析发现，通过对Ni/CeO

基催化剂进行改性，可以调控Ni/CeO

基催化剂的CO

甲烷化催化性能与产物选择性，可为提升其CO

甲烷化催化性能提供新的思路。

Abstract

hydrogenation to methane (also known as “CO

methanation”) is an important way to achieve the goal of carbon neutralization. CeO

is considered as one of the most important catalyst supports because of its abundant surface oxygen vacancies and excellent oxygen storage capacity. Transition metal Ni is also widely studied because of its excellent catalytic performance and low price. The Ni/CeO

-based catalysts formed by the combination of CeO

and metal Ni show good application prospects in CO

methanation. The reaction mechanisms of Ni/CeO

-based catalysts for CO

methanation were summarized and the preparation methods of Ni/CeO

-based catalysts were introduced

and the key parameters affecting catalytic performance of CO

methanation such as the characteristics of active centers

properties of supports

types of additives and metal-support interactions were summarized

and the catalytic performances of Ni/CeO

-based catalysts were also summarized. It is found that by modifying Ni/CeO

-based catalysts

the catalytic performances and product selectivities of Ni/CeO

-based catalysts for CO

methanation can be regulated

which can provide new ideas for improving their catalytic performances of CO

methanation.

关键词

Ni/CeO2基催化剂CO2甲烷化金属-载体相互作用制备方法

Keywords

Ni/CeO2-based catalystsCO2 methanationmetal-support interactionspreparation method

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Ni/CeO2基催化剂构筑及其CO2甲烷化催化性能研究进展

Research progress on construction of Ni/CeO2-based catalysts and their catalytic performances of CO2 methanation

DOI：10.12434/j.issn.2097-2547.20240175

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Ni/CeO₂基催化剂构筑及其CO₂甲烷化催化性能研究进展

Research progress on construction of Ni/CeO₂-based catalysts and their catalytic performances of CO₂ methanation