CO<sub>2</sub>加氢制甲醇催化剂理化性质对催化性能影响研究进展

李鹏阳; 王改荣; 张彩东; 田志强; 牛佳星; 李兰杰

doi:10.12434/j.issn.2097-2547.20240073

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CO₂加氢制甲醇催化剂理化性质对催化性能影响研究进展

C1化学与催化转化

- CO₂加氢制甲醇催化剂理化性质对催化性能影响研究进展
- Research progress on impact of physicochemical properties of catalysts on catalytic performances for CO₂ hydrogenation to methanol
- 低碳化学与化工 2024, 49(11): 12-20.
- 作者机构：
  
  河北河钢材料技术研究院有限公司，河北石家庄 050023
- 作者简介：
  
  李鹏阳（1994—），硕士，助理工程师，研究方向为CO2资源化利用技术，E-mail：1146001241@qq.com。
  李兰杰（1983—），博士，正高级工程师，研究方向为钒钛钢铁低碳冶金与新材料，E-mail：lilanjie@hbisco.com。
- 基金信息：
  
  国家重点研发计划(2023YFB4204005);京津冀基础研究合作专项(E2021318022);河北省自然科学基金(E2023318001);河北省自然科学基金燕赵青年科学家项目(E2023318014);河北省自然科学基金杰出青年科学基金(B2022318001)
- DOI：10.12434/j.issn.2097-2547.20240073
  中图分类号： TQ426;O643.36
- 纸质出版日期：2024-11-25，
  
  收稿日期：2024-02-29，
  
  修回日期：2024-04-19，
- 稿件说明：
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李鹏阳,王改荣,张彩东等.CO₂加氢制甲醇催化剂理化性质对催化性能影响研究进展[J].低碳化学与化工,2024,49(11):12-20.

LI Pengyang,WANG Gairong,ZHANG Caidong,et al.Research progress on impact of physicochemical properties of catalysts on catalytic performances for CO₂ hydrogenation to methanol[J].Low-carbon Chemistry and Chemical Engineering,2024,49(11):12-20.
李鹏阳,王改荣,张彩东等.CO₂加氢制甲醇催化剂理化性质对催化性能影响研究进展[J].低碳化学与化工,2024,49(11):12-20. DOI： 10.12434/j.issn.2097-2547.20240073.

LI Pengyang,WANG Gairong,ZHANG Caidong,et al.Research progress on impact of physicochemical properties of catalysts on catalytic performances for CO₂ hydrogenation to methanol[J].Low-carbon Chemistry and Chemical Engineering,2024,49(11):12-20. DOI： 10.12434/j.issn.2097-2547.20240073.

摘要

化石能源大规模利用造成CO

大量排放，并引发了系列气候问题。将CO

转化为甲醇可实现CO

的减排和资源化利用，是当前的研究热点。CO

加氢制甲醇催化剂已得到了广泛研究，但存在催化活性低、甲醇选择性差以及反应过程中产生的水导致催化剂失活和反应速率降低等问题。全面了解催化剂理化性质与催化性能之间的关系，对于开发高效稳定的催化体系至关重要。首先介绍了CO

加氢制甲醇的3种反应机理；然后综述了关于CO

加氢制甲醇催化剂理化性质对催化性能影响的研究进展，包括金属比表面积和孔隙率、金属颗粒尺寸和分散度、氧空位、酸碱性、金属-载体相互作用以及还原性等；最后对CO

加氢制甲醇催化剂的未来研究进行了展望。

Abstract

The extensive use of fossil fuels have led to massive CO

emissions

causing a series of climate issues. Converting CO

into methanol can achieve CO

emission r

eduction and resource utilization

making it a current research hotspot. CO

hydrogenation to methanol catalysts have been extensively studied

but issues such as low catalytic activity

poor methanol selectivity and catalyst deactivation caused by water produced during the reaction

which slows the reaction

still exist. A comprehensive understanding of the relationship between the physicochemical properties of catalysts and their catalytic performance is crucial for the development of efficient and stable catalytic systems. Three reaction mechanisms for CO

hydrogenation to methanol were first introduced. Then the research progress on the impact of the physicochemical properties of CO

hydrogenation to methanol catalysts on their catalytic performances was reviewed

including metal specific surface area and porosity

metal particle size and dispersion

oxygen vacancy

acid-basicity

metal-support interaction and reducibility. Finally

the future researches for CO

hydrogenation to methanol catalysts were prospected.

关键词

CO2加氢甲醇催化剂理化性质催化性能

Keywords

CO2 hydrogenationmethanol catalystsphysicochemical propertiescatalytic performances

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Research progress on impact of physicochemical properties of catalysts on catalytic performances for CO2 hydrogenation to methanol

DOI：10.12434/j.issn.2097-2547.20240073

摘要

Abstract

关键词

Keywords

references

CO₂加氢制甲醇催化剂理化性质对催化性能影响研究进展

Research progress on impact of physicochemical properties of catalysts on catalytic performances for CO₂ hydrogenation to methanol