纳米金刚石改性钴基催化剂的费托合成性能研究‬‬‬‬‬‬‬‬‬‬‬‬

伊程程; 韦春洪; 徐冰; 刘岳峰

doi:10.12434/j.issn.2097-2547.20240044

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纳米金刚石改性钴基催化剂的费托合成性能研究‬‬‬‬‬‬‬‬‬‬‬‬

合成气化工与催化转化

- 纳米金刚石改性钴基催化剂的费托合成性能研究‬‬‬‬‬‬‬‬‬‬‬‬
- Study on catalytic performance of cobalt-based catalysts modified with nanodiamonds in Fischer-Tropsch synthesis
- 低碳化学与化工 2024, 49(8): 38-45.
- 作者机构：
  
  1.沈阳化工大学化学工程学院，辽宁沈阳 110142
  2.中国科学院大连化学物理研究所，辽宁大连 116023
- 作者简介：
  
  伊程程（1993—），硕士研究生，研究方向为费托合成，E-mail：yichengcheng@dicp.ac.cn。
  刘岳峰（1985—），博士，研究员，研究方向为多相催化，E-mail：yuefeng.liu@dicp.ac.cn。
- 基金信息：
  
  国家自然科学基金(91645117)
- DOI：10.12434/j.issn.2097-2547.20240044
  中图分类号： TQ426;O643.3
- 纸质出版日期：2024-08-25，
  
  收稿日期：2024-02-02，
  
  修回日期：2024-03-05，
- 稿件说明：
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伊程程,韦春洪,徐冰等.纳米金刚石改性钴基催化剂的费托合成性能研究‬‬‬‬‬‬‬‬‬‬‬‬[J].低碳化学与化工,2024,49(08):38-45.

YI Chengcheng,WEI Chunhong,XU Bing,et al.Study on catalytic performance of cobalt-based catalysts modified with nanodiamonds in Fischer-Tropsch synthesis[J].Low-carbon Chemistry and Chemical Engineering,2024,49(08):38-45.
伊程程,韦春洪,徐冰等.纳米金刚石改性钴基催化剂的费托合成性能研究‬‬‬‬‬‬‬‬‬‬‬‬[J].低碳化学与化工,2024,49(08):38-45. DOI： 10.12434/j.issn.2097-2547.20240044.

YI Chengcheng,WEI Chunhong,XU Bing,et al.Study on catalytic performance of cobalt-based catalysts modified with nanodiamonds in Fischer-Tropsch synthesis[J].Low-carbon Chemistry and Chemical Engineering,2024,49(08):38-45. DOI： 10.12434/j.issn.2097-2547.20240044.

摘要

Co基催化剂在费托合成反应中具有优异的反应活性以及碳链增长能力，其催化性能与金属Co纳米颗粒的还原度和粒径紧密相关，通过添加助剂调控金属Co的还原度和分散度是提高其催化费托合成反应性能的重要手段。以具有化学惰性以及良好导热性的SiC为载体，加入少量具有丰富表面官能团的纳米金刚石（NDs）作为结构调节剂，有效提高了催化剂中Co物种的分散度和还原度，提升了其催化费托合成反应性能。N

物理吸/脱附结果表明，NDs的加入对催化剂的比表面积、孔径等参数影响较小。CO化学吸附结果表明，适量NDs的加入促进了催化剂中活性金属Co的分散，增加了金属Co的表面积，为费托合成反应提供了更多的活性位点。透射电镜（TEM）结果表明，在Co/SiC（

(Co) = 10%）中加入NDs后，催化剂中金属Co的粒径减小，且NDs在催化剂表面均匀分散。H

程序升温还原（H

-TPR）和CO预吸附的H

程序升温表面反应（CO-H

-TPSR）结果表明，NDs的加入降低了Co

还原为金属Co的还原温度，促进了Co

的还原以及CO的活化。调节剂修饰的Co/1.0NDs-SiC（

(Co) = 10%，

(NDs):

(SiC) = 1.0%）与Co/SiC催化剂相比，CO转化率从15.6%提升至29.0%，产物中C

烃类选择性仍可保持在75%以上，且稳定运行70 h未见明显失活。以上结果可为研发纳米碳材料改性的高效费托合成反应的催化剂提供

新的研究思路。

Abstract

Cobalt-based catalysts exhibit excellent reactivity and carbon chain growth capability in the Fischer-Tropsch synthesis reaction

and their catalytic performance is closely related to the reduction degree and size of metal Co particles. Regulating the reduction degree and dispersion degree of metal Co by adding promoters is an important way to enhance their catalytic performance in Fischer-Tropsch synthesis reaction. By using SiC as a support with chemical inertness and good thermal conductivity

and adding a small amount of nanodiamonds (NDs) with rich surface functional groups as structural regulators

the dispersion degree and reduction degree of Co species in the catalyst were effectively improved

and its catalytic performance in Fischer-Tropsch synthesis reaction was enhanced. The results of N

physical adsorption/desorption show that the addition of NDs has little effect on the parameters such as specific surface areas and pore sizes of the catalysts. The results of CO chemisorption show that the addition of an appropriate amount of NDs promotes the dispersion of active metal Co in the catalysts

increases the surface area of metal Co and provides more active sites for the Fischer-Tropsch synthesis reaction. The results of transmission electron microscopy (TEM) show that after the addition of NDs to Co/SiC (

(NDs):

(SiC) = 1.0%)

the particle sizes of metal Co in the catalysts are reduced

and NDs are uniformly dispersed on the catalyst surface. The results of H

-temperature programmed reduction (H

-TPR) and CO-H

-temperature programmed surface reaction (CO-H

-TPSR) show that the addition of NDs reduces the reduction temperature of Co

to metal Co and promotes the reduction of Co

and the activation of CO. Compared with the Co/SiC catalyst

the NDs-modified Co/1.0NDs-SiC (

(Co) = 10%

(NDs):

(SiC) = 1.0%) catalyst exhibits an increase of CO conversion rate from 15.6% to 29.0%

and the selectivity of C

hydrocarbon products still maintains at above 75%

and shows stable operation and no significant deactivation for 70 h. The above results can provide a new research idea for the development of efficient catalysts modified with nanocarbon materials in Fischer-Tropsch synthesis reaction.

关键词

Co基催化剂费托合成纳米金刚石碳调节剂

Keywords

Co-based catalystFischer-Tropsch synthesisnanodiamondscarbon regulator

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