二氧化碳催化加氢制高级醇催化剂研究进展

吴彬; 姚如伟; 牛琴琴; 李聪明

doi:10.12434/j.issn.2097-2547.20240003

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二氧化碳催化加氢制高级醇催化剂研究进展

二氧化碳化工与催化转化

- 二氧化碳催化加氢制高级醇催化剂研究进展
- Research progress on catalysts for catalytic hydrogenation of carbon dioxide to higher alcohols
- 低碳化学与化工 2024, 49(8): 89-99.
- 作者机构：
  
  太原理工大学省部共建煤基能源清洁高效利用国家重点实验室，山西太原 030024
- 作者简介：
  
  吴彬（1998—），硕士研究生，研究方向为多相催化与CO2转化利用，E-mail：Wb1932453@163.com。
  姚如伟（1993—），博士，助理研究员，研究方向为CO2催化转化，E-mail：yaoruwei@tyut.edu.cn；
  李聪明（1974—），博士，教授，研究方向为碳一化学与化工，E-mail：licongming0523@163.com。
- 基金信息：
  
  国家自然科学基金(22202150);山西省重点研发计划(202202090301013);山西省自然科学基金(20210302123143)
- DOI：10.12434/j.issn.2097-2547.20240003
  中图分类号： TQ072
- 纸质出版日期：2024-08-25，
  
  收稿日期：2024-01-02，
  
  修回日期：2024-02-20，
- 稿件说明：
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吴彬,姚如伟,牛琴琴等.二氧化碳催化加氢制高级醇催化剂研究进展[J].低碳化学与化工,2024,49(08):89-99.

WU Bin,YAO Ruwei,NIU Qinqin,et al.Research progress on catalysts for catalytic hydrogenation of carbon dioxide to higher alcohols[J].Low-carbon Chemistry and Chemical Engineering,2024,49(08):89-99.
吴彬,姚如伟,牛琴琴等.二氧化碳催化加氢制高级醇催化剂研究进展[J].低碳化学与化工,2024,49(08):89-99. DOI： 10.12434/j.issn.2097-2547.20240003.

WU Bin,YAO Ruwei,NIU Qinqin,et al.Research progress on catalysts for catalytic hydrogenation of carbon dioxide to higher alcohols[J].Low-carbon Chemistry and Chemical Engineering,2024,49(08):89-99. DOI： 10.12434/j.issn.2097-2547.20240003.

摘要

二氧化碳（CO

）催化加氢制高级醇是实现CO

高价值利用及缓解温室效应的重要途径之一。综述了近年来CO

催化加氢制高级醇的研究进展。首先从热力学角度分析了CO

催化加氢制高级醇的有利反应条件及催化剂要求。然后重点介绍了适用于该领域的不同类型的催化剂（贵金属基、铜基、钴基和钼基催化剂）的研究情况。最后基于关键中间体及主反应路径，总结了CO

催化加氢制C

醇合成机理。通过总结与分析，指出了目前CO

催化加氢制高级醇研究面临的主要挑战，并对该领域未来的研究方向进行了展望。

Abstract

Catalytic hydrogenation of carbon dioxide (CO

) to higher alcohols is one of the important ways to realize the high value utilization of CO

and mitigate the greenhouse effect. The research progress on catalytic hydrogenation of CO

to higher alcohols in recent years was reviewed. Firstly

the favorable reaction conditions and catalyst requirements for catalytic hydrogenation of CO

to higher alcohols were analyzed from the thermodynamic point of view. Then the researches of different types of catalysts (precious metal based

copper based

cobalt and molybdenum based catalysts) applicable to the field were introduced. Finally

based on the key intermediates and main reaction pathways

the synthesis mechanisms of catalytic hydrogenation of CO

to higher alcohols were summarized. Through summary and analysis

the main challenges in the research of catalytic hydrogenation of CO

to higher alcohols were pointed out

and the future research direction in the field was prospected.

关键词

二氧化碳催化加氢高级醇催化剂合成机理

Keywords

carbon dioxidecatalytic hydrogenationhigher alcoholscatalystssynthesis mechanisms

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