碳纳米管功能化改性的研究进展

闫江毅; 丁一汇; 李风亭

doi:10.12434/j.issn.2097-2547.20230400

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碳纳米管功能化改性的研究进展

C1化学与催化转化

- 碳纳米管功能化改性的研究进展
- Research progress on functional modification of carbon nanotubes
- 低碳化学与化工 2024, 49(10): 1-10.
- 作者机构：
  
  同济大学环境科学与工程学院，污染控制与资源再利用国家重点实验室，中国气象局上海城市气候变化与应对重点实验室，上海 200092
- 作者简介：
  
  闫江毅（1996—），博士研究生，研究方向为新型功能化纳米材料，E-mail：jyyan@tongji.edu.cn。
  李风亭（1963—），博士，教授，研究方向为新型功能化纳米气体分离材料、存储材料及储能材料，E-mail：fengting@tongji.edu.cn。
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20230400
  中图分类号： TB383
- 纸质出版日期：2024-10-25，
  
  收稿日期：2023-12-07，
  
  修回日期：2024-01-11，
- 稿件说明：
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闫江毅,丁一汇,李风亭.碳纳米管功能化改性的研究进展[J].低碳化学与化工,2024,49(10):1-10.

YAN Jiangyi,DING Yihui,LI Fengting.Research progress on functional modification of carbon nanotubes[J].Low-carbon Chemistry and Chemical Engineering,2024,49(10):1-10.
闫江毅,丁一汇,李风亭.碳纳米管功能化改性的研究进展[J].低碳化学与化工,2024,49(10):1-10. DOI： 10.12434/j.issn.2097-2547.20230400.

YAN Jiangyi,DING Yihui,LI Fengting.Research progress on functional modification of carbon nanotubes[J].Low-carbon Chemistry and Chemical Engineering,2024,49(10):1-10. DOI： 10.12434/j.issn.2097-2547.20230400.

摘要

碳纳米管（CNTs）因具有理想的原子空间几何结构、高电子迁移率和卓越的纳米级尺寸效应自被发现以来即成为了纳米科技领域的研究热点。研究人员对碳纳米管的理论模型进行了深入的研究，通过实验探索了其结构、力学性质以及电子结构等。由于碳纳米管在生长过程中受到动力学和热力学等不确定性因素的影响，通常会被引入不同类型的缺陷，因此对碳纳米管进行功能化改性成为克服其局限性的主要途径。通过归纳国内外报道的碳纳米管改性的研究成果，从碳纳米管的结构特性、功能化方法、接枝基团以及受控体系下不同功能选择剂对碳纳米管活性的促进作用等方面进行了阐述和分析。分析认为，依托碳纳米管特定的骨架结构，功能性基团或材料的引入能够显著地影响碳纳米管的物理化学性质和表面活性，并推动其在更广泛领域中的应用。今后，实现超纯碳纳米管的高产率制备和高功能化修饰是需要重点关注的方向。

Abstract

Carbon nanotubes (CNTs) have been a research interest in the field of nanotechnology since their discovery due to their ideal atomic space geometry

high electron mobility and excellent nanoscale size effect. Researchers have conducted in-depth researches on the theoretical model of carbon nanotubes and explored their structures

mechanical properties and electronic structures through experiments. Different kinds of defects are typically introduced during the growing process of carbon nanotubes since they are subject to uncertain factors including kinetics and thermodynamics

and thus functional modification of carbon nanotubes has become a major way to overcome their limitations. By summarizing the studies on modification of carbon nanotubes reported at home and abroad

the structural properties of carbon nanotubes

functionalization methods

grafting groups

and the promotion on the activity of carbon nanotubes by different functional selective agents in a controlled system were elaborated and analyzed. The results show that relying on specific backbone structure of carbon nanotubes

the introduction of functional groups or materials can significantly affect the physicochemical properties and surface activities of carbon nanotubes and promote their applications in a wider range of fields. In the future

achieving high-yield preparation and highly functional modification of ultrapure carbon nanotubes are directions that needs to be focused on.

关键词

碳纳米管结构特性可控修饰功能化改性

Keywords

carbon nanotubesstructural characteristiccontrolled modificationfunctional modification

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