MgO基CO<sub>2</sub>吸附剂成型技术研究进展

宋锦博; 屈婷; 荆洁颖; 李文英

doi:10.12434/j.issn.2097-2547.20230390

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MgO基CO₂吸附剂成型技术研究进展

二氧化碳捕集

- MgO基CO₂吸附剂成型技术研究进展
- Research progress on granulation technologies of MgO-based CO₂ adsorbent
- 低碳化学与化工 2024, 49(7): 1-12.
- 作者机构：
  
  1.太原理工大学省部共建煤基能源清洁高效利用国家重点实验室,山西太原 030024
  2.山西浙大新材料与化工研究院,山西太原,030000
- 作者简介：
  
  宋锦博（1999－），硕士研究生，研究方向为吸附强化制氢，E-mail：songjinbo0679@link.tyut.edu.cn。
  荆洁颖（1985－），博士，教授，研究方向为能源化工、环境催化，E-mail：jingjieying@tyut.edu.cn。
- 基金信息：
  
  国家重点研发计划(2022YFE0208400);山西浙大新材料与化工研究院研发项目(2021SX-FR002);中央高校基本科研业务费专项资金(2022ZFJH004)
- DOI：10.12434/j.issn.2097-2547.20230390
  中图分类号： TQ029+.4
- 纸质出版日期：2024-07-25，
  
  收稿日期：2023-11-28，
  
  修回日期：2023-12-25，
- 稿件说明：
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宋锦博,屈婷,荆洁颖等.MgO基CO₂吸附剂成型技术研究进展[J].低碳化学与化工,2024,49(07):1-12.

SONG Jinbo,QU Ting,JING Jieying,et al.Research progress on granulation technologies of MgO-based CO₂ adsorbent[J].Low-carbon Chemistry and Chemical Engineering,2024,49(07):1-12.
宋锦博,屈婷,荆洁颖等.MgO基CO₂吸附剂成型技术研究进展[J].低碳化学与化工,2024,49(07):1-12. DOI： 10.12434/j.issn.2097-2547.20230390.

SONG Jinbo,QU Ting,JING Jieying,et al.Research progress on granulation technologies of MgO-based CO₂ adsorbent[J].Low-carbon Chemistry and Chemical Engineering,2024,49(07):1-12. DOI： 10.12434/j.issn.2097-2547.20230390.

摘要

碳捕集、利用与封存（CCUS）技术是缓解温室效应的有效途径。使用固体吸附剂捕集CO

是减少CO

排放的可靠途径之一。在各种固体吸附剂中，MgO基吸附剂由于具有来源广泛、再生温度低以及理论吸附容量高的特点备受关注。但成型后的MgO基吸附剂颗粒面临着机械强度低、稳定性差和极易逸出反应器等问题，难以在工业中被广泛应用。重点总结了不同成型方法以及成型工艺条件对MgO基吸附剂的CO

吸附性能的影响。在MgO基吸附剂成型时，颗粒尺寸较小的吸附剂的碳酸化速率较快，磨耗率较低。添加适量成型助剂和蒸汽可以改善吸附剂颗粒的化学性能和机械强度，但较高的煅烧温度会加剧吸附剂颗粒的烧结和磨损。今后，MgO基CO

吸附剂成型技术的研究重点应以简单的工艺、低成本和良好的循环稳定性为立足点，制备既具有良好CO

吸附性能，又具有良好机械性能的吸附剂颗粒应用于工业化CO

捕集。

Abstract

Carbon capture

utilization and storage (CCUS) technology is an effective way to mitigate the greenhouse effect. Using solid adsorbents to capture CO

is considered to be one of reliable ways of reducing CO

emissions. MgO-based adsorbe

nts have attracted much attention due to their wide source

low regeneration temperature and high theoretical adsorption capacity in various solid adsorbents. However

the formed MgO-based adsorbents still face the problems of low mechanical strength

poor stability and easy to escape from the reactor

so they are difficult to be widely used in industry. The effects of different granulation methods and granulation process conditions on the CO

adsorption performance of MgO-based adsorbents were summarized. In the granulation process

the MgO-based adsorbents with smaller particle sizes have faster carbonation rates and lower wear rates. The chemical properties and mechanical strength of adsorbent particles can be improved by adding proper amount of granulation additives and steam. However

higher calcination temperatures can exacerbate sintering and wear of absorbent particles. In the future

the research should focus on developing simplified processes

low costs and good cycle stability

and prepare absorbent particles with both excellent CO

adsorption performance and mechanical properties for industrial-scale CO

capture.

关键词

MgO基吸附剂CO2捕集成型方法成型技术

Keywords

MgO-based adsorbentCO2 capturegranulation methodsgranulation technologies

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Research progress on granulation technologies of MgO-based CO2 adsorbent

DOI：10.12434/j.issn.2097-2547.20230390

摘要

Abstract

关键词

Keywords

references

MgO基CO₂吸附剂成型技术研究进展

Research progress on granulation technologies of MgO-based CO₂ adsorbent