季铵基吸附剂CO<sub>2</sub>变湿捕集-释放机制及相关材料研究进展

高云芳; 宋新山

doi:10.12434/j.issn.2097-2547.20230373

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季铵基吸附剂CO₂变湿捕集-释放机制及相关材料研究进展

二氧化碳捕集与利用

- 季铵基吸附剂CO₂变湿捕集-释放机制及相关材料研究进展
- Research progress on CO₂ moisture swing capture-release mechanism of quaternary ammonium-based adsorbents and related materials
- 低碳化学与化工 2024, 49(11): 104-112.
- 作者机构：
  
  东华大学环境科学与工程学院，上海 201600
- 作者简介：
  
  高云芳（2000—），硕士研究生，研究方向为CO2捕集，E-mail：2222339@mail.dhu.edu.cn。
  宋新山（1972—），博士，教授，博士研究生导师，研究方向为环境科学与工程，E-mail：newmountain@dhu.edu.cn。
- 基金信息：
  
  国家自然科学基金(52170152);上海市科技攻关项目(21DZ1202402)
- DOI：10.12434/j.issn.2097-2547.20230373
  中图分类号： TQ028;X701
- 纸质出版日期：2024-11-25，
  
  收稿日期：2023-11-17，
  
  修回日期：2023-12-19，
- 稿件说明：
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高云芳,宋新山.季铵基吸附剂CO₂变湿捕集-释放机制及相关材料研究进展[J].低碳化学与化工,2024,49(11):104-112.

GAO Yunfang,SONG Xinshan.Research progress on CO₂ moisture swing capture-release mechanism of quaternary ammonium-based adsorbents and related materials[J].Low-carbon Chemistry and Chemical Engineering,2024,49(11):104-112.
高云芳,宋新山.季铵基吸附剂CO₂变湿捕集-释放机制及相关材料研究进展[J].低碳化学与化工,2024,49(11):104-112. DOI： 10.12434/j.issn.2097-2547.20230373.

GAO Yunfang,SONG Xinshan.Research progress on CO₂ moisture swing capture-release mechanism of quaternary ammonium-based adsorbents and related materials[J].Low-carbon Chemistry and Chemical Engineering,2024,49(11):104-112. DOI： 10.12434/j.issn.2097-2547.20230373.

摘要

变湿吸附作为一种新型的CO

捕集技术，具有受水分变化驱动捕集-释放CO

的特点，可有效降低CO

捕集能耗和运行成本。阐述了季铵基吸附剂的变湿吸附技术机理，以及热力学、动力学角度的作用机制；介绍了影响吸附剂性能的因素；归纳了近年来吸附剂合成改性方法及研究进展；最后总结了该领域当前面临的挑战并指出了发展趋势。季铵基吸附剂吸附CO

的过程通过水蒸发驱动并受水分波动影响。当吸附剂负载二价及三价酸根阴离子，亲水/疏水层间距和阳离子间距均较小时，CO

吸附性能较强。可通过定向调控孔隙结构制备更小粒径、更丰富孔隙度和更高比表面积的吸附剂材料。此外，可通过强化季铵化或双季铵化等手段将季铵基官能团进行化学嫁接，以提高活性位点的密度并高效利用。目前变湿吸附技术处于发展阶段，在保持吸附剂较高比表面积和官能团利用率的基础上，改善吸附容量和循环速率是面向实际应用的必然需求；其规模化应用、捕集能耗的降低、环境耐受性的提高，以及捕集后CO

的处理也是亟待研究的重要方向。

Abstract

As a new type of CO

capture technology

moisture swing adsorption has the characteristics of capture-release CO

driven by moisture change

which can effectively reduce the energy consumption and operation cost of CO

capture. The mechanism of moisture swing adsorption technology of quaternary ammonium-based adsorbents and the mechanism of action from the perspective of thermodynamics and kinetics were described. The influencing factors of adsorbents performance were introduced. The synthesis and modification methods and research progress of adsorbents in recent years were summarized. Finally

the current challenges in this field were summarized and the development trend was pointed out. The process of CO

adsorption by quaternary ammonium-based adsorbents is driven by water evaporation and affected by moisture fluctuation. When the adsorbents are loaded with divalent and trivalent acid anions

the hydrophilic/hydrophobic layer spacing and cation spacing are small

and the CO

adsorption performance is strong. The adsorbent materials with smaller particle size

richer porosity and higher specific surface area can be prepared by directional regulation of pore structure. In addition

the quaternary

ammonium functional groups are chemically grafted by enhanced quaternization or biquaternization to enhance the density of active sites and efficient utilization. Moisture swing adsorption technology is currently in the development stage. On the basis of maintaining a high specific surface area and functional group utilization

improving the adsorption capacity and cycle rate is an inevitable demand for practical applications. Its large-scale application

reducing capture energy consumption

improving environmental tolerance

and the treatment of CO

after capture are also the key directions to be studied.

关键词

CO2捕集变湿吸附剂季铵基动力学热力学

Keywords

CO2 capturemoisture swing adsorbentsquaternary ammonium-basedkineticsthermodynamics

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季铵基吸附剂CO2变湿捕集-释放机制及相关材料研究进展

Research progress on CO2 moisture swing capture-release mechanism of quaternary ammonium-based adsorbents and related materials

DOI：10.12434/j.issn.2097-2547.20230373

摘要

Abstract

关键词

Keywords

references

季铵基吸附剂CO₂变湿捕集-释放机制及相关材料研究进展

Research progress on CO₂ moisture swing capture-release mechanism of quaternary ammonium-based adsorbents and related materials