醇胺法吸收烟道气中二氧化碳的研究进展

李亚清; 宋沆; 张玉涛; 郭强; 张园勃; 陈淼; 王麟迦; 金新祖

doi:10.12434/j.issn.2097-2547.20230352

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醇胺法吸收烟道气中二氧化碳的研究进展

二氧化碳捕集与利用

- 醇胺法吸收烟道气中二氧化碳的研究进展
- Research progress on absorption of carbon dioxide in flue gas by alcohol amine method
- 低碳化学与化工 2024, 49(10): 81-91.
- 作者机构：
  
  西安科技大学安全科学与工程学院，陕西西安 710054
- 作者简介：
  
  李亚清（1983－），博士，副教授，研究方向为碳捕集及利用，E-mail：lyqcumt@126.com。
  宋沆（2000－），硕士研究生，研究方向为碳捕集及利用，E-mail：411849188@qq.com。
- 基金信息：
  
  国家自然科学基金(52174196);中国博士后科学基金(2023M742817);陕西省博士后科研项目(2023BSHEDZZ299)
- DOI：10.12434/j.issn.2097-2547.20230352
  中图分类号： TK028
- 纸质出版日期：2024-10-25，
  
  收稿日期：2023-10-25，
  
  修回日期：2023-11-28，
- 稿件说明：
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李亚清,宋沆,张玉涛等.醇胺法吸收烟道气中二氧化碳的研究进展[J].低碳化学与化工,2024,49(10):81-91.

LI Yaqing,SONG Hang,ZHANG Yutao,et al.Research progress on absorption of carbon dioxide in flue gas by alcohol amine method[J].Low-carbon Chemistry and Chemical Engineering,2024,49(10):81-91.
李亚清,宋沆,张玉涛等.醇胺法吸收烟道气中二氧化碳的研究进展[J].低碳化学与化工,2024,49(10):81-91. DOI： 10.12434/j.issn.2097-2547.20230352.

LI Yaqing,SONG Hang,ZHANG Yutao,et al.Research progress on absorption of carbon dioxide in flue gas by alcohol amine method[J].Low-carbon Chemistry and Chemical Engineering,2024,49(10):81-91. DOI： 10.12434/j.issn.2097-2547.20230352.

摘要

二氧化碳（CO

）捕集、利用与封存技术是实现双碳目标的主要技术手段之一。醇胺法吸收烟道气中CO

是目前发展最成熟、应用最广泛的CO

捕集工艺，已普遍应用于烟道气工业除碳。吸收剂是醇胺法的核心要素，选择合适的吸收剂已成为目前的重点研

究方向。综述了醇胺类吸收剂的分类和工作原理，以及吸收烟道气中CO

的工艺流程。深度分析了乙醇胺（MEA）和甲基二乙胺（MDEA）单独作为吸收剂，以及MEA和MDEA分别作为主要吸收剂的二元混合吸收体系的性能。针对醇胺法吸收烟道气中CO

存在的再生效率低、解吸能耗高、吸收剂易腐蚀设备和回收成本高等缺点，提出了在醇胺溶液中加入活化剂和添加剂、使用新型吸收剂和优化工艺参数等一系列优化措施。最后对醇胺法吸收烟道气中CO

的发展进行了展望，以期为开发高效醇胺类吸收剂提供借鉴。

Abstract

Carbon dioxide (CO

) capture

utilization and storage technology is one of the main technological ways to achieve the carbon peaking and carbon neutrality goal. Alcohol amine method to absorb CO

in flue gas is the most mature and widely used CO

capture process

which has been commonly used in the industrial decarbonization of flue gas. Absorbents are the core elements of the alcohol amine method

and the selection of suitable absorbents has become a key research direction at present. The classification and working principles of alcohol amine absorbents and the process flow of CO

absorption in flue gas were reviewed. The performances of a binary mixed absorption system of ethanolamine (MEA) and methylenediamine (MDEA) as absorbents and MEA and MDEA as main absorbents respectively were analyzed in depth. A series of optimization measures

including adding activators and additives into the alcohol amine solution

using new absorbents

were proposed to address the drawbacks of low regeneration efficiency

high desorption energy consumption

easy corrosion of absorbents and high recovery costs in the alcohol amine method to absorb CO

in flue gas. Finally

the development of the alcohol amine method to absorb CO

in flue gas was discussed

so as to provide a reference for the development of high-efficiency alcohol amine absorbents.

关键词

CO2碳捕集醇胺法MEAMDEA烟道气

Keywords

CO2carbon capturealcohol amine methodMEAMDEAflue gas

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