甲烷选择性氧化制含氧化合物催化剂研究进展

余海杰; 李潇; 冉建速; 丁大千; 王健健

doi:10.12434/j.issn.2097-2547.20230279

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甲烷选择性氧化制含氧化合物催化剂研究进展

碳一分子资源化利用

- 甲烷选择性氧化制含氧化合物催化剂研究进展
- Research progress in catalysts for selective oxidation of methane to oxygenated compounds
- 低碳化学与化工 2023, 48(5): 9-21.
- 作者机构：
  
  1.重庆大学化学化工学院，前沿交叉学科研究院，煤矿灾害动力学与控制全国重点实验室，跨尺度多孔材料研究中心，重庆 401331
  2.内蒙古工业大学化工学院，内蒙古呼和浩特 010051
- 作者简介：
  
  余海杰（1996—），硕士研究生，研究方向为甲烷催化转化，E-mail：824139378@qq.com。
  李潇（1993—），博士，助理研究员，研究方向为金属纳米催化材料，E-mail：lixiao@cqu.edu.cn；
  丁大千（1989—），博士，副教授，研究方向为含碳废弃物资源化利用，E-mail：ddqcatal@imut.edu.cn；
  王健健（1987—），博士，研究员，研究方向为多相催化，E-mail：wangjianjian@cqu.edu.cn。
- 基金信息：
  
  煤矿灾害动力学与控制全国重点实验室面上项目(2011DA105287-MS202203);重庆自然科学基金面上项目(CSTB2022NSCQ-MSX0458)
- DOI：10.12434/j.issn.2097-2547.20230279
  中图分类号：
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余海杰, 李潇, 冉建速, 等. 甲烷选择性氧化制含氧化合物催化剂研究进展[J]. 低碳化学与化工, 2023,48(5):9-21.

YU Haijie, LI Xiao, RAN Jiansu, et al. Research progress in catalysts for selective oxidation of methane to oxygenated compounds[J]. Low-carbon Chemistry and Chemical Engineering, 2023,48(5):9-21.
余海杰, 李潇, 冉建速, 等. 甲烷选择性氧化制含氧化合物催化剂研究进展[J]. 低碳化学与化工, 2023,48(5):9-21. DOI： 10.12434/j.issn.2097-2547.20230279.

YU Haijie, LI Xiao, RAN Jiansu, et al. Research progress in catalysts for selective oxidation of methane to oxygenated compounds[J]. Low-carbon Chemistry and Chemical Engineering, 2023,48(5):9-21. DOI： 10.12434/j.issn.2097-2547.20230279.

摘要

甲烷选择性氧化制含氧化合物是天然气资源高效利用的新路线之一。围绕甲烷选择性氧化制甲醇、甲醛、甲酸和乙酸，综述了国内外研究的新进展，分析了催化剂的活性中心、反应过程中的活性物种、反应机理，以及催化剂的构效关系，展望了甲烷选择性氧化制含氧化合物的未来发展方向，可为设计与开发高活性、高选择性的甲烷选择性氧化催化剂提供参考。

Abstract

The selective oxidation of methane to oxygenated compounds is considered a novel approach for the efficient utilization of natural gas resources. Recent advancements in both domestic and international research were reviewed, focusing on the selective oxidation of methane to methanol, formaldehyde, formic acid, and acetic acid. The active centers of catalysts, the active intermediates formed during the reaction, the reaction mechanism, and the structure-activity relationship of catalysts were analyzed. Furthermore, the future prospects for the selective oxidation of methane to oxygenated compounds were outlined. It can offer theoretical guidance for the design and development of highly active and selective catalysts for selective oxidation of methane.

关键词

甲烷选择性氧化活性物种反应机理催化剂

Keywords

methaneselective oxidationactive intermediatereaction mechanismcatalysts

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