多孔碳材料室温下催化氧化H2S的研究进展
Research progress on porous carbon materials for catalytic oxidation of H2S at room temperature
- 低碳化学与化工 2023, 48(5): 135-146.
- 作者机构：
1.四川大学 建筑与环境学院,四川 成都 610065
2.四川大学 碳中和未来技术学院,四川 成都 610065
3.成都达奇科技股份有限公司,四川 成都 610065
- 作者简介：
刘晓丽（1987—），博士研究生，工程师，研究方向为工业烟气污染物控制与资源化、环境催化与环境功能材料，E-mail：liuxiaolisn@163.com。
李建军（1963—），博士，教授，博士生导师，研究方向为工业烟气污染物控制与资源化、催化材料、能源回收利用及节能降碳，E-mail：jjli@scu.edu.cn。
- 基金信息：四川省重点研发计划(2022ZHCG0136)
DOI：10.12434/j.issn.2097-2547.20230258
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刘晓丽, 李建军, 李新. 多孔碳材料室温下催化氧化H2S的研究进展[J]. 低碳化学与化工, 2023,48(5):135-146.
LIU Xiaoli, LI Jianjun, LI Xin. Research progress on porous carbon materials for catalytic oxidation of H2S at room temperature[J]. Low-carbon Chemistry and Chemical Engineering, 2023,48(5):135-146.
刘晓丽, 李建军, 李新. 多孔碳材料室温下催化氧化H2S的研究进展[J]. 低碳化学与化工, 2023,48(5):135-146. DOI： 10.12434/j.issn.2097-2547.20230258.
LIU Xiaoli, LI Jianjun, LI Xin. Research progress on porous carbon materials for catalytic oxidation of H2S at room temperature[J]. Low-carbon Chemistry and Chemical Engineering, 2023,48(5):135-146. DOI： 10.12434/j.issn.2097-2547.20230258.
摘要
硫化氢（H,2,S）是一种剧毒和腐蚀性气体，即使是在低浓度水平下，也会对工业生产、生态环境和人类健康产生不利影响。因此，从工业气体中脱除H,2,S具有重要意义。近年来，室温下催化氧化H,2,S（简称“催化氧化H,2,S”，下同）具有成本低、脱除效率高和可回收硫资源等优点，受到了科研人员的广泛关注。多孔碳材料具有比表面积高和孔体积大的优点，适合用作催化氧化H,2,S的催化剂。首先分析了多孔碳材料催化氧化H,2,S的反应机理，然后在此基础上综述了可用于催化氧化H,2,S的多孔碳材料的研究进展，指出通过采用不同的改性方法，如杂原子掺杂、碱溶液浸渍和金属氧化物负载等可以明显提高多孔碳材料催化氧化H,2,S的性能。最后对多孔碳材料催化氧化H,2,S的研究重点和有待解决的关键科学问题进行了展望，可为该领域的未来研究提供参考。
Abstract
Hydrogen sulfide (H,2,S) is a highly toxic and corrosive gas, even at low concentration levels, will have negative effects on industrial production, ecological environment and human health. Therefore, the removal of H,2,S from industrial gases is of great significance. In recent years, catalytic oxidation of H,2,S at room temperature (referred to as “catalytic oxidation of H,2,S”, the same below) have attracted extensive attention of researchers because of its low cost, high sulfur removal efficiency and the possibility of sulfur recovery. Porous carbon materials have the advantages of high specific surface area and large pore volume, and are suitable for catalytic oxidation of H,2,S. The mechanisms for catalytic oxidation of H,2,S by porous carbon materials were first discussed, and then the research progress of porous carbon materials that can be used for catalytic oxidation of H,2,S was reviewed. It is pointed out that the catalytic oxidation performance of porous carbon materials can be significantly improved by using different modification methods, such as heteroatom doping, alkaline solution impregnation and metal oxide loading. Finally, the key research points and the key scientific problems to be solved in catalytic oxidation of H,2,S by porous carbon materials were prospected, which can provide a reference for the future research of this field.
关键词
硫化氢多孔碳材料催化氧化室温
Keywords
hydrogen sulfideporous carbon materialscatalytic oxidationroom temperature
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