催化剂中金属与载体相互作用的表征研究进展

彭洁; 李曜; 储政; 于杨

doi:10.12434/j.issn.2097-2547.20230246

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催化剂中金属与载体相互作用的表征研究进展

C1化学与催化转化

- 催化剂中金属与载体相互作用的表征研究进展
- Research progress in characterization of metal-support interactions in catalysts
- 低碳化学与化工 2024, 49(2): 1-9.
- 作者机构：
  
  中石化南京化工研究院有限公司，江苏南京 210048
- 作者简介：
  
  彭洁（1994—），博士，助理研究员，研究方向为工业催化剂开发与应用，E-mail：pengjiely@163.com。
  于杨（1979—），博士，副研究员，研究方向为工业催化剂开发与应用，E-mail：yuyang.nhgs@sinopec.com。
- 基金信息：
  
  江苏省“卓越博士后计划”
- DOI：10.12434/j.issn.2097-2547.20230246
  中图分类号： TQ426;O657.99
- 纸质出版日期：2024-02-25，
  
  收稿日期：2023-07-16，
  
  修回日期：2023-09-06，
- 稿件说明：
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彭洁,李曜,储政等.催化剂中金属与载体相互作用的表征研究进展[J].低碳化学与化工,2024,49(02):1-9.

PENG Jie,LI Yao,CHU Zheng,et al.Research progress in characterization of metal-support interactions in catalysts[J].Low-carbon Chemistry and Chemical Engineering,2024,49(02):1-9.
彭洁,李曜,储政等.催化剂中金属与载体相互作用的表征研究进展[J].低碳化学与化工,2024,49(02):1-9. DOI： 10.12434/j.issn.2097-2547.20230246.

PENG Jie,LI Yao,CHU Zheng,et al.Research progress in characterization of metal-support interactions in catalysts[J].Low-carbon Chemistry and Chemical Engineering,2024,49(02):1-9. DOI： 10.12434/j.issn.2097-2547.20230246.

摘要

负载型催化剂是低碳催化转化领域重要的一类催化剂，金属-载体相互作用广泛存在于负载型催化剂中。这种相互作用会显著影响催化剂的物理结构和电子结构，进而既可调控活性金属的催化活性和稳定性，又可达到金属-载体协同催化的效果，促进低碳烃类、醇类等的选择性催化转化。因此，研究金属-载体相互作用对催化剂优化和催化机理的深入探究都有十分重要的意义。基于非原位和原位表征技术，从静态性质和动态性质两个方面，综述了金属-载体相互作用的表征研究进展。通过非原位表征技术，如高分辨电镜、振动光谱、X射线谱学和电子顺磁共振谱等，可以表征金属与载体之间的物质输运、电荷偏移等情况；通过原位表征技术，如原位红外、原位X射线谱学和原位电子顺磁共振等，可以表征金属-载体相互作用的强弱变化、反应过程中催化剂的界面结构和组分变化以及动态电荷转移的过程等。

Abstract

Supported catalysts are crucial in low-carbon catalytic conversion

and metal-support interactions is widely present in supported catalysts. These interactions play a vital role in determining the physical and electronic structure of these catalysts

and not only regulate the catalytic activity and stability of active metals but also enable the synergistic catalysis effect between metals and supports

thus promoting the selective catalytic conversion of low-carbon hydrocarbons

alcohols and other compounds. Hence

understanding the metal-support interactions is essential for the optimization of catalysts and exploring catalytic mechanisms deeply. The research progress in characterization of metal-support interactions using ex situ and in situ techniques were discussed. Ex situ characterization techniques

such as high-resolution electron microscopy

vibrational spectroscopy

X-ray spectroscopy and electron par

amagnetic resonance spectroscopy can investigate mass transport and charge transfer between metals and supports. In situ characterization techniques

such as in situ infrared spectroscopy

in situ

X-ray spectroscopy and in situ

electron paramagnetic resonance can characterize the strength changes of metal-support interactions

changes of interface structures and compositions of catalysts during reactions

as well as the dynamic charge transfer processes.

关键词

金属-载体相互作用表征技术静态性质动态性质

Keywords

metal-support interactionscharacterization techniquesstatic propertiesdynamic properties

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