Ammonia borane（AB） is a liquid-phase hydrogen storage material that has gained significant attention due to its high hydrogen content. However, the slow rate and the uncertain catalytic mechanism of AB hydrolysis have hindered its large-scale application. Therefore, the development of efficient supported catalysts for AB hydrolysis to generate hydrogen is of great importance.The research progress on catalysts for hydrolysis of AB was reviewed, focusing on active center materials and carrier materials such as carbon materials, metal oxides, metal hydroxides, transition metal carbides, two-dimensional transition metal carbonide/nitrides,metal-organic frameworks, metal nitrides, and covalent organic frameworks. The reaction mechanism of AB hydrolysis was discussed,and the future development of AB hydrolysis for hydrogen production was also prospected.