铁基催化剂活性相调控及其催化CO2加氢制线性
α -烯烃研究进展Research progress on active phases regulation of iron-based catalysts and their CO2 catalytic hydrogenation to linear
α -olefins- 低碳化学与化工 2023, 48(5): 1-8.
- 作者机构：
1.宁夏大学 化学化工学院 省部共建煤炭高效利用与绿色化工国家重点实验室，宁夏 银川 750021
2.国家能源集团宁夏煤业有限责任公司煤炭化学工业技术研究院，宁夏 银川 750411
3.国家煤及煤化工产品质量检验检测中心（宁夏） 宁夏计量质量检验检测研究院，宁夏 银川 750200
- 作者简介：
高新华（1990—），博士，研究员，研究方向为CO2转化利用，E-mail：gxh@nxu.edu.cn。
王 晨（1996—），博士研究生，研究方向为CO2转化利用，E-mail：840933486@qq.com；
段 斌（1986—），硕士，高级工程师，研究方向为煤化工，E-mail：416850821@qq.com。
- 基金信息：国家自然科学基金(21965029);宁夏自然科学基金(2022AAC03040;2022AAC01001)
DOI：10.12434/j.issn.2097-2547.20230108
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高新华, 夏世钦, 梁洁, 等. 铁基催化剂活性相调控及其催化CO2加氢制线性
α -烯烃研究进展[J]. 低碳化学与化工, 2023,48(5):1-8.GAO Xinhua, XIA Shiqin, LIANG Jie, et al. Research progress on active phases regulation of iron-based catalysts and their CO2 catalytic hydrogenation to linear
α -olefins[J]. Low-carbon Chemistry and Chemical Engineering, 2023,48(5):1-8.高新华, 夏世钦, 梁洁, 等. 铁基催化剂活性相调控及其催化CO2加氢制线性
α -烯烃研究进展[J]. 低碳化学与化工, 2023,48(5):1-8. DOI： 10.12434/j.issn.2097-2547.20230108.GAO Xinhua, XIA Shiqin, LIANG Jie, et al. Research progress on active phases regulation of iron-based catalysts and their CO2 catalytic hydrogenation to linear
α -olefins[J]. Low-carbon Chemistry and Chemical Engineering, 2023,48(5):1-8. DOI： 10.12434/j.issn.2097-2547.20230108.
摘要
线性,α,-烯烃（LAOs）作为重要的化工原料，通常用于共聚单体、合成润滑油、增塑剂用醇和油品添加剂。以二氧化碳（CO,2,）和氢气（H,2,）作为原料，通过CO,2,加氢反应生产LAOs可以缓解温室效应、实现CO,2,高值化利用，具有重要意义。CO,2,加氢制LAOs一般包括逆水煤气变换（RWGS）和费托合成（FTS）两个步骤，四氧化三铁（Fe,3,O,4,）和碳化铁（,χ,-Fe,5,C,2,等）可分别催化RWGS和FTS反应，因此Fe基催化剂是当前的研究热点。介绍了Fe基催化剂的物相演变过程及其失活机制，重点分析了载体、助剂和表面改性对促进,χ,-Fe,5,C,2,活性相生成、调控Fe,3,O,4,/,χ,-Fe,5,C,2,比例（物质的量之比）和维持,χ,-Fe,5,C,2,相稳定的作用，总结了Fe基催化剂上CO,2,加氢制LAOs面临的主要问题以及未来的研究方向。
Abstract
As an important chemical raw material, linear ,α,-olefins (LAOs) are usually used for the copolymerization of monomers and the synthesis of lubricants, plasticizers and oil additives. It is of great significance to use carbon dioxide (CO,2,) and hydrogen (H,2,) as raw materials to produce LAOs through CO,2, hydrogenation reaction, which can alleviate the greenhouse effect and realize high value utilization of CO,2,. CO,2, hydrogenation to LAOs generally consists of two steps: Reverse water gas shift (RWGS) and Fischer-Tropsch synthesis (FTS). Ferroferric oxide (Fe,3,O,4,) and iron carbide (,χ,-Fe,5,C,2 ,et al.) can catalyze RWGS and FTS reactions, respectively, so Fe-based catalysts are currently the focus of research. The phase evolution process and deactivation mechanism of Fe-based catalysts were discussed. The effects of supports, promoters and surface modification on promoting the generation of ,χ,-Fe,5,C,2, active phase, regulating the ratio of Fe,3,O,4,/,χ,-Fe,5,C,2 ,(mole fraction), and maintaining the stability of ,χ,-Fe,5,C,2, phase were emphatically analyzed. The main problems and future research directions of CO,2, hydrogenation to LAOs on Fe-based catalysts were summarized.
关键词
线性α-烯烃CO2加氢Fe基催化剂活性相
Keywords
linear α-olefinsCO2 hydrogenationFe-based catalystsactive phases
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