有机液体储氢体系研究进展

李欣雨; 唐鋆磊; 李佳奇; 雷宪章; 周太刚

doi:10.12434/j.issn.2097-2547.20230080

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有机液体储氢体系研究进展

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- 有机液体储氢体系研究进展
- Research progress in hydrogen storage system of organic liquid
- 低碳化学与化工 2023, 48(6): 107-119.
- 作者机构：
  
  1.西南石油大学化学化工学院，碳中和研究院，四川成都 610500
  2.天府永兴实验室，四川成都 610000
  3.中国农业大学理学院，北京 100193
  4.成都岷山绿氢能源有限公司，四川成都 610000
- 作者简介：
  
  李欣雨（1996—），硕士研究生，研究方向为有机液体储氢，E-mail：2811945568@qq.com。
  李佳奇（1982—），博士，副教授，研究方向为有机合成及化学储氢，E-mail：jiaqili@cau.edu.cn；
  雷宪章（1955—），博士，德国国家工程院院士，教授，研究方向为能源电力及装备、新型能源及新型材料，E-mail：leixianzhang@hotmail.com；
  周太刚（1982—），博士，研究员，研究方向为有机合成、不对称催化及化学储氢，E-mail：tgzhou@swpu.edu.cn。
- 基金信息：
  
  四川省科技计划资助项目(2021ZYCD005);西南石油大学自然科学“揭榜挂帅”项目(2021JBGS07);天府实验室碳中和科技创新基地建设项目(2021ZYD0099)
- DOI：10.12434/j.issn.2097-2547.20230080
  中图分类号：
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李欣雨,唐鋆磊,李佳奇等.有机液体储氢体系研究进展[J].低碳化学与化工,2023,48(06):107-119.

LI Xinyu,TANG Junlei,LI Jiaqi,et al.Research progress in hydrogen storage system of organic liquid[J].Low-carbon Chemistry and Chemical Engineering,2023,48(06):107-119.
李欣雨,唐鋆磊,李佳奇等.有机液体储氢体系研究进展[J].低碳化学与化工,2023,48(06):107-119. DOI： 10.12434/j.issn.2097-2547.20230080.

LI Xinyu,TANG Junlei,LI Jiaqi,et al.Research progress in hydrogen storage system of organic liquid[J].Low-carbon Chemistry and Chemical Engineering,2023,48(06):107-119. DOI： 10.12434/j.issn.2097-2547.20230080.

摘要

有机液体储氢技术是利用液态有机储氢载体进行加（脱）氢反应，在常温常压下实现大规模、远距离氢气安全储运的技术，被国际能源署推荐为国际氢气贸易和远程氢气运输的最佳方式之一。但是目前有机液体储氢技术还存在加（脱）氢反应过程缓慢、脱氢温度高、储氢体系循环率低以及高度依赖贵金属催化剂等缺点。本文首先对常见的有机氢载体进行分类，并分析了各种有机氢载体的物理化学性质及其在加（脱）氢反应中的特征差异，然后从加（脱）氢反应机理和催化剂的研究等方面对有机液体储氢体系的研究现状进行了总结，最后对有机液体储氢技术的发展前景进行了展望。

Abstract

Organic liquid hydrogen storage technology is a technology that uses liquid organic hydrogen storage carriers to hydrogen addition (dehydrogenation) reaction and achieve large-scale, long-distance hydrogen storage and transportation at normal temperature and pressure. It is recommended by the International Energy Agency as one of the best ways for international hydrogen trade and long-distance hydrogen transportation. However, the current organic liquid hydrogen storage technology still has some shortcomings, such as slow hydrogen addition (dehydrogenation) reaction process, high dehydrogenation temperature, low cycle rate of hydrogen storage system and high dependence on precious metal catalyst. The common organic hydrogen carriers were classified firstly, and the physical and chemical properties of various organic hydrogen carriers and their characteristic differences in hydrogen addition (dehydrogenation) reaction were analyzed, and then the current research status of organic liquid hydrogen storage system was summarized from the research of hydrogen addition (dehydrogenation) reaction mechanism and catalyst. Finally, the development prospect of organic liquid hydrogen storage technology was prospected.

关键词

有机液体储氢有机氢载体加氢脱氢催化剂

Keywords

organic liquid hydrogen storageorganic hydrogen carriershydrogenationdehydrogenationcatalyst

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