1. 陇东学院 石油化工学院,甘肃,庆阳,745000
2. 中国石油天然气股份有限公司庆阳石化分公司,甘肃,庆阳,745000
3. 宁夏天利丰能源利用有限公司,宁夏,吴忠,751000
4. 兰州工业学院 机械工程学院,甘肃,兰州,730050
扫 描 看 全 文
任金平, 芦娅妮, 黄波, 等. 天然气液化过程中重烃组分脱除工艺设计及应用[J]. 低碳化学与化工.
REN Jinping, LU Yani, HUANG Bo, et al. Design and application of heavy hydrocarbons removal in natural gas liquefaction process[J]. Low-Carbon Chemistry and Chemical Engineering.
任金平, 芦娅妮, 黄波, 等. 天然气液化过程中重烃组分脱除工艺设计及应用[J]. 低碳化学与化工. DOI: 10.12434/j.issn.2097-2547.20220323.
REN Jinping, LU Yani, HUANG Bo, et al. Design and application of heavy hydrocarbons removal in natural gas liquefaction process[J]. Low-Carbon Chemistry and Chemical Engineering. DOI: 10.12434/j.issn.2097-2547.20220323.
天然气液化前需对原料气进行净化处理,脱除其中的CO,2,、H,2,O、H,2,S和重烃(C,5,及以上烃类,简写为“C,5+,”)组分等,防止以上组分在液化段冻结形成固体,堵塞管道和设备。以西部某液化天然气(LNG)工厂为例,针对该厂管道原料天然气C,5+,组分变化波动大、含量(物质的量分数,下同)高的情况,在对原料天然气组分检测分析的基础上,对原C,5+,组分脱除工艺进行了改造设计,采用Aspen Hysys软件对设计的C,5+,组分脱除新工艺进行了模拟计算并应用于生产,最后对生产中净化处理后的天然气组分进行了检测分析。结果表明,低温冷凝预分离+高性能活性炭吸附组合的C,5+,组分脱除工艺理论上可行,在保证天然气C,5+,组分满足液化过程要求的情况下,最大限度的保留了C,2,~C,4,组分不被脱除,提高了LNG的热值。模拟结果中脱除C,5+,组分后的天然气中C,5+,组分含量为0.007265%,与实际生产中净化处理后的天然气检测结果中的C,5+,组分含量0.0076%相差不大,较为吻合。
Before natural gas liquefaction,the raw natural gas needs to be purified to remove CO,2,H,2,O,H,2,S and heavy hydrocarbon(C,5, and above hydrocarbons,abbreviated as“C,5+,”) components in it,so as to prevent the above components from freezing and forming solid in the liquefaction section and blocking the pipeline and equipment.Taking a western liquefied natural gas(LNG) plant as an example,in view of the large variation and high content(mole fraction,the same as below) of C,5+,components of raw natural gas in the pipeline of the plant,the original C,5+,component removal process was reconstructed and designed based on the analysis and detection of raw natural gas components,and the designed C,5+, component removal process was simulated and calculated with Aspen Hysys software and applied to production.Finally,the components of purified natural gas in production were detected and analyzed.The research shows that the C,5+, component removal process combined with low temperature condensation pre-separation and high performance activated carbon adsorption is theoretically feasible.Under the condition that the C,5+, components of natural gas meet the requirements of liquefaction process,the C,2,~C,4, components are retained to the maximum extent,and the heating value of LNG is improved.In the simulation results,the C,5+, component content in the natural gas after C,5+, component removal is 0.007265%,which is similar to 0.0076%of C,5+, component content in the natural gas after purification in the actual production.
天然气重烃脱除液化工艺改造模拟计算
natural gasheavy hydrocarbons removalliquefactionprocess reconstructsimulation and calculation
0
浏览量
144
下载量
0
CSCD
关联资源
相关文章
相关作者
相关机构