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Research progress on catalysts modified by rare earth elements for CO2 hydrogenation to methanol
- Low-carbon Chemistry and Chemical Engineering Vol. 49, Issue 11, Pages: 1-11(2024)
- 作者机构：
1.兰州大学 材料与能源学院，甘肃 兰州 730000
2.兰州大学 化学化工学院 功能有机分子化学国家重点实验室，甘肃 兰州 730000
3.中国科学院 兰州化学物理研究所 羰基合成与选择氧化国家重点实验室，甘肃 兰州 730000
- 作者简介：
- 基金信息：
DOI：10.12434/j.issn.2097-2547.20240236
CLC： TQ426Published：25 November 2024，
Received：27 May 2024，
Revised：02 July 2024，
- 稿件说明：
移动端阅览
杨军,梁丽烨,李华等.稀土元素改性CO2加氢制甲醇催化剂的研究进展[J].低碳化学与化工,2024,49(11):1-11.
YANG Jun,LIANG Liye,LI Hua,et al.Research progress on catalysts modified by rare earth elements for CO2 hydrogenation to methanol[J].Low-carbon Chemistry and Chemical Engineering,2024,49(11):1-11.
杨军,梁丽烨,李华等.稀土元素改性CO2加氢制甲醇催化剂的研究进展[J].低碳化学与化工,2024,49(11):1-11. DOI： 10.12434/j.issn.2097-2547.20240236.
YANG Jun,LIANG Liye,LI Hua,et al.Research progress on catalysts modified by rare earth elements for CO2 hydrogenation to methanol[J].Low-carbon Chemistry and Chemical Engineering,2024,49(11):1-11. DOI： 10.12434/j.issn.2097-2547.20240236.
摘要
化石燃料对人类社会具有重要作用，然而CO
2
大量排放对全球气候产生了负面影响。CO
2
加氢制甲醇不仅能够有效降低大气中CO
2
浓度，还提供了高附加值化学品。非贵金属（Cu）基、贵金属（Pd）基和双金属氧化物等一系列催化剂已经被运用于CO
2
加氢制甲醇，然而传统Cu基催化剂存在反应条件苛刻、活性位点易烧结和团聚的问题，Pd基催化剂抗烧结性能较好且在低温下有优异的反应活性，但贵金属对CO
2
的吸附较弱，CO
2
在低温下很难被活化。双金属氧化物催化剂（以ln
2
O
3
基和ZrO
2
基催化剂为主）具有优异的催化性能和良好的稳定性，其中单独的In
2
O
3
自身稳定性较差，且In
2
O
3
基催化剂的活性相 In
2
O
3-
x
容易被过度还原形成金属 In 而失活，需要掺杂其他改性元素进一步提高其稳定性和活性；单独的ZrO
2
催化性能不理想，需要通过与其他金属或金属氧化物相互作用提升其催化性能。稀土元素（La、Ce和Y）作为改性元素或其氧化物作为催化剂载体，能有效调节催化剂的表面酸碱性、活性相分散度和比表面积以及金属-载体相互作用等，从而改善催化剂对CO
2
的吸附和活化性能，增大产物选择性，并提高催化剂稳定性。综述了La、Ce和Y对Cu基、Pd基和双金属氧化物催化剂的改性作用，以期为稀土元素改性CO
2
加氢制甲醇催化剂的研发和应用提供参考。
Abstract
Fossil fuels have an important contribution to human society
but the large amount of CO
2
emissions has a negative impact on the global climate. CO
2
hydrogenation to methanol not only effectively reduces the concent
ration of CO
2
in the atmosphere
but also provides high value-added chemicals. A range of non-precious metal (Cu)-based
precious metal (Pd)-based and bimetallic oxide catalysts have been used for CO
2
hydrogenation to methanol. However
conventional Cu-based catalysts suffer from harsh reaction conditions and easy sintering as well as agglomeration of active sites. Pd-based catalysts are more resistant to sintering and have excellent reactivity at low temperatures
but noble metals have weak adsorption of CO
2
and CO
2
is difficult to be activated at low temperatures. Bimetallic oxide catalysts (mainly ln
2
O
3
-based and ZrO
2
-based catalysts) have excellent catalytic performance and good stability. Among which
the stability of In
2
O
3
alone is poor
and the active phase In
2
O
3-
x
of In
2
O
3
-based catalyst is easily deactivated by excessive reduction to form metal In
which needs to be doped with other modified elements to further improve its stability and activity. The catalytic performance of ZrO
2
alone for CO
2
hydrogenation to methanol is not ideal
and its catalytic performance needs to be improved by interacting with other metals or metal oxides. Rare earth elements (La
Ce and Y) as modified elements or their oxides as catalyst carriers can effectively regulate the surface acidity and alkalinity of catalysts
the dispersion of active phases and their specific surface area and metal-carrier interactions
etc.
so as to improve the adsorption and activation capacity of catalysts for CO
2
increase the selectivity of products and enhance the stability of the catalysts. The modification effects of La
Ce and Y on Cu-based
Pd-based and bimetallic oxide catalysts were reviewed
in order to provide reference for the development and application of catalysts modified by rare earth elements for CO
2
hydrogenation to
methanol.
关键词
CO2加氢甲醇稀土元素改性作用
Keywords
CO2 hydrogenationmethanolrare earth elementsmodification effects
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