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Research progress on naphthalene-decalin organic liquid hydrogen storage technology
- Low-carbon Chemistry and Chemical Engineering Vol. 49, Issue 9, Pages: 97-105(2024)
- 作者机构：
1.上海交通大学 化学化工学院，上海 200240
2.太原理工大学 化学工程与技术学院，山西 太原 030024
- 作者简介：
- 基金信息：
DOI：10.12434/j.issn.2097-2547.20240174
CLC： TQ116.29Published：25 September 2024，
Received：23 April 2024，
Revised：29 May 2024，
- 稿件说明：
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邹家富,闫晓亮,刘鹏等.萘-十氢萘有机液体储氢技术研究进展[J].低碳化学与化工,2024,49(09):97-105.
ZOU Jiafu,YAN Xiaoliang,LIU Peng,et al.Research progress on naphthalene-decalin organic liquid hydrogen storage technology[J].Low-carbon Chemistry and Chemical Engineering,2024,49(09):97-105.
邹家富,闫晓亮,刘鹏等.萘-十氢萘有机液体储氢技术研究进展[J].低碳化学与化工,2024,49(09):97-105. DOI： 10.12434/j.issn.2097-2547.20240174.
ZOU Jiafu,YAN Xiaoliang,LIU Peng,et al.Research progress on naphthalene-decalin organic liquid hydrogen storage technology[J].Low-carbon Chemistry and Chemical Engineering,2024,49(09):97-105. DOI： 10.12434/j.issn.2097-2547.20240174.
摘要
氢气未被高效存储是制约绿色氢能大规模应用的瓶颈。相比现有储氢技术，萘-十氢萘有机液体储氢作为一种极具应用前景的储氢技术，有望为未来能源储存和利用提供一种全新、高效的解决方案。萘-十氢萘储氢体系可提升有机液体储氢量、完善加氢/脱氢循环以及提高经济性。综述了萘-十氢萘有机液体储氢技术研究进展，分析了萘加氢和十氢萘脱氢机理，讨论了萘加氢与十氢萘脱氢的催化剂结构、工艺过程和技术经济性等，总结了萘-十氢萘有机液体储氢技术面临的主要挑战。从需求关键点出发，通过深入探究十氢萘脱氢反应机理，从原子角度设计高效催化剂，构筑催化剂表面结构，提高十氢萘脱氢效率，以推动萘-十氢萘有机液体储氢技术的商业化。
Abstract
The inefficient storage hydrogen is the bottleneck that restricts the large-scale application of green hydrogen energy. Compared with the existing hydrogen storage technologies
naphthalene-decalin organic liquid hydrogen storage
as a highly promising hydrogen storage technology
is expected to provide a new and efficient solution for future energy storage and utilization. The naphthalene-decalin hydrogen storage system can enhance the hydrogen storage capacity of organic liquids
improve the hydrogenation/dehydrogenation cycle and increase economic efficiency. The research progress on naphthalene-decalin organic liquid hydrogen storage technology was reviewed
and the mechanisms of naphthalene hydrogenation and decalin dehydrogenation were analyzed
and the structures of catalysts
processes and technical economy of naphthalene hydrogenation and decalin dehydrogenation were discussed
and the main challenges of naphthalene-decalin organic liquid hydrogen storage technology were summarized. Starting from the key points of demand
through in-depth exploration of the mechanism of decalin dehydrogenation
highly efficient catalysts from the atomic point of view are designed and structures of catalyst surface are constructed to improve the efficiency of decalin dehydrogenation and promote the commercialization of naphthalene-decalin organic liquid hydrogen storage technology.
关键词
萘十氢萘加氢脱氢
Keywords
naphthalenedecalinhydrogenationdehydrogenation
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