- About Journal
- Editorial Board
- Guidance
- Journal Online
- 个人中心
- 退出登录
浏览全部资源
扫码关注微信
Research progress of carbon dioxide capture in flue gas by membrane separation method
- Low-carbon Chemistry and Chemical Engineering Vol. 49, Issue 11, Pages: 113-121(2024)
- 作者机构：
中国石化工程建设有限公司，北京 100101
- 作者简介：
- 基金信息：
DOI：10.12434/j.issn.2097-2547.20240045
CLC： TQ028;X701Published：25 November 2024，
Received：02 February 2024，
Revised：19 March 2024，
- 稿件说明：
移动端阅览
闫瀚钊,王艳丽,李进锋.膜分离法捕集烟气中二氧化碳的研究进展[J].低碳化学与化工,2024,49(11):113-121.
YAN Hanzhao,WANG Yanli,LI Jinfeng.Research progress of carbon dioxide capture in flue gas by membrane separation method[J].Low-carbon Chemistry and Chemical Engineering,2024,49(11):113-121.
闫瀚钊,王艳丽,李进锋.膜分离法捕集烟气中二氧化碳的研究进展[J].低碳化学与化工,2024,49(11):113-121. DOI： 10.12434/j.issn.2097-2547.20240045.
YAN Hanzhao,WANG Yanli,LI Jinfeng.Research progress of carbon dioxide capture in flue gas by membrane separation method[J].Low-carbon Chemistry and Chemical Engineering,2024,49(11):113-121. DOI： 10.12434/j.issn.2097-2547.20240045.
摘要
膜分离法捕集烟气中二氧化碳（CO
2
）因具有污染小、操作简便和设备体积小等特点而受到了广泛关注。结合国内外膜分离法捕集烟气中CO
2
的研究进展，首先归纳了CO
2
分离膜材料的性能指标和开发情况；然后对比了不同形式膜组件的特点，分析了影响膜分离过程设计与优化的因素，总结了膜分离法大规模工业化的难点；最后对膜分离法捕集烟气中CO
2
技术未来的发展进行了展望（包括研发新型膜材料与配套制备工艺、开发新型膜组件，以及优化工艺流程并建设工业化示范装置）。
Abstract
The membrane separation method for capturing carbon dioxide (CO
2
) in flue gas has attracted wide attention because of its characteristics such as low pollution
simple operation and small equipment size. Based on the research progresses of CO
2
capture in flue gas by membrane separation method at home and abroad
the performance indexes and development of CO
2
separation membrane materials were firstly summarized. And then the characteristics of different membrane modules were compared and the factors affecting the design and optimization of membrane separation process were analyzed
and the difficulties of large-scale industrialization of membrane separation method were summarized. Finally
the future development of membrane separation technology for capturing CO
2
in flue gas was prospected
including research and development of new membrane materials and supporting preparation processes
development of new membrane modules
optimization of process flow and construction of industrial demonstration equipment.
关键词
膜分离法膜材料膜组件二氧化碳捕集烟气
Keywords
membrane separation methodmembrane materialsmembrane modulescarbon dioxide captureflue gas
references
徐南平, 赵静, 刘公平. “双碳”目标下膜技术发展的思考[J]. 化工进展, 2022, 41(3): 1091-1096.
XU N P, ZHAO J, LIU G P. Thinking of membrane technology development towards “carbon emission peak” and “carbon neutrality” targets [J]. Chemical Industry and Engineering Progress, 2022, 41(3): 1091-1096.
王丽娟, 张剑, 王雪松, 等. 中国电力行业二氧化碳排放达峰路径研究[J]. 环境科学研究, 2022, 35(2): 329-338.
WANG L J, ZHANG J, WANG X S, et al. Pathway of carbon emission peak in China’s electric power industry [J]. Research of Environmental Sciences, 2022, 35(2): 329-338.
谷俊男, 邢心语, 李磊, 等. 膜法脱除烟气中二氧化碳的工艺技术进展[J]. 现代化工, 2023, 43(S1): 81-84.
GU J N, XING X Y, LI L, et al. Technical advances in removal of carbon dioxide from flue gas by membrane method [J]. Modern Chemical Industry, 2023, 43(S1): 81-84.
陆诗建, 贡玉萍, 刘玲, 等. 有机胺CO2吸收技术研究现状与发展方向[J]. 洁净煤技术, 2022, 28(9): 44-54.
LU S J, GONG Y P, LIU L, et al. Research status and future development direction of CO2 absorption technology for organic amine [J]. Clean Coal Technology, 2022, 28(9): 44-54.
惠武卫, 姬存民, 赵合楠, 等. 低浓度CO2捕集技术研究进展[J]. 天然气化工—C1化学与化工, 2022, 47(4): 19-24.
HUI W W, JI C M, ZHAO H N, et al. Research progress of low concentration CO2 capture technology [J]. Natural Gas Chemical Industry, 2022, 47(4): 19-24.
罗双江, 白璐, 单玲珑, 等. 膜法二氧化碳分离技术研究进展及展望[J]. 中国电机工程学报, 2021, 41(4): 1209-1216.
LUO S J, BAI L, SHAN L L, et al. Research progress and prospect in membrane-mediated CO2 separation [J]. Proceedings of the CSEE, 2021, 41(4): 1209-1216.
GUO F, LI D S, DING R, et al.Constructing MOF-doped two-dimensional composite material ZIF-90@C3N4 mixed matrix membranes for CO2/N2 separation [J]. Separation and Purification Technology, 2022, 280: 119803.
HAN Y, HO W S W. Recent advances in polymeric facilitated transport membranes for carbon dioxide separation and hydrogen purification [J]. Journal of Polymer Science, 2020, 58(18): 2435-2449.
蔡博峰, 李琦, 张贤, 等. 中国二氧化碳捕集利用与封存（CCUS）年度报告（2021）—中国 CCUS 路径研究[R]. 北京: 生态环境部环境规划院, 中国科学院武汉岩土力学研究所, 中国21世纪议程管理中心, 2021.
CAI B F, LI Q, ZHANG X, et al. Annual report on carbon dioxide capture, utilization and storage (CCUS) in China (2021)—Study on CCUS path in China [R]. Beijing: Chinese Academy of Environmental Planning, Institute of Rock and Soil Mechanics of Chinese Academy of Sciences, Management Centre of Agendum in the 21st Century, 2021.
陈凤. 用于CO2分离的多层复合膜渗透选择性能强化研究[D]. 天津: 天津大学, 2020.
CHEN F. Enhancing separation performances of multi-layer composite membranes for CO2 separation [D]. Tianjin: Tianjin University, 2020.
TIWARI R R, SMITH Z P, LIN H, et al. Gas permeation in thin films of “high free-volume” glassy perfluoropolymers: Part I. Physical aging [J]. Polymer, 2014, 55(22): 5788-5800.
ZHANG J, XIAO P, LI G, et al. Effect of flue gas impurities on CO2 capture performance from flue gas at coal-fired power stations by vacuum swing adsorption [J]. Energy Procedia, 2009, 1(1): 1115-1122.
杨林军, 张琳, 孙莹. 燃煤净烟气中共存杂质对膜法捕集CO2影响现状[J]. 化工进展, 2019, 38(4): 1996-2002.
YANG L J, ZHANG L, SUN Y. Present situation of the effect of coexistent impurities in coal fired flue gas on CO2 capture by membranes [J]. Chemical Industry and Engineering Progress, 2019, 38(4): 1996-2002.
许家友. CO2膜分离过程的模拟及优化[D]. 天津: 天津大学, 2019.
XU J Y. Simulation and optimization of membrane processes for CO2 separation [D]. Tianjin: Tianjin University, 2019.
HAO A H, WAN X, LIU X F, et al. Inorganic microporous membranes for hydrogen separation: Challenges and solutions [J]. Nano Research Energy, 2022, 1: 9120013.
WANG B, WU T Y, YU M, et al. Highly ordered nanochannels in a nanosheet-directed thin zeolite nanofilm for precise and fast CO2 separation [J]. Small, 2020, 16(41): 2002836.
HAN Y, HO W W. Polymeric membranes for CO2 separation and capture [J]. Journal of Membrane Science, 2021, 628: 119244.
TOCCI E, GUGLIUZZA A, LORENZO L D, et al. Transport properties of a co-poly (amide-12-b-ethylene oxide) membrane: A comparative study between experimental and molecular modelling results [J]. Journal of Membrane Science, 2008, 323: 316-327.
CHEN H, XIAO Y, CHUNG T S. Synthesis and characterization of poly (ethylene oxide) containing copolyimides for hydrogen purification [J]. Polymer, 2010, 51(18): 4077-4086.
YAVE W, CAR A, PEINEMANN K V. Nanostructured membrane material designed for carbon dioxide separation [J]. Journal of Membrane Science, 2010, 350: 124-129.
WHITE L S, AMO K D, WU T, et al. Extended field trials of polaris sweep modules for carbon capture [J]. Journal of Membrane Science, 2017, 542: 217-225.
BRINKMANN T, LILLEPÄRG J, NOTZKE H, et al. Development of CO2 selective poly (ethylene oxide)-based membranes: From laboratory to pilot plant scale [J]. Engineering, 2017, 3(4): 485-493.
HAN Y, HO W W. Facilitated transport membranes for H2 purification from coal-derived syngas: A techno-economic analysis [J]. Journal of Membrane Science, 2021, 636: 119549.
CHEN T Y, DENG X, LIN L C, et al. New sterically hindered polyvinylamine-containing membranes for CO2 capture from flue gas [J]. Journal of Membrane Science, 2022, 645: 120195.
DONG S L, WANG Z, SHENG M L, et al. High-performance multi-layer composite membrane with enhanced interlayer compatibility and surface crosslinking for CO2 separation [J]. Journal of Membrane Science, 2020, 610: 118221.
WU H Y, LI Q H, SHENG M L, et al. Membrane technology for CO2 capture: From pilot-scale investigation of two-stage plant to actual system design [J]. Journal of Membrane Science, 2021, 624: 119137.
LI S, WANG Z, HE W, et al. Effects of minor SO2 on the transport properties of fixed carrier membranes for CO2 capture [J]. Industrial & Engineering Chemistry Research, 2014, 53(18): 7758-7767.
SANDRU M, KIM T J, CAPALA W, et al. Pilot scale testing of polymeric membranes for CO2 capture from coal fired power plants [J]. Energy Procedia, 2013, 37: 6473-6480.
SALIM W, VAKHARIA V, CHEN Y, et al. Fabrication and field testing of spiral-wound membrane modules for CO2 capture from flue gas [J]. Journal of Membrane Science, 2018, 556: 126-137.
MALEH M S, RAISI A. CO2-philic moderate selective layer mixed matrix membranes containing surface functionalized NaX towards highly-efficient CO2 capture [J]. RSC Advances, 2019, 9(27): 15542-15553.
YUAN J W, ZHU H P, SUN J J, et al. Novel ZIF-300 mixed-matrix membranes for efficient CO2 capture [J]. ACS Applied Materials & Interfaces, 2017, 9(44): 38575-38583.
GUO F, LI B Z, DING R, et al. A novel composite material UiO-66@HNT/Pebax mixed matrix membranes for enhanced CO2/N2 separation [J]. Membranes, 2021, 11(9): 693.
DUAN K, WANG J, ZHANG Y T, et al. Covalent organic frameworks (COFs) functionalized mixed matrix membrane for effective CO2/N2 separation [J]. Journal of Membrane Science, 2019, 572: 588-595.
REZAKAZEMI M, AMOOGHIN A E, MONTAZER-RAHMATI M M, et al. State-of-the-art membrane based CO2 separation using mixed matrix membranes (MMMs): An overview on current status and future directions [J]. Progress in Polymer Science, 2014, 39(5): 817-861.
李潘源. 分离CO2促进传递膜渗透选择性能强化研究[D]. 天津: 天津大学, 2016.
LI P Y. Enhancing separation performances of facilitated transport membranes for CO2 separation [D]. Tianjin: Tianjin University, 2016.
董松林. 高性能CO2分离多层复合膜的研制及放大[D]. 天津: 天津大学, 2020.
DONG S L. Development and scaling up of the high-performance multilayer composite membrane for CO2 separation [D]. Tianjin: Tianjin University, 2020.
霍文博. 超高渗透CO2分离膜中空纤维组件结构设计优化[D]. 大连: 大连理工大学, 2022.
HUO W B. Optimum design of hollow fiber modules’ structure forultra-high permeable CO2 separation membranes [D]. Dalian: Dalian University of Technology, 2022.
李博扬. 燃煤电厂烟气CO2膜法分离实验研究与工艺模拟优化[D]. 上海: 上海交通大学, 2020.
LI B Y. Experimental study and process simulation optimization of CO2 membrane separation of flue gas from coal-fired power plant [D]. Shanghai: Shanghai Jiao Tong University, 2020.
SCHWINGE J, NEAL P R, WILEY D E, et al. Spiral wound modules and spacers: Review and analysis [J]. Journal of Membrane Science, 2004, 242: 129-153.
HAN Y, SALIM W, CHEN KK, et al. Field trial of spiral-wound facilitated transport membrane module for CO2 capture from flue gas [J]. Journal of Membrane Science, 2019, 575: 242-251.
LIU B, QIAO Y, LI Q, et al. CO2 separation from CO2-EOR associated gas using hollower fiber membranes: A process design and simulation study [J]. Journal of Natural Gas Science and Engineering, 2022, 100: 104451.
ELHAMBAKHSH A, KESHAVARZ P. Sono-hollow fiber membrane contactors: A new approach for CO2 separation by physical/chemical absorbents [J]. Journal of Natural Gas Science and Engineering, 2022, 101: 104538.
孙亚伟, 谢美连, 刘庆岭, 等. 膜法分离燃煤电厂烟气中CO2的研究现状及进展[J]. 化工进展, 2017, 36(5): 1880-1889.
SUN Y W, XIE M L, LIU Q L, et al. Membrane-based carbon dioxide separation from flue gases of coal-fired power plant-current status and developments [J]. Chemical Industry and Engineering Progress, 2017, 36(5): 1880-1889.
YOO M J, LEE J H, YOO S Y, et al. Defect control for large-scale thin-film composite membrane and its bench-scale demonstration [J]. Journal of Membrane Science, 2018, 566: 374-382.
POHLMANN J, BRAM M, WILKNER K, et al. Pilot scale separation of CO2 from power plant flue gases by membrane technology [J]. International Journal of Greenhouse Gas Control, 2016, 53: 56-64.
HAN Y, HO W W. Moving beyond 90% carbon capture by highly selective membrane processes [J]. Membranes, 2022, 12(4): 399.
HAN Y, HO W W. Design of amine-containing CO2-selective membrane process for carbon capture from flue gas [J]. Industrial & Engineering Chemistry Research, 2019, 59(12): 5340-5350.
ZHANG X P, HE X Z, GUNDERSEN T. Post-combustion carbon capture with a gas separation membrane: Parametric study, capture cost, and exergy analysis [J]. Energy & Fuels, 2013, 27(8): 4137-4149.
张晨昕. 分离CO2膜传质机理及其过程模拟研究[D]. 天津: 天津大学, 2014.
ZHANG C X. Mass transport mechanism investigation and processsimulation for CO2 separation membrane [D]. Tianjin: Tianjin University, 2014.
XU J Y, WANG Z, QIAO Z H, et al. Post-combustion CO2 capture with membrane process: Practical membrane performance and appropriate pressure [J]. Journal of Membrane Science, 2019, 581: 195-213.
ZHAO L, RIENSCHE E, BLUM L, et al. Multi-stage gas separation membrane processes used in post-combustion capture: Energetic and economic analyses [J]. Journal of Membrane Science, 2010, 359: 160-172.
ARIAS A, MUSSATI M, MORES P, et al. Optimization of multi-stage membrane systems for CO2 capture from flue gas [J]. International Journal of Greenhouse Gas Control, 2016, 53: 371-390.
HAN Y, WU D Z, HO W W. Simultaneous effects of temperature and vacuum and feed pressures on facilitated transport membrane for CO2/N2 separation [J]. Journal of Membrane Science, 2019, 573: 476-484.
ZHAO L, RIENSCHE E, WEBER M, et al. Cascaded membrane processes for post-combustion CO2 capture [J]. Chemical Engineering & Technology, 2012, 35(3): 489-496.
GIORDANO L, ROIZARD D, BOUNACEUR R, et al. Evaluating the effects of CO2 capture benchmarks on efficiency and costs of membrane systems for post-combustion capture: A parametric simulation study [J]. International Journal of Greenhouse Gas Control, 2017, 63: 449-461.
YANG D X, WANG Z, WANG J X, et al. Potential of two-stage membrane system with recycle stream for CO2 capture from postcombustion gas [J]. Energy & fuels, 2009, 23(10): 4755-4762.
MERKEL T C, LIN H, WEI X, et al. Power plant post-combustion carbon dioxide capture: An opportunity for membranes [J]. Journal of Membrane Science, 2010, 359: 126-139.
0
Views
0
下载量
0
CNKI被引量
- L-PDFDownload
- XMLDownload
- Meta-XMLDownload
- BibTeXDownload
- EndnoteDownload
- RefMan Download
- NoteExpressDownload
- NoteFirstDownload
Publicity Resources
Related Articles
Related Author
Related Institution
- Postal code：610225
- Tel：028-85964717 Email：dthxyhg@swchem.com
- Technical support is provided by Beijing Founder electronics co., LTD 蜀ICP备12008600号-10
蜀公网安备51012202001533 - It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
- Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.
- Total Visits：138991 Visits Today：251
