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Research progress on degradation of alcoholamine solution for CO2 capture in flue gas
- Low-carbon Chemistry and Chemical Engineering Vol. 49, Issue 7, Pages: 13-22(2024)
- 作者机构：
1.中国矿业大学 碳中和研究院，江苏 徐州 221116
2.中国矿业大学 化工学院，江苏 徐州 221116
- 作者简介：
- 基金信息：
DOI：10.12434/j.issn.2097-2547.20230347
CLC： TQ413Published：25 July 2024，
Received：19 October 2023，
Revised：20 December 2023，
- 稿件说明：
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陆诗建,王风,刘玲等.烟道气CO2捕集用醇胺溶液降解研究进展[J].低碳化学与化工,2024,49(07):13-22.
LU Shijian,WANG Feng,LIU Ling,et al.Research progress on degradation of alcoholamine solution for CO2 capture in flue gas[J].Low-carbon Chemistry and Chemical Engineering,2024,49(07):13-22.
陆诗建,王风,刘玲等.烟道气CO2捕集用醇胺溶液降解研究进展[J].低碳化学与化工,2024,49(07):13-22. DOI： 10.12434/j.issn.2097-2547.20230347.
LU Shijian,WANG Feng,LIU Ling,et al.Research progress on degradation of alcoholamine solution for CO2 capture in flue gas[J].Low-carbon Chemistry and Chemical Engineering,2024,49(07):13-22. DOI： 10.12434/j.issn.2097-2547.20230347.
摘要
目前在多种CO
2
吸收捕集技术中，醇胺法是吸收量最大、经济效益最好和研究最广泛的方法。然而，醇胺法中使用的醇胺溶液吸收剂面临的降解问题是该方法的主要缺陷。针对醇胺溶液吸收剂的降解问题，首先综述了热降解和氧化降解的产物、机理和控制研究进展，然后综述了金属离子催化降解的降解机理、规律和控制研究进展，最后对醇胺溶液吸收剂的降解问题进行了总结，并对未来的抗降解研究方向进行了展望。
Abstract
At present
among the various CO
2
absorption and capture technologies
the alcoholamine method is the most widely studied method with the largest amount of absorption and the best economic benefit. However
the degradation of the alcoholamine solution absorbents used in the alcoholamine method is the main defect. In view of the problem of the degradation of alcoholamine solution absorbents
the research progress on products
mechanisms and controls of thermal degradation and oxidative degradation were first reviewed. And then the research progress on mechanisms
rules and controls of metal ion catalytic degradation were reviewed. Finally
the degradation problem of alcoholamine solution absorbents was summarized
and the future research direction of anti-degradation was prospected.
关键词
CO2捕集热降解氧化降解金属离子催化降解抗降解
Keywords
CO2 capturethermal degradationoxidative degradationmetal ion catalytic degradationanti-degradation
references
DAVIS J D. Thermal degradation of aqueous amines used for carbon dioxide capture [D]. Austin: The University of Texas at Austin, 2009.
DAVIS J, ROCHELLE G. Thermal degradation of monoethanolamine at stripper conditions [J]. Energy Procedia, 2009, 1(1): 327-333.
SAEED I M, ALI B S, JAN B M, et al. Thermal degradation of diethanolamine at stripper condition for CO2 capture: Product types and reaction mechanisms [J]. Chinese Journal of Chemical Engineering, 2019, 27(12): 2900-2908.
OGIDI M O, THOMPSON W A. Thermal degradation of morpholine in CO2 post-combustion capture [J]. Energy Procedia, 2017, 114: 1033-1037.
汪铁林, 延斯·克劳斯. 二氧化碳捕集中2-氨基-2-甲基-1-丙醇溶剂的热降解[J]. 武汉工程大学学报, 2013, 35(10): 1-5.
WANG T L, KLAUS J. Thermal degradation of 2-amino-2-methyl-1-propanol solvent for carbon dioxide capture [J]. Journal of Wuhan Institute of Technology, 2013, 35(10): 1-5.
LEPAUMIER H, PICQ D, CARRETTE P L. New amines for CO2 capture. Ⅱ. Mechanisms of amine degradation in the presence of CO2 [J]. Industrial & Engineering Chemistry Research, 2009, 48: 9061-9067.
FREEMAN S A, DAVIS J, ROCHELLE G T. Degradation of aqueous piperazine for carbon dioxide capture [J]. International Journal Greenhouse Gas Control, 2010, 4: 756-761.
MAMUM S, JACKOBSEN J P, SVENDSEN H F, et al. Experimental and modeling study of the solubility of carbon dioxide in aqueous 30 mass% 2-[(2-aminoethyl) amino] ethanol solution [J]. Industrial & Engineering Chemistry Research, 2006, 45: 2505-2512.
WANG T, JENS K J. Oxidative degradation of aqueous 2-amino-2-methyl-1-propanol solvent for CO2 capture [J]. Industrial & Engineering Chemistry Research, 2012, 51: 6529-6536.
EIDE H I, LEPAUMIER H, DA S E F, et al. A study of thermal degradation of different amines and their resulting degradation products [C]//IEAGHG. 1st Post Combustion Capture Conference, Abu Dhabi: Post Combustion Capture Conference, 2011: 668-670.
GARY T R. Thermal degradation of amines for CO2 capture [J]. Current Opinion in Chemical Engineering, 2012, 1: 183-190.
王利军. 天然气电厂基于MEA的烟气CO2捕集系统工艺研究[D]. 北京: 北京交通大学, 2014.
WANG L J. The study of CO2 capture system in natural gas power plant based on MEA [D]. Beijing: Beijing Jiaotong University, 2014.
KENNARD M L, MEISEN A. Mechanism and kinetics of diethanolamine degradation [J]. Industrial & Engineering Chemistry Fundamentals, 1985, 24(2): 129-140.
CHAKMA A, MEISEN A. Methyl diethanolamine degratio mechanism and kinetics [J]. Canadian Journal of Chemical Engineering, 2009, 75(5): 861-871.
YOON B, HWANG G S. First-principles assessment of anomalous thermal degradation of aqueous 2-amino-2-methy-l-propanol for CO2 capture [J]. Energy & Fuels, 2021, 35: 16705-16712.
黄宇辉. 用于烟气CO2化学吸收技术的混合胺吸收剂降解研究[D]. 杭州: 浙江大学, 2021.
HUANG Y H. Research on degradation of blended amine solution for CO2 chemical absorption technology [D]. Hangzhou: Zhejiang University, 2021.
陈思铭. 基于乙基乙醇胺的非水溶液法捕集二氧化碳[D]. 大连: 大连理工大学, 2018.
CHEN S M. Carbon dioxide capture by ethylethanolamine based nonaqueous solution [D]. Dalian: Dalian University of Technology, 2018.
储可弘. 乙基乙醇胺非水CO2吸收剂的降解性能研究[D]. 大连: 大连理工大学, 2020.
CHU K H. Study on the degradation performance of ethylethanolamine non-aqueous CO2 absorbent [D]. Dalian: Dalian University of Technology, 2020.
林海周, 裴爱国, 方梦祥. 燃煤电厂烟气二氧化碳胺法捕集工艺改进研究进展[J]. 化工进展, 2018, 37(12): 4874-4886.
LIN H Z, PEI A G, FANG M X. Progress of research on process modifications for amine solvent-based post combustion CO2 capture from coal-fired power plant [J]. Chemical Industry and Engineering Progress, 2018, 37(12): 4874-4886.
周姗, 王淑娟, ROCHELLE G T, 等. CO2捕集过程中有机胺热降解的实验研究[J]. 清华大学学报（自然科学版）, 2012, 52(1): 81-86.
ZHOU S, WANG S J, ROCHELLE G T, et al. Experiment research on amine thermal degradation during CO2 capture [J]. Journal of Tsinghua University (Science and Technology), 2012, 52(1): 81-86.
陈健, 罗伟亮, 李晗. 有机胺吸收二氧化碳的热力学和动力学研究进展[J]. 化工学报, 2014, 65(1): 12-21.
CHEN J, LUO W L, LI H. A review for research on thermodynamics and kinetics of carbon dioxide absorption with organic amines [J]. CIESC Journal, 2014, 65(1): 12-21.
DU Y, YUAN Y, ROCHELLE G T. Capacity and absorption rate of tertiary and hindered amines blended with piperazine for CO2 capture [J]. Chemical Engineering Science, 2016, 155: 397-404.
HINAI A A, HADRI N E, ZAHRA M A. Amine-blends screening and characterization for CO2 post-combustion capture [M]. Berlin: Springer International Publishing, 2017.
KIM Y E, PARK J H, YUN S H, et al. Carbon dioxide absorption using a phase transitional alkanolamine-alcohol mixture [J]. Journal of Industrial and Engineering Chemistry, 2014, 20(4): 1486-1492.
ZHANG W, JIN X, TU W, et al. A novel CO2 phase change absorbent: MEA/1-propanol/H2O [J]. Energy & Fuels, 2017, 31(4): 4273-4279.
PARKS C, ALBORZI E, AKRAM M, et al. DFT studies on thermal and oxidative degradation of monoethanolamine [J]. Industrial & Engineering Chemistry Research, 2020, 59: 15214-15225.
徐燕洁, 张威, 葛春亮, 等. 烷醇胺类两相吸收剂降解性能研究[J]. 中国电机工程学报, 2022, 42(4): 1347-1355.
XU Y J, ZHANG W, GE C L, et al. Degradation performance of alkanolamine based biphasic solvent [J]. Proceedings of the CSEE, 2022, 42(4): 1347-1355.
柴欢欢. 羟乙基乙二胺溶液捕集CO2过程中的降解及再生[D]. 大连: 大连理工大学, 2017.
CHAI H H. Study on degradation and reclamation of aqueous 2-(2-aminoethylamine-ethanol solution for CO2 capture [D]. Dalian: Dalian University of Technology, 2017.
WANG T L, JENS K. A study of oxidative degradation of AMP for post-combustion capture [J]. Energy Procedia, 2012, 23: 102-110.
VEGA F, CANO M, SANNA A, et al. Oxidative degradation of a novel AMP/AEP blend designed for CO2 capture based on partial oxy-combustion technology [J]. Chemical Engineering Journal, 2018, 350: 883-892.
WANG T L, JENS K. Towards an understanding of the oxidative degradation pathways of AMP for post-combustion CO2 capture [J]. International Journal of Greenhouse Gas Control, 2015, 37: 354-361.
WANG T L, JENS K. Oxidative degradation of aqueous PZ solution and AMP/PZ blends for post-combustion carbon dioxide capture [J]. International Journal of Greenhouse Gas Control, 2014, 24: 98-105.
李世霞. CO2吸收剂降解分析与实验研究[D]. 青岛: 中国石油大学（华东）, 2017.
LI S X. Experimental study and degradation analysis of CO2 absorbent [D]. Qingdao: China University of Petroleum (East China), 2017.
VOICE A K, ROCHELLE G T. Products and process variables in oxidation of monoethanolamine for CO2 capture [J]. International Journal of Greenhouse Gas Control, 2013, 12: 472-474.
孙晨辰, 王淑娟, 周珊. 乙醇胺热降解-氧化降解循环过程及SO2在其中的影响[J]. 环境科学学报, 2014, 34(1): 54-59.
SUN C C, WANG S J, ZHOU S. Monoethanolamine thermal-oxidative degradation in CO2 capture process and the effect of SO2 [J]. Acta Scientiae Circumstantiae, 2014, 34(1): 54-59.
GIFTJA A F, HARTONO A, GRIMSTVEDT A, et al. NMR study of oxidative degradation of MEA in presence of Fe2+ [J]. Energy Procedia, 2012, 23: 111-118.
SANNA A, VEGA F, NAVARRETE B, et al. Accelerated MEA degradation study in hybrid CO2 capture systems [J]. Energy Procedia, 2014, 63: 745-749.
REYNOLDS A J, VERHEYEN T V, ADELOJU S B, et al. Monoethanolamine degradation during pilot-scale post-combustion capture of CO2 from a Brown coal-fired power station [J]. Energy & Fuels, 2015, 29(11): 7441-7455.
王昊, 侯法柱, 尚航, 等. 乙醇胺法燃煤电厂CO2捕集系统尾气二次污染分析[J]. 化工进展, 2015, 34(9): 3495-3499.
WANG H, HOU F Z, SHANG H, et al. Analysis on exhaust secondary pollution of CO2 capture system using MEA in coal-fired power station [J]. Chemical Industry and Engineering Progress, 2015, 34(9): 3495-3499.
DA SILVA E F, LEPAUMIER H, GRIMSTVEDT A, et al. Understanding 2-ethanolamine degradation in postcombustion CO2 capture [J]. Industrial & Engineering Chemistry Research, 2012, 51(41): 13329-13338.
LEONARD G, VOICE A, TOYE D, et al. Influence of dissolved metals and oxidative degradation inhibitors on the oxidative and thermal degradation of monoethanolamine in postcombustion CO2 capture [J]. Industrial & Engineering Chemistry Research, 2014, 53(47): 18121-18129.
THOMPSON J G, BHATNAGAR S, COMBS M, et al. Pilot testing of a heat integrated 0.7 MWe CO2 capture system with two-stage air-stripping: Amine degradation and metal accumulation [J]. International Journal of Greenhouse Gas Control, 2017, 64: 23-33.
SUN C C, WANG S J, ZHOU S, et al. SO2 effect on monoethanolamine oxidative degradation in CO2 capture process [J]. International Journal of Greenhouse Gas Control, 2014, 23: 98-104.
LEPAUMIER H, GRIMSTVEDT A, VERNSTAD K, et al. Degradation of MMEA at absorber and stripper conditions [J]. Chemistry Engineering Science, 2011, 66(15): 3491-3498.
VEVELSTAD S J, GRIMSTVEDT A, KNUUTILA H, et al. Influence of experimental setup on amine degradation [J]. International Journal of Greenhouse Gas Control, 2014, 23: 156-167.
李红, 吉珂, 齐天勤机, 等. 复配醇胺溶液对CO2的吸收解吸性能及其降解性能[J]. 化工进展, 2022, 41(2): 1025-1035.
LI H, JI K, QI T Q J, et al. Properties of CO2 absorption-desorption based on alcohol amines solutions and their degradation [J]. Chemical Industry and Engineering Progress, 2022, 41(2): 1025-1035.
LEE I Y, KWAK N S, LEE J H, et al. Oxidative degradation of alkanolamines with inhibitors in CO2 capture process [J]. Energy Procedia, 2013, 37: 1830-1835.
LIU H B, OMKAR A N, ROCHELLE G T. Oxidative degradation of amine solvents for CO2 capture [J]. Energy Procedia, 2014, 63: 1546-1557.
CHEN D, MARTELL A E, MCMANUS D J C J O C. Studies on the mechanism of chelate degradation in iron-based, liquid redox H2S removal processes [J]. Canadian Journal of Chemistry, 1995, 73(2): 264-274.
CHI S, ROCHELLE G T. Oxidative degradation of monoethanolamine [J]. Industrial & Engineering Chemistry Research, 2002, 41(17): 4178-4186.
BEDELL S A. Oxidative degradation mechanisms for amines in flue gas capture [C]//GALE J, HERZOG H, BRAITSCH J. 9th International Conference on Greenhouse Gas Control Technologies, Washington DC: Greenhouse Gas Control Technologies, 2008: 771-778.
季芹芹, 刘建周, 张亚萍, 等. 有机胺吸收燃煤烟气CO2中抗氧化剂的作用机理研究[J]. 中国煤炭, 2012, 38(5): 113-117.
JI Q Q, LIU J Z, ZHANG Y P, et al. The mechanism of antioxidant on the absorption of CO2 from flue gas by organic amine [J]. China Coal, 2012, 38(5): 113-117.
UYANGA I J, IDEM R O. Studies of SO2- and O2-induced degradation of aqueous MEA during CO2 capture from power plant flue gas streams [J]. Industrial & Engineering Chemistry Research, 2007, 46(8): 2558-2566.
SEXTON A J, ROCHELLE G T. Catalysts and inhibitors for MEA oxidation [C]//GALE J, HERZOG H, BRAITSCH J. 9th International Conference on Greenhouse Gas Control Technologies, Washington DC: Greenhouse Gas Control Technologies, 2008: 1179-1185.
FYTIANOS G, GRIMSTVEDT A, KNUUTILA H, et al. Effect of MEA’s degradation products on corrosion at CO2 capture plants [C]//DIXON T, HERZOG H, TWINNING S. 12th International Conference on Greenhouse Gas Control Technologies, Washington DC: Greenhouse Gas Control Technologies, 2014: 1869-1875.
DE ORTE M R, SARMIENTO A M, DELVALLS T A, et al. Simulation of the potential effects of CO2 leakage from carbon capture and storage activities on the mobilization and speciation of metals [J]. Marine Pollution Bulletin, 2014, 86(1/2): 59-67.
CHOI W, PARK J, CHOI M. Cation effects of phosphate additives for enhancing the oxidative stability of amine-containing CO2 adsorbents [J]. Industrial & Engineering Chemistry Research, 2021, 60(17): 6147-6152.
张一智, 庾泽华, 杨超江, 等. 金属离子对MDEA + MEA复配胺液发泡影响研究[J]. 煤气与热力, 2019, 39(11): 25-29+45.
ZHANG Y Z, YU Z H, YANG C J, et al. Study on effect of metal ions on MDEA + MEA compound amine solution foaming [J]. Gas & Heat, 2019, 39(11): 25-29+45.
MAZARI S A, ALI B S, JAN B M, et al. Degradation study of piperazine, its blends and structural analogs for CO2 capture: A review [J]. International Journal of Greenhouse Gas Control, 2014, 31: 214-228.
CHANDAN P, RICHBURG L, BHATNAGAR S, et al. Impact of fly ash on monoethanolamine degradation during CO2 capture [J]. International Journal of Greenhouse Gas Control, 2014, 25: 102-108.
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