Research progress on metal corrosion of organic amine absorbents for CO<sub>2</sub> capture

ZHAO Xinglei; LI Lurui; YE Yi; SUN Wei; LV Jianhui

doi:10.12434/j.issn.2097-2547.20230294

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Research progress on metal corrosion of organic amine absorbents for CO₂ capture

- Research progress on metal corrosion of organic amine absorbents for CO₂ capture
- Vol. 49, Issue 7, Pages: 34-41(2024)
- 作者机构：
  
  1.中国石油集团安全环保技术研究院有限公司，北京 102206
  2.北京化工大学化学工程学院，北京 100029
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20230294
  CLC： TG174.42;X701
- Published：25 July 2024，
  
  Received：01 September 2023，
  
  Revised：23 October 2023，
- 稿件说明：
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赵兴雷,李璐蕊,叶舣等.CO₂捕集中有机胺吸收剂的金属腐蚀研究进展[J].低碳化学与化工,2024,49(07):34-41.

ZHAO Xinglei,LI Lurui,YE Yi,et al.Research progress on metal corrosion of organic amine absorbents for CO₂ capture[J].Low-carbon Chemistry and Chemical Engineering,2024,49(07):34-41.
赵兴雷,李璐蕊,叶舣等.CO₂捕集中有机胺吸收剂的金属腐蚀研究进展[J].低碳化学与化工,2024,49(07):34-41. DOI： 10.12434/j.issn.2097-2547.20230294.

ZHAO Xinglei,LI Lurui,YE Yi,et al.Research progress on metal corrosion of organic amine absorbents for CO₂ capture[J].Low-carbon Chemistry and Chemical Engineering,2024,49(07):34-41. DOI： 10.12434/j.issn.2097-2547.20230294.

摘要

通过溶剂法进行CO

捕集具有技术成熟、成本低的优点，被广泛使用。有机胺作为常用的吸收剂，具有吸收速率快、吸收容量大等优点，但是由于有机胺与CO

发生化学反应后，溶液具有腐蚀性，导致设备管线被腐蚀。综述了有机胺溶液的腐蚀机理，其中氢化胺离子、碳酸氢根离子以及水分子是主要的氧化剂，为腐蚀的发生提供条件。探讨了有机胺溶液的种类和浓度、CO

负载量、温度、O

含量以及降解产物等因素对溶液腐蚀性的影响，其中CO

负载量和温度是影响溶液腐蚀性的主要因素。归纳了采用无机和有机类缓蚀剂、调节溶液pH值和使用不锈钢材料等缓蚀方法，针对胺溶液的有机类缓蚀剂更值得关注。提出了未来缓蚀技术的发展方向，需开发新型缓蚀剂并与耐腐蚀材料相结合，可为深入研究及解决有机胺溶液的腐蚀问题提供参考。

Abstract

The solvent method for CO

capture has the advantages of mature technology and low cost

and is widely used. As commonly used absorbents

organic amines have the advantages of fast absorption rate and large absorption capacity. However

due to the chemical reaction betwe

en organic amines and CO

the solution becomes corrosive

resulting in corrosion of equipment pipelines. The corrosion mechanism of organic amine solutions was reviewed. Hydrogenated amine ions

bicarbonate ions and water molecules are the main oxidants

which provide conditions for the occurrence of corrosion. The effects of the types and concentrations of organic amine solution

loadings

temperatures

content and degradation products on the corrosiveness of the solution were discussed. Among them

loadings and temperatures are the main factors. The methods of using inorganic and organic corrosion inhibitors

adjusting the pH value of the solution and using stainless steel materials were summarized. The organic corrosion inhibitors for amine solutions are more worthy value of attention. The development direction of future corrosion inhibition technology was put forward. It is necessary to develop new corrosion inhibitors and combine them with corrosion resistant materials

which can provide a reference for further research and solving the corrosion problem of organic amine solutions.

关键词

CO2捕集有机胺吸收剂腐蚀机理缓蚀技术

Keywords

CO2 captureamine absorbentcorrosion mechanismcorrosion inhibition technology

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Research progress on metal corrosion of organic amine absorbents for CO2 capture

DOI：10.12434/j.issn.2097-2547.20230294

摘要

Abstract

关键词

Keywords

references

Research progress on metal corrosion of organic amine absorbents for CO₂ capture