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Research progress in characterization of metal-support interactions in catalysts
- Low-carbon Chemistry and Chemical Engineering Vol. 49, Issue 2, Pages: 1-9(2024)
- 作者机构：
中石化南京化工研究院有限公司，江苏 南京 210048
- 作者简介：
- 基金信息：
DOI：10.12434/j.issn.2097-2547.20230246
CLC： TQ426;O657.99Published：25 February 2024，
Received：16 July 2023，
Revised：06 September 2023，
- 稿件说明：
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彭洁,李曜,储政等.催化剂中金属与载体相互作用的表征研究进展[J].低碳化学与化工,2024,49(02):1-9.
PENG Jie,LI Yao,CHU Zheng,et al.Research progress in characterization of metal-support interactions in catalysts[J].Low-carbon Chemistry and Chemical Engineering,2024,49(02):1-9.
彭洁,李曜,储政等.催化剂中金属与载体相互作用的表征研究进展[J].低碳化学与化工,2024,49(02):1-9. DOI： 10.12434/j.issn.2097-2547.20230246.
PENG Jie,LI Yao,CHU Zheng,et al.Research progress in characterization of metal-support interactions in catalysts[J].Low-carbon Chemistry and Chemical Engineering,2024,49(02):1-9. DOI： 10.12434/j.issn.2097-2547.20230246.
摘要
负载型催化剂是低碳催化转化领域重要的一类催化剂，金属-载体相互作用广泛存在于负载型催化剂中。这种相互作用会显著影响催化剂的物理结构和电子结构，进而既可调控活性金属的催化活性和稳定性，又可达到金属-载体协同催化的效果，促进低碳烃类、醇类等的选择性催化转化。因此，研究金属-载体相互作用对催化剂优化和催化机理的深入探究都有十分重要的意义。基于非原位和原位表征技术，从静态性质和动态性质两个方面，综述了金属-载体相互作用的表征研究进展。通过非原位表征技术，如高分辨电镜、振动光谱、X射线谱学和电子顺磁共振谱等，可以表征金属与载体之间的物质输运、电荷偏移等情况；通过原位表征技术，如原位红外、原位X射线谱学和原位电子顺磁共振等，可以表征金属-载体相互作用的强弱变化、反应过程中催化剂的界面结构和组分变化以及动态电荷转移的过程等。
Abstract
Supported catalysts are crucial in low-carbon catalytic conversion
and metal-support interactions is widely present in supported catalysts. These interactions play a vital role in determining the physical and electronic structure of these catalysts
and not only regulate the catalytic activity and stability of active metals but also enable the synergistic catalysis effect between metals and supports
thus promoting the selective catalytic conversion of low-carbon hydrocarbons
alcohols and other compounds. Hence
understanding the metal-support interactions is essential for the optimization of catalysts and exploring catalytic mechanisms deeply. The research progress in characterization of metal-support interactions using ex situ and in situ techniques were discussed. Ex situ characterization techniques
such as high-resolution electron microscopy
vibrational spectroscopy
X-ray spectroscopy and electron par
amagnetic resonance spectroscopy can investigate mass transport and charge transfer between metals and supports. In situ characterization techniques
such as in situ infrared spectroscopy
in situ
X-ray spectroscopy and in situ
electron paramagnetic resonance can characterize the strength changes of metal-support interactions
changes of interface structures and compositions of catalysts during reactions
as well as the dynamic charge transfer processes.
关键词
金属-载体相互作用表征技术静态性质动态性质
Keywords
metal-support interactionscharacterization techniquesstatic propertiesdynamic properties
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