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Research progress of catalyst for levulinic acid hydrogenation to
γ ‑valerolactone- Low-carbon Chemistry and Chemical Engineering Vol. 49, Issue 2, Pages: 35-48(2024)
- 作者机构：
太原工业学院 化学与化工系，山西 太原 030008
- 作者简介：
- 基金信息：
DOI：10.12434/j.issn.2097-2547.20230103
CLC： TQ426;TQ203.2;O643.3Published：25 February 2024，
Received：23 March 2023，
Revised：22 May 2023，
- 稿件说明：
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高晓庆,郑洪岩,薛彦峰等.乙酰丙酸加氢制备γ-戊内酯催化剂研究进展[J].低碳化学与化工,2024,49(02):35-48.
GAO Xiaoqing,ZHENG Hongyan,XUE Yanfeng,et al.Research progress of catalyst for levulinic acid hydrogenation to γ‑valerolactone[J].Low-carbon Chemistry and Chemical Engineering,2024,49(02):35-48.
高晓庆,郑洪岩,薛彦峰等.乙酰丙酸加氢制备γ-戊内酯催化剂研究进展[J].低碳化学与化工,2024,49(02):35-48. DOI： 10.12434/j.issn.2097-2547.20230103.
GAO Xiaoqing,ZHENG Hongyan,XUE Yanfeng,et al.Research progress of catalyst for levulinic acid hydrogenation to γ‑valerolactone[J].Low-carbon Chemistry and Chemical Engineering,2024,49(02):35-48. DOI： 10.12434/j.issn.2097-2547.20230103.
摘要
催化转化碳中性且可再生的生物质制备液体燃料和精细化学品是实现双碳目标的主要途径之一，
γ
-戊内酯（GVL）可作为绿色溶剂并可用于合成高品位航空燃料。乙酰丙酸（LA）是重要的生物质平台化学品，经催化加氢可制备高附加值产品GVL。首先简要介绍了生物质组成，然后从所采用的均相催化剂、多相催化剂（Ru、Pd、Ni、Cu和双金属）等分类角度重点综述了LA加氢制备GVL的研究进展，详细讨论了催化剂结构性质、反应性能、稳定性、构效关系和反应机理。最后，对LA加氢制备GVL面临的挑战进行了分析，对未来的研究方向和发展趋势作了进一步展望，可为设计大规模商业应用的高活性耐酸性Ru基催化剂提供参考。
Abstract
Catalytic conversion of carbon-neutral and renewable biomass into liquid fuel and fine chemicals is one of main solutions to achieve carbon peaking and carbon neutrality goals
and
γ
-valerolactone (GVL) can be used as a green solvent and can be synthesized into high-grade aviation fuel. Levulinic acid (LA)
as an important biomass-derived platform chemical
can be catalytically hydrogenated into highly value-added GVL. Biomass composition was briefly introduced first
and then the research progress of LA hydrogenation to GVL was fully reviewed based on the perspective of homogeneous and heterogeneous catalysts (Ru
Pd
Ni
Cu and bimetal). The catalyst structural properties
reaction performance
stability
structure-performance correlation and re
action mechanism were discussed in detail. Finally
the major challenges were analysized
future prospects and development trend for LA hydrogenation to GVL were further prospected
which can provide a basis for designing high-activity and acid-resisting Ru-based catalysts with large-scale commercial applications.
关键词
生物质乙酰丙酸加氢γ-戊内酯催化剂
Keywords
biomasslevulinic acidhydrogenationγ-valerolactonecatalyst
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