Research progress of plasmon photocatalysts for CO2 conversion
- Low-carbon Chemistry and Chemical Engineering Vol. 48, Issue 6, Pages: 10-16(2023)
- 作者机构：
中海石油气电集团技术研发中心，北京 100028
- 作者简介：
- 基金信息：
DOI：10.12434/j.issn.2097-2547.20230063
CLC：
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戴若云,侯建国,王秀林等.等离激元光催化CO2转化催化剂研究进展[J].低碳化学与化工,2023,48(06):10-16.
DAI Ruoyun,HOU Jianguo,WANG Xiulin,et al.Research progress of plasmon photocatalysts for CO2 conversion[J].Low-carbon Chemistry and Chemical Engineering,2023,48(06):10-16.
戴若云,侯建国,王秀林等.等离激元光催化CO2转化催化剂研究进展[J].低碳化学与化工,2023,48(06):10-16. DOI： 10.12434/j.issn.2097-2547.20230063.
DAI Ruoyun,HOU Jianguo,WANG Xiulin,et al.Research progress of plasmon photocatalysts for CO2 conversion[J].Low-carbon Chemistry and Chemical Engineering,2023,48(06):10-16. DOI： 10.12434/j.issn.2097-2547.20230063.
摘要
CO,2,的资源化利用对实现碳循环意义重大。在众多CO,2,化学利用手段中，光催化CO,2,转化被认为是最为绿色和清洁的方案，但受限于较低的反应转化效率，尚未能取得大规模应用。等离激元光催化剂可利用表面等离激元共振现象，有效应对C==O键活化困难、光能利用不足和光生载流子寿命短等问题，提高CO,2,的转化效率和产物选择性。为了促进光催化CO,2,转化技术的商业化进程，等离激元光催化CO,2,转化催化剂的性能仍有待进一步改进。通过介绍等离激元光催化CO,2,转化的机理和梳理讨论近年等离激元光催化CO,2,转化催化剂的研究进展，总结了等离激元光催化CO,2,转化催化剂的设计思路与调控手段，强调了提高反应转化效率和降低催化剂成本的重要性，指出了未来该催化剂的研究和发展方向。
Abstract
The resource utilization of CO,2, is of great significance to the realization of carbon cycle. Photocatalytic CO,2, conversion is considered to be the greenest and cleanest method among various chemical CO,2, utilization methods, but it has not been applied on a large scale due to its low reaction conversion efficiency. The plasmon photocatalysts can take advantage of the surface plasmon resonance phenomenon to effectively deal with the problems such as the difficulty of C==O bond activation, the insufficient utilization of light energy and the short life of photo-generated carrier, so as to improve the CO,2, conversion efficiency and product selectivity. In order to promote the commercialization of photocatalytic CO,2, conversion technology, the performance of plasmon photocatalytic CO,2, conversion catalysts still needs to be further improved. Herein, by introducing the mechanism and discussing the recent research progress of plasmon photocatalytic CO,2, conversion catalysts, the design ideas and regulation methods were summarized, the importance of improving reaction conversion efficiency and reducing catalyst cost was emphasized, and the future research and development direction was pointed out.
关键词
CO2化学利用光催化剂等离激元现象
Keywords
chemical CO2 utilizationphotocatalystsplasmon phenomenon
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