ZIF-8/水相多孔吸附体系的构建及其CO<sub>2</sub>吸附性能研究

郑佳豪; 侯艺菲; 史利娟; 马倩; 易群

doi:10.12434/j.issn.2097-2547.20260069

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ZIF-8/水相多孔吸附体系的构建及其CO₂吸附性能研究

更新时间：2026-07-03

- ZIF-8/水相多孔吸附体系的构建及其CO₂吸附性能研究
- Construction of ZIF-8/aqueous phase porous adsorption system and its CO₂ capture performance study
- 低碳化学与化工 2026: 1-10.
- 作者机构：
  
  武汉工程大学化工与制药学院，湖北武汉 430205
- 作者简介：
  
  郑佳豪（2001—），硕士研究生，研究方向为碳捕集，E-mail：18834715561@163.com。
  马倩（1996—），博士，研究方向为碳一转化，E-mail：mm1171228@163.com；
  易群（1985—），博士，教授，研究方向为分离材料与过程强化，E-mail：yq20071001@163.com。
- 基金信息：
  
  国家自然科学基金(22272125;22478309);海南省重点研发计划(ZDYF2024GXJS005);山西浙大新材料与化工研究院技术开发项目(2022SX-TD015);武汉市科技局自然科学基金项目-探索计划（晨光计划）(2024040801020325);武汉工程大学研究生教育创新基金(CX2023039)
- DOI：10.12434/j.issn.2097-2547.20260069
  中图分类号： TQ028.1
- 收稿：2026-02-06，
  
  修回：2026-03-17，
  
  网络首发：2026-06-29，
- 稿件说明：
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郑佳豪,侯艺菲,史利娟等.ZIF-8/水相多孔吸附体系的构建及其CO₂吸附性能研究[J].低碳化学与化工,DOI:10.12434/j.issn.2097-2547.20260069.

ZHENG Jiahao,HOU Yifei,SHI Lijuan,et al.Construction of ZIF-8/aqueous phase porous adsorption system and its CO₂ capture performance study[J].Low-Carbon Chemistry and Chemical Engineering,DOI:10.12434/j.issn.2097-2547.20260069.
郑佳豪,侯艺菲,史利娟等.ZIF-8/水相多孔吸附体系的构建及其CO₂吸附性能研究[J].低碳化学与化工,DOI:10.12434/j.issn.2097-2547.20260069. DOI：

ZHENG Jiahao,HOU Yifei,SHI Lijuan,et al.Construction of ZIF-8/aqueous phase porous adsorption system and its CO₂ capture performance study[J].Low-Carbon Chemistry and Chemical Engineering,DOI:10.12434/j.issn.2097-2547.20260069. DOI：

摘要

作为实现碳减排的关键技术，CO

捕集、封存与利用正发挥着越来越重要的作用。然而，以传统多孔液体进行CO

捕集面临着依赖有机溶剂、成本高和环境不友好等问题。以ZIF-8为吸附质，筛选了稳定剂，调控了稳定剂与ZIF-8的质量比以及ZIF-8固含量（

(ZIF-8)/(

(ZIF-8) +

(水))），构建了ZIF-8/水相多孔吸附体系，并对其CO

吸附性能进行了测试。结果表明，聚乙烯醇（PVA）为优选稳定剂，在

(PVA):

(ZIF-8) = 1.0:0.5、ZIF-8固含量为5%时，体系具备良好的流动性与分散稳定性，在常温常压下（25 °C、101.3 kPa）的CO

吸附量为0.663 mmol/g。经过5次吸/脱附循环后，该体系的CO

吸附量仍保持在初始CO

吸附量的86%以上。本研究将为开发低成本、低能耗且环境友好的CO

吸附体系提供新思路。

Abstract

As a key technology for achieving carbon reduction

capture

storage

and utilization is playing an increasingly important role. However

capture using traditional porous liquids faces problems such as dependence on organic solvents

high cost and environmental unfriendliness. Using ZIF-8 as the adsorption medium

stabilizers were screened

and the mass ratios of stabilizers to ZIF-8 and the ZIF-8 solid contents (

(ZIF-8)/(

(ZIF-8) +

(water))) were adjusted. The ZIF-8/aqueous phase porous adsorption system was constructed

and its CO

adsorption performance was tested. The results show that polyvinyl alcohol (PVA) is the preferred stabilizer. When

(PVA):

(ZIF-8) = 1.0:0.5 and the ZIF-8 solid content of 5%

the system exhibits good fluidity and dispersion stability

achieving a CO

adsorption capacity of 0.663 mmol/g at ambient temperature and pressure (25 °C

101.3 kPa). After five adsorption/desorption cycles

the CO

adsorption capacity remains above 86% of the initial CO

adsorption capacity. This study will provide new ideas for developing low-cost

low-energy and environmentally friendly CO

capture systems.

关键词

Keywords

references

秦阿宁 , 吴晓燕 , 李娜娜 , 等 . 国际碳捕集、利用与封存（CCUS）技术发展战略与技术布局分析 [J ] . 科学观察 , 2022 , 17 ( 4 ): 29 - 37 .

QIN A N , WU X Y , LI N N , et al . Analysis on international strategy and technology development of carbon capture, utilization and storage (CCUS) [J ] . Science Focus , 2022 , 17 ( 4 ): 29 - 37 .

张贤 , 李凯 , 马乔 , 等 . 碳中和目标下 CCUS 技术发展定位与展望 [J ] . 中国人口·资源与环境 , 2021 , 31 ( 9 ): 29 - 33 .

ZHANG X , LI K , MA Q , et al . Orientation and prospect of CCUS development under carbon neutrality target [J ] . China population, Resources and Environment , 2021 , 31 ( 9 ): 29 - 33 .

REISS P S , LITTLE M A , SANTOLINI V , et al . Periphery-functionalized porous organic cages [J ] . Chemistry—A European Journal , 2016 , 22 ( 46 ): 16547 - 16553 .

BRIGGS M E , COOPER A I . A perspective on the synthesis, purification, and characterization of porous organic cages [J ] . Chemistry of Materials , 2017 , 29 ( 1 ): 149 - 157 .

KONG M , SONG L J , LIAO H P , et al . A review on development of post-combustion CO 2 capture technologies: Performance of carbon-based, zeolites and MOFs adsorbents [J ] . Fuel , 2024 , 371 : 132103 .

CAO C C , CHEN C X , WEI Z W , et al . Catalysis through dynamic spacer installation of multivariate functionalities in metal-organic frameworks [J ] . Journal of the American Chemical Society , 2019 , 141 ( 6 ): 2589 - 2593 .

CHEN C , HUANG Y , ZHU Y D , et al . Nonignorable influence of oxygen in hard carbon for sodium ion storage [J ] . ACS Sustainable Chemistry & Engineering , 2020 , 8 ( 3 ): 1497 - 1506 .

YOO Y S , WANG X L , XIE H M , et al . Unlocking liquid chemisorption in solid matrices: Immobilized deep eutectic solvent-ZIF-8 composites for next-generation CO 2 capture [J ] . Journal of Materials Chemistry A , 2026 , 14 ( 10 ): 5816 - 5830 .

JIE K C , ZHOU Y J , RYAN H P , et al . Engineering permanent porosity into liquids [J ] . Advanced Materials , 2021 , 33 ( 18 ): 2005745 .

KNEBEL A , BAVYKINA A , DATTA S J , et al . Solution processable metal-organic frameworks for mixed matrix membranes using porous liquids [J ] . Nature Materials , 2020 , 19 ( 12 ): 1346 - 1353 .

WANG D C , XIN Y Y , YAO D , et al . Shining light on porous liquids: From fundamentals to syntheses, applications and future challenges [J ] . Advanced Functional Materials , 2022 , 32 ( 1 ): 2104162 .

SIEGELMAN R L , KIM E J , LONG J R . Porous materials for carbon dioxide separations [J ] . Nature Materials , 2021 , 20 ( 8 ): 1060 - 1072 .

LIU H Y , FU Z B , HUANG Q S , et al . Experimental investigation on continuous reaction crystallizer for CO 2 capture by phase-change method [J ] . Chemical Engineering Journal , 2023 , 466 : 143345 .

KAR S , SEN R , GOEPPERT A , et al . Integrative CO 2 capture and hydrogenation to methanol with reusable catalyst and amine: Toward a carbon neutral methanol economy [J ] . Journal of the American Chemical Society , 2018 , 140 ( 5 ): 1580 - 1583 .

BENNETT T D , COUDERT F , JAMES S L , et al . The changing state of porous materials [J ] . Nature Materials , 2021 , 20 : 1179 - 1187 .

GIRI N , DEL PÓPOLO M G , MELAUGH G , et al . Liquids with permanent porosity [J ] . Nature , 2015 , 527 : 216 - 220 .

LI P P , CHEN H , SCHOTT J A , et al . Porous liquid zeolites: Hydrogen bonding-stabilized H-ZSM-5 in branched ionic liquids [J ] . Nanoscale , 2019 , 11 ( 4 ): 1515 - 1519 .

LI Y F , YUAN S L . The role of the nanoconfinement effect in the adsorption of carbon dioxide by porous liquids [J ] . American Chemical Society Sustainable Chemistry & Engineering , 2024 , 12 ( 28 ): 10455 - 10465 .

宇国佳 , 靳冬玉 , 周智勇 , 等 . 多孔液体的设计合成与应用研究进展 [J ] . 化工学报 , 2023 , 74 ( 1 ): 257 - 275 .

YU G J , JIN D Y , ZHOU Z Y , et al . Advances in the design, synthesis and application of porous liquids [J ] . CIESC Journal , 2023 , 74 ( 1 ): 257 - 275 .

COLLADO P , PIÑEIRO M M , PÉREZ-RODRÍGUEZ M . Molecular simulation of SO 2 separation and storage using a cryptophane-based porous liquid [J ] . International Journal of Molecular Sciences , 2024 , 25 ( 5 ): 2718 .

CAO P , XING D F , LV Q L , et al . Hybrid absorption-adsorption of CO 2 capture using type III porous liquids: Experimental and rigorous phase equilibrium models [J ] . ACS Sustainable Chemistry & Engineering , 2025 , 13 ( 30 ): 11823 - 11834 .

SAHU K P , SINGH S , SINGH A K , et al . Nanomaterials via ZIF-8: Preparations, catalytic and drug delivery applications [J ] . Chemical Engineering Journal , 2025 , 508 : 160663 .

SCHEJN A , BALAN L , FALK V , et al . Controlling ZIF-8 nano- and microcrystal formation and reactivity through zinc salt variations [J ] . CrystEngComm , 2014 , 16 ( 21 ): 4493 - 4500 .

LI Y , CHUNG T S , KULPRATHIPANJA S . Novel Ag + -zeolite/polymer mixed matrix membranes with a high CO 2 /CH 4 selectivity [J ] . American Institute of Chemical Engineers Journal , 2007 , 53 ( 3 ): 610 - 616 .

ZHANG J , LI X Q , SU F F , et al . ZIF-8 porous liquids with different sterically hindered solvents and porous guests for catalytic conversion of carbon dioxide [J ] . ACS Applied Materials & Interfaces , 2024 , 16 ( 45 ): 61957 - 61969 .

AVILA J , LEPRE L F , SANTINI C C , et al . High-Performance porous ionic liquids for low-pressure CO 2 capture [J ] . Angewandte Chemie International Edition , 2021 , 60 ( 23 ): 12876 - 12882 .

BAVYKINA A , CADIAU A , GASCON J . Porous liquids based on porous cages, metal organic frameworks and metal organic polyhedra [J ] . Coordination Chemistry Reviews , 2019 , 386 : 85 - 95 .

ERDOSY D P , WENNY M B , CHO J , et al . Microporous water with high gas solubilities [J ] . Nature , 2022 , 608 : 712 - 718 .

WU H N , LI Q C , ZHANG Y K , et al . One-step supramolecular fabrication of ionic liquid/ZIF-8 nanocomposites for low-energy CO 2 capture from flue gas and conversion [J ] . Fuel , 2022 , 322 : 124175 .

YANG J X , GAO D , ZHANG H , et al . Construction of ZIF-8 and amino functionalized porous ionic liquids for efficient CO 2 capture [J ] . Fuel , 2024 , 366 : 131351 .

YANG R , XIE H X , WU H J , et al . Cisplatin-encapsulated zeolitic imidazolate framework-8 nano-system enhanced radiosensitivity of non-small cell lung cancer [J ] . Scientific Reports , 2025 , 15 : 42758 .

HE S F , CHEN L H , CUI J , et al . General way to construct micro- and mesoporous metal-organic framework-based porous liquids [J ] . Journal of the American Chemical Society , 2019 , 141 ( 50 ): 19708 - 19714 .

VEDRTNAM A , SINGH A , SINGH A , et al . High-performance carbon dioxide adsorption with zeolitic imidazolate framework-8-based cellulose air filters [J ] . Applied Sciences , 2024 , 14 ( 23 ): 11019 .

JIA Z Q , WU G R , WU D Z , et al . Preparation of ultra-stable ZIF-8 dispersions in water and ethanol [J ] . Journal of Porous Materials , 2017 , 24 : 1655 - 1660 .

MIYAZAKI T , MIYATA N , YOSHIDA T , et al . Detailed structural study on the poly(vinyl alcohol) adsorption layers on a Si substrate with solvent vapor-induced swelling [J ] . Langmuir , 2020 , 36 ( 13 ): 3415 - 3424 .

JIN G , WANG H J , ZHANG K X , et al . ZIF-8 based porous liquids with high hydrothermal stability for carbon capture [J ] . Materials Today Communications , 2023 , 36 : 106820 .

AVILA J , ČERVINKA C , DUGAS P Y , et al . Porous ionic liquids: Structure, stability, and gas absorption mechanisms [J ] . Advanced Materials Interfaces , 2021 , 8 ( 9 ): 2001982 .

LAI Y Y , YANG J S , CAI L K , et al . Precise modulation of surface layer dynamics for tunable flowability and gas absorption properties of molecular porous liquids [J ] . Advanced Functional Materials , 2023 , 33 ( 12 ): 2210122 .

LIU S J , LIU J D , HOU X D , et al . Porous liquid: A stable ZIF-8 colloid in ionic liquid with permanent porosity [J ] . Langmuir , 2018 , 34 ( 12 ): 3654 - 3660 .

WANG D C , YING Y P , XIN Y Y , et al . Porous liquids open new horizons: Synthesis, applications, and prospects [J ] . Accounts of Materials Research , 2023 , 4 ( 10 ): 854 - 866 .

LI X Q , WANG D C , NING H L , et al . An electrostatic repulsion strategy construct ZIFs based liquids with permanent porosity for efficient CO 2 capture [J ] . Separation and Purification Technology , 2021 , 276 : 119305 .

XIN Y Y , WANG D C , YAO D D , et al . Post-synthetic modification of UiO-66-OH toward porous liquids for CO 2 capture [J ] . New Journal of Chemistry , 2022 , 46 ( 5 ): 2189 - 2197 .

王茜茜 , 孙德贇 , 高艳安 , 等 . 低黏度多孔低共熔溶剂ZIF-8-PDES的CO 2 捕集性能 [J ] . 低碳化学与化工 , 2025 , 50 ( 12 ): 95 - 103 .

WANG X X , SUN D Y , GAO Y A , et al . CO 2 capture performance of low-viscosity porous metathetical solvent ZIF-8-PDES [J ] . Low-Carbon Chemistry and Chemical Engineering , 2025 , 50 ( 12 ): 95 - 103 .

CHEN Z A , ZOU L , CAO R , et al . Porous covalent organic framework liquid for boosting CO 2 adsorption and catalysis via dynamically expanding effect [J ] . National Science Review , 2025 , 12 ( 3 ): nwaf032 .

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ZIF-8/水相多孔吸附体系的构建及其CO2吸附性能研究

Construction of ZIF-8/aqueous phase porous adsorption system and its CO2 capture performance study

DOI：10.12434/j.issn.2097-2547.20260069

摘要

Abstract

关键词

Keywords

references

ZIF-8/水相多孔吸附体系的构建及其CO₂吸附性能研究

Construction of ZIF-8/aqueous phase porous adsorption system and its CO₂ capture performance study