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北京石油化工学院 新材料与化工学院 燃料清洁化及高效催化减排技术北京市重点实验室,北京 102600
孙 浩(1999—),硕士研究生,研究方向为费托合成催化剂,E-mail:sh19992024@163.com。
罗明生(1963—),博士,教授,研究方向为工业催化,E-mail:luoms9297@163.com。
收稿:2026-01-07,
修回:2026-03-05,
网络首发:2026-07-06,
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孙浩,罗明生,刘清龙.铁基费托合成催化剂中氧化物与碳基载体研究进展[J].低碳化学与化工,
SUN Hao,LUO Mingsheng,LIU Qinglong.Research progress on oxide and carbon-based supports in iron-based Fischer-Tropsch synthesis catalysts[J].Low-Carbon Chemistry and Chemical Engineering,
孙浩,罗明生,刘清龙.铁基费托合成催化剂中氧化物与碳基载体研究进展[J].低碳化学与化工, DOI:10.12434/j.issn.2097-2547.20260009.
SUN Hao,LUO Mingsheng,LIU Qinglong.Research progress on oxide and carbon-based supports in iron-based Fischer-Tropsch synthesis catalysts[J].Low-Carbon Chemistry and Chemical Engineering, DOI:10.12434/j.issn.2097-2547.20260009.
随着生物质航空煤油市场的蓬勃发展,费托合成技术再次成为研究热点。当前工业应用的共沉淀型铁基催化剂存在机械强度不足的缺点,易引发催化剂结构塌陷、反应器堵塞等问题。考虑到负载型铁基催化剂在费托合成技术中的应用潜力,对近年来负载型铁基费托合成催化剂载体的研究成果进行了综述。首先概述了氧化物和碳基载体的研究现状,然后从结构特性、改性策略和催化机制等方面对两种载体进行了分析,最后对未来负载型铁基催化剂载体的发展进行了展望。
With the booming market of biomass-derived aviation kerosene
Fischer-Tropsch (FTS) technology has once again become a research hotspot. Coprecipitated iron-based catalysts currently used in industrial applications suffer from poor mechanical strength
which easily leads to structural collapse of catalysts and reactor clogging. In view of the promising application potential of supported iron-based catalysts in FTS
recent research progress on supports for supported iron-based FTS catalysts was reviewed. Firstly
the research status of oxide and carbon-based supports was summarized
then the two types of supports from the perspectives of structural characteristics
modification strategies and catalytic mechanisms were analyzed. Finally
the future developments of supports for supported iron-based catalysts were prospected.
任志安 , 章海霞 . “双碳”目标下能源结构绿色低碳转型: 效果评估与空间溢出 [J ] . 生态经济 , 2025 , 41 ( 12 ): 61 - 67+76 .
REN Z A , ZHANG H X . Green and low-carbon transition of energy structure under the dual carbon goals: Effectiveness assessment and spatial spillover effects [J ] . Ecological Economy , 2025 , 41 ( 12 ): 61 - 67+76 .
欧阳泽华 . “十五五”时期我国绿色能源格局展望和发展要点 [J ] . 团结 , 2025 , ( 4 ): 22 - 25 .
OUYANG Z H . Outlook and development priorities of China’s green energy pattern during the “14th Five-Year Plan” period [J ] . Unity , 2025 , ( 4 ): 22 - 25 .
WEI J , GE Q G , YAO R W , et al . Directly converting CO 2 into a gasoline fuel [J ] . Nature Communications , 2017 , 8 ( 1 ): 15174 .
张曈 , 何富贵 , 孔祥斌 , 等 . 碱助剂改性铁基费托合成反应催化剂的研究进展 [J ] . 低碳化学与化工 , 2024 , 49 ( 12 ): 1 - 11 .
ZHANG T , HE F G , KONG X B , et al . Research progress on alkali promoters modified iron-based catalysts for Fischer-Tropsch synthesis reaction [J ] . Low-Carbon Chemistry and Chemical Engineering , 2024 , 49 ( 12 ): 1 - 11 .
AMIN M , USMAN M , KELLA T , et al . Issues and challenges of fischer-tropsch synthesis catalysts [J ] . Frontiers in Chemistry , 2024 , 12 : 1462503 .
DI Z X , FENG X L , YANG Z , et al . Effect of iron precursor on catalytic performance of precipitated iron catalyst for fischer-tropsch synthesis reaction [J ] . Catalysis Letters , 2020 , 150 ( 9 ): 2640 - 2647 .
陈超 , 锁小明 , 李正甲 , 等 . 助剂对铁基费托合成催化剂性能影响的研究进展 [J ] . 高校化学工程学报 , 2025 , 39 ( 5 ): 799 - 806 .
CHEN C , SUO X M , LI Z J , et al . Progress in the influence of promoters on the performances of the Fe-based Fischer-Tropsch synthesis catalysts [J ] . Journal of Chemical Engineering of Chinese Universities , 2025 , 39 ( 5 ): 799 - 806 .
CHAI J C , JIANG J D , GONG Y , et al . Recent mechanistic understanding of Fischer-Tropsch synthesis on Fe-carbide [J ] . Catalysts , 2023 , 13 ( 7 ): 1052 .
CHEN Y , HE H H , LI Y F , et al . Study on the regulation of Fischer-Tropsch synthesis catalytic performance by mixing oxides with iron-based catalysts [J ] . Journal of Fuel Chemistry and Technology , 2025 , 53 ( 8 ): 1212 - 1222 .
HAN X X , HUANG S Y , WEI C Y , et al . Tailoring surface and penetrating carbon in Fe-based catalysts to balance the activity and stability of Fischer-Tropsch synthesis [J ] . ACS Catalysis , 2024 , 14 ( 24 ): 18354 - 18364 .
CAI Y , WANG M L , ZHAO S , et al . Trace-level halogen blocks CO 2 emission in Fischer-Tropsch synthesis for olefins production [J ] . Science , 2025 , 516 : 516 - 520 .
MUNIRATHINAM R , MINH P D , NZIHOU A . Effect of the support and its surface modifications in cobalt-based Fischer-Tropsch synthesis [J ] . Industrial & Engineering Chemistry Research , 2018 , 57 ( 48 ): 16137 - 16161 .
VAN ETTEN M P C , DE LAAT M E , HENSEN E J M , et al . Unraveling the role of metal-support interactions on the structure sensitivity of Fischer-Tropsch synthesis [J ] . The Journal of Physical Chemistry C , 2023 , 127 ( 31 ): 15148 - 15156 .
ZHANG W Z , LIN H Y , AN Y L , et al . Strong metal-support interactions: From characterization, manipulation to application in fischer-tropsch synthesis and atmospheric CO 2 hydrogenation [J ] . ChemCatChem , 2024 , 16 ( 15 ): 202301623 .
LIU S Y , REN J , ZHANG H K , et al . Synthesis, characterization and isomerization performance of micro/mesoporous materials based on H-ZSM-22 zeolite [J ] . Journal of Catalysis , 2016 , 335 : 11 - 23 .
WANG T A , HU J Y , OUYANG R , et al . Nature of metal-support interaction for metal catalysts on oxide supports [J ] . Science , 2024 , 386 ( 6706 ): 915 - 920 .
FAN X , LI D H , SHU Y X , et al . Confinement effect and application in catalytic oxidation-reduction reaction of confined single-atom catalysts [J ] . ACS Catalysis , 2024 , 14 ( 19 ): 12991 - 13014 .
HE R S , WANG Y , LI M , et al . Tailoring the CO 2 hydrogenation performance of Fe-based catalyst via unique confinement effect of the carbon shell [J ] . Chemistry—A European Journal , 2023 , 29 ( 41 ): e202301918 .
LUO G Y , LI Z S , LIU Q Y , et al . Enhanced synthesis of C 2+ alcohols from syngas over a Co-Co 2 C catalyst supported on mesoporous carbon-silica composites [J ] . Chemical Engineering Journal , 2023 , 475 : 146206 .
ZHAO M , ZHAO Z A , LYU Y , et al . Co-Al spinel as an efficient support for Co-based Fischer-Tropsch catalyst: The effect of metal-support interaction [J ] . Industrial & Engineering Chemistry Research , 2021 , 60 ( 8 ): 2849 - 2860 .
HE L X , GUAN C , BULUSHEV D A , et al . Regulation of metal-support interaction in single-atom catalysis [J ] . Small , 2024 , 24 ( 48 ): 2410976 .
HORÁČEK J . Fischer-Tropsch synthesis, the effect of promoters, catalyst support, and reaction conditions selection [J ] . Monatshefte für Chemie—Chemical Monthly , 2020 , 151 ( 5 ): 649 - 675 .
付长亮 , 姜巧娟 , 王焕锋 , 等 . F-T合成催化剂Ce-Co/SiO 2 的性能研究 [J ] . 天然气化工—C1化学与化工 , 2018 , 43 ( 4 ): 13 - 16+87 .
FU C L , JIANG Q J , WANG H F , et al . Performance study on Ce-Co/SiO 2 catalyst for F-T synthesis [J ] . Natural Gas Chemical Industry , 2018 , 43 ( 4 ): 13 - 16+87 .
HEIKKINEN N , DHAMO D , UOTILA I , et al . Production of C 2 -C 4 olefins with Fischer‐Tropsch synthesis: The effect of Cu promoter loading on an Fe-Cu-K/SiO 2 catalyst [J ] . ChemCatChem , 2024 , 16 ( 19 ): e202400560 .
YAGHOOBPOUR E , ZAMANI Y , ZARRINPASHNE S , et al . Fischer-Tropsch synthesis: Effect of silica on hydrocarbon production over cobalt-based catalysts [J ] . Chemical Papers , 2019 , 73 ( 1 ): 205 - 214 .
YUN M Y , CHEN T , ZHAO N , et al . Enhanced Fischer-Tropsch synthesis performance on Co@SiO 2 catalyst with core-shell structure [J ] . Molecular Catalysis , 2025 , 572 : 114749 .
宋茜茜 . 利用均一孔结构铁基催化剂研究载体表面性质对费托合成性能的影响 [D ] . 福州 : 福建师范大学 , 2020 .
SONG Q Q . Effects of support surface properties on Fischer-Tropsch synthesis performance over the uniform pore-structure iron-based catalysts [D ] . Fuzhou : FuJian Normal University , 2020 .
LIU J H , LI R Z , LI Y , et al . Crystal phase-mediated Ni-TiO 2 interface engineering for photothermocatalytic Fischer-Tropsch synthesis of multi-carbon hydrocarbons [J ] . ACS Catalysis , 2025 , 15 ( 22 ): 19527 - 19536 .
梁昊 , 张书南 , 张若楠 , 等 . FeTi强相互作用促进CO 2 高效加氢制低碳烯烃(英文) [J ] . 催化学报 , 2025 , 71 ( 4 ): 146 - 157 .
LIANG H , ZHANG S N , ZHANG R N , et al . Strong interact ion between Fe and Ti compositions for effective CO 2 hydrogenation to light olefins [J ] . Chinese Journal of Catalysis , 2025 , 71 ( 4 ): 146 - 157 .
ZHAO D J , LYU S S , CHENG Q P , et al . Highly efficient assembly-line production of long-chain hydrocarbons via Fischer-Tropsch synthesis over ru/TiO 2 catalysts [J ] . Journal of the American Chemical Society , 2025 , 147 ( 24 ): 20493 - 20503 .
YU H L , WANG C Q , XIN X , et al . Engineering ZrO 2 -Ru interface to boost fischer-tropsch synthesis to olefins [J ] . Nature Communications , 2024 , 15 ( 1 ): 5143 .
李金林 , 谢卫 . 二氧化锆助剂对碳纳米管负载钴基催化剂费-托合成催化性能的影响 [J ] . 中南民族大学学报(自然科学版) , 2011 , 30 ( 2 ): 1 - 5 .
LI J L , XIE W . Effect of ZrO 2 promoter on the performance of carbon nanotube supported cobalt catalysts in Fischer-Tropsch synthesis [J ] . Journal of South-Central University for Nationalities (Natural Science Edition) , 2011 , 30 ( 2 ): 1 - 5 .
朱杰 , 李文慧 , 刘邦荐 , 等 . 高比表面积二氧化锆的合成及其催化应用 [J ] . 化工进展 , 2019 , 38 ( 1 ): 315 - 323 .
ZHU J , LI W H , LIU B J , et al . Preparation of high-surface-area ZrO 2 and its application in catalysis [J ] . Chemical Industry and Engineering Progress , 2019 , 38 ( 1 ): 315 - 323 .
PAKDEL M G , ATASHI H , MIRZAEI A A , et al . Deactivation model for an industrial γ ‐alumina supported iron catalyst in the Fischer-Tropsch synthesis [J ] . Chemistry Select , 2019 , 4 ( 7 ): 2064 - 2069 .
VOSOUGHI V , BADOGA S , DALAI A K , et al . Modification of mesoporous alumina as a support for cobalt-based catalyst in Fischer-Tropsch synthesis [J ] . Fuel Processing Technology , 2017 , 162 : 55 - 65 .
MINNERMANN M , NEUMANN B , ZIELASEK V , et al . Alumina-promoted cobalt and iron xerogels as catalyst for the Fischer-Tropsch synthesis [J ] . Catalysis Science & Technology , 2013 , 3 ( 12 ): 3256 .
ARSALANFAR M , NOURI A , ABDOUSS M , et al . Fischer-Tropsch synthesis over the Co-Ni/Al 2 O 3 nanocatalyst: Influence of process variables, modeling and optimization using response surface methodology [J ] . Journal of Chemical Technology & Biotechnology , 2024 , 99 ( 1 ): 133 - 148 .
DOLSIRIRITTIGUL N , NUMPILAI T , FAUNGNAWAKIJ K , et al . Exploring the impact of cobalt and H 2 to CO ratios on catalytic performance of FeKAl and FeCoKAl catalysts in CO hydrogenation to light olefins [J ] . Fuel , 2025 , 383 : 133833 .
YANG Z , LUO M S , LIU Q L , et al . Effect of alkali metals on CoMo 2 C/Al 2 O 3 catalysts for syngas to higher alcohols [J ] . ChemCatChem , 2025 , 17 ( 8 ): e202402143 .
CHEN Y , HE H H , LI Y F , et al . Study on the regulation of Fischer-Tropsch synthesis catalytic performance by mixing oxides with iron-based catalysts [J ] . Journal of Fuel Chemistry and Technology , 2025 , 53 ( 8 ): 1212 - 1222 .
LU Q C , LI C X , LI J , et al . Morphology-dependent catalytic activity of ZnFe 2 O 4 spinel toward light olefins from Fischer-Tropsch synthesis [J ] . ChemCatChem , 2025 , 17 ( 3 ): e202401600 .
HAN X X , HUANG S Y , WEI C Y , et al . Tailoring surface and penetrating carbon in Fe-based catalysts to balance the activity and stability of Fischer-Tropsch synthesis [J ] . ACS Catalysis , 2024 , 14 ( 24 ): 18354 - 18364 .
CHENG Q P , LIU Y H , LYU S S , et al . Manipulating metal-support interactions of metal catalysts for Fischer-Tropsch synthesis [J ] . Chinese Journal of Chemical Engineering , 2021 , 35 : 220 - 230 .
LI Y , LI R Z , LI Z H , et al . Effect of support on catalytic performance of photothermal Fischer-Tropsch synthesis to produce lower olefins over Fe 5 C 2 -based catalysts [J ] . Chemical Research in Chinese Universities , 2020 , 36 ( 6 ): 1006 - 1012 .
PAN X L , JIAO F , MIAO D Y , et al . Oxide-zeolite-based composite catalyst concept that enables syngas chemistry beyond Fischer-Tropsch synthesis [J ] . Chemical Reviews , 2021 , 121 ( 11 ): 6588 - 6609 .
ZHANG Y C , HU R G , SU H Q , et al . ZSM‐5‐promoted Co-based light-assisted thermocatalytic Fischer-Tropsch synthesis catalyst for production of liquid fuel [J ] . Energy Technology , 2024 , 12 ( 6 ): 2301280 .
JIAO F , LI J J , PAN X L , et al . Selective conversion of syngas to light olefins [J ] . Science , 2016 , 351 ( 6277 ): 1065 - 1068 .
CHENG K , GU B , LIU X L , et al . Direct and highly selective conversion of synthesis gas into lower olefins: Design of a bifunctional catalyst combining methanol synthesis and carbon—carbon coupling [J ] . Angewandte Chemie International Edition , 2016 , 55 ( 15 ): 4725 - 4728 .
ZHANG P , MENG F H , LI X J , et al . Excellent selectivity for direct conversion of syngas to light olefins over a MnGa oxide and SAPO-34 bifunctional catalyst [J ] . Catalysis Science & Technology , 2019 , 9 ( 20 ): 5577 - 5581 .
SU J J , WANG D , WANG Y D , et al . Direct conversion of syngas into light olefins over zirconium-doped indium (III) oxide and SAPO-34 bifunctional catalysts: design of oxide component and construction of reaction network [J ] . ChemCatChem , 2018 , 10 ( 8 ): 1536 - 1541 .
WANG S , WANG P F , SHI D Z , et al . Direct conversion of syngas into light olefins with low CO 2 emission [J ] . ACS Catalysis , 2020 , 10 ( 3 ): 2046 - 2059 .
RAVEENDRA G , LI C M , CHENG Y , et al . Direct transformation of syngas to lower olefins synthesis over hybrid ZnAl 2 O 3 /SAPO-34 catalysts [J ] . New Journal of Chemistry , 2018 , 42 ( 7 ): 4419 - 4431 .
LIU X L , WANG M H , YIN H R , et al . Tandem catalysis for hydrogenation of CO and CO 2 to lower olefins with bifunctional catalysts composed of spinel oxide and SAPO-34 [J ] . ACS Catalysis , 2020 , 10 ( 14 ): 8303 - 8314 .
XU M , HE S , CHEN H , et al . TiO 2 - x -modified Ni nanocatalyst with tunable metal-support interaction for water-gas shift reaction [J ] . ACS Catalysis , 2017 , 7 ( 10 ): 7600 - 7609 .
VAN DEELEN T W , HERNÁNDEZ MEJÍA C , DE JONG K P . Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity [J ] . Nature Catalysis , 2019 , 2 ( 11 ): 887 - 900 .
TIAN Z P , WANG C G , SI Z , et al . Enhancement of light olefins selectivity over N-doped Fischer-Tropsch synthesis catalyst supported on activated carbon pretreated with KMnO 4 [J ] . Catalysts , 2019 , 9 ( 6 ): 505 .
CHERNAVSKII P A , PANKINA G V , KAZANTSEV R V , et al . Potassium as a structural promoter for an iron/activated carbon catalyst: Unusual effect of component deposition order on magnetite particle size and catalytic behavior in Fischer-Tropsch synthesis [J ] . ChemCatChem , 2018 , 10 ( 6 ): 1313 - 1320 .
TIAN Z P , WANG C G , SI Z , et al . Fischer-Trop sch synthesis to light olefins over iron-based catalysts supported on KMnO 4 modified activated carbon by a facile method [J ] . Applied Catalysis A: General , 2017 , 541 : 50 - 59 .
ASAMI K , KOMIYAMA K , YOSHIDA K , et al . Synthesis of lower olefins from synthesis gas over active carbon-supported iron catalyst [J ] . Catalysis Today , 2018 , 303 : 117 - 122 .
PAN X , BAO X . The effects of confinement inside carbon nanotubes on catalysis [J ] . Accounts of Chemical Research , 2011 , 44 ( 8 ): 553 - 562 .
GU B , ORDOMSKY V V , BAHRI M , et al . Effects of the promotion with bismuth and lead on direct synthesis of light olefins from syngas over carbon nanotube supported iron catalysts [J ] . Applied Catalysis B: Environmental , 2018 , 234 : 153 - 166 .
GU B , HE S , PERON D V , et al . Synergy of nanoconfinement and promotion in the design of efficient supported iron catalysts for direct olefin synthesis from syngas [J ] . Journal of Catalysis , 2019 , 376 : 1 - 16 .
GU B , PERON D V , BARRIOS A J , et al . Mobility and versatility of the liquid bismuth promoter in the working iron catalysts for light olefin synthesis from syngas [J ] . Chemical Science , 2020 , 11 ( 23 ): 6167 - 6182 .
TORRES G H M , BITTER J H , KHARE C B , et al . Supported iron nanoparticles as catalysts for sustainable production of lower olefins [J ] . Science , 2012 , 335 ( 6070 ): 835 - 838 .
DÍAZ J A , MARTÍNEZ-FERNÁNDEZ M , ROMERO A , et al . Synthesis of carbon nanofibers supported cobalt catalysts for Fischer-Tropsch process [J ] . Fuel , 2013 , 111 : 422 - 429 .
HOLMEN A , VENVIK H J , MYRSTAD R , et al . Monolithic, microchannel and carbon nanofibers/carbon felt reactors for syngas conversion by Fischer-Tropsch synthesis [J ] . Catalysis Today , 2013 , 216 : 150 - 157 .
TORRES G H M , BITTER J H , DAVIDIAN T , et al . Iron particle size effects for direct production of lower olefins from synthesis gas [J ] . Journal of the American Chemical Society , 2012 , 134 ( 39 ): 16207 - 16215 .
DÍAZ J A , AKHAVAN H , ROMERO A , et al . Cobalt and iron supported on carbon nanofibers as catalysts for Fischer-Tropsch synthesis [J ] . Fuel Processing Technology , 2014 , 128 : 417 - 424 .
OSCHATZ M , HOFMANN J P , VAN DEELEN T W , et al . Effects of the functionalization of the ordered mesoporous carbon support surface on iron catalysts for the Fischer-Tropsch synthesis of lower olefins [J ] . ChemCatChem , 2017 , 9 : 620 - 628 .
CRUZ M G A , FERNANDES F A N , OLIVEIRA A C , et al . Effect of the calcination temperatures of the Fe-based catalysts supported on polystyrene mesoporous carbon for FTS synthesis [J ] . Catalysis Today , 2017 , 282 : 174 - 184 .
程杨 , 孟凡会 , 李忠 . 费托合成中碳载体负载铁催化剂研究进展 [J ] . 天然气化工—C1化学与化工 , 2019 , 44 ( 1 ): 113 - 117 .
CHENG Y , MENG F H , LI Z . Advances in carbon material supported Fe-based catalysts for Fischer-Tropsch synthesis [J ] . Natural Gas Chemical Industry , 2019 , 44 ( 1 ): 113 - 117 .
ZHAO X , LV S , WANG L , et al . Comparison of preparation methods of iron-based catalysts for enhancing Fischer-Tropsch synthesis performance [J ] . Molecular Catalysis , 2018 , 449 : 99 - 105 .
WEZENDONK T A , SUN X H , DUGULAN A I , et al . Controlled formation of iron carbides and their performance in Fischer-Tropsch synthesis [J ] . Journal of Catalysis , 2018 , 362 : 106 - 117 .
王爱梅 . MOF衍生多孔碳负载铁基费托合成催化剂的制备与性能研究 [D ] . 北京 : 北京化工大学 , 2022 .
WANG A M . Study of preparation and properties of iron-based Fischer-Tropsch catalysts derived from metal-organic frameworks [D ] . Beijing : Beijing University of Chemical Technology , 2022 .
OAR-ARTETA L , VALERO-ROMERO M J , WEZENDONK T A , et al . Formulation and catalytic performance of MOF-derived Fe@C/Al composites for high temperature Fischer-Tropsch synthesis [J ] . Catalysis Science & Technology , 2018 , 8 ( 1 ): 210 – 220 .
WEZENDONK T A , WARRINGA Q S E , SANTOS V P , et al . Structural and elemental influence from various MOFs on the performance of Fe@C catalysts for Fischer-Tropsch synthesis [J ] . Faraday Discussions , 2017 , 197 : 225 - 242 .
CHEN Y P , WEI J T , DUYAR M S , et al . Carbon-based catalysts for Fischer-Tropsch synthesis [J ] . Chemical Society Reviews , 2021 , 50 ( 4 ): 2337 - 2366 .
韩小雪 , 陈妍希 , 赵俏 , 等 . 碳限域铁基费托合成催化剂研究进展 [J ] . 化工进展 , 2021 , 40 ( 4 ): 1917 - 1927 .
HAN X X , CHEN Y X , ZHAO Q , et al . Advances in carbon-confined iron-based catalysts for Fischer-Tropsch synthesis [J ] . Chemical Industry and Engineering Progress , 2021 , 40 ( 4 ): 1917 - 1927 .
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