丙烯氧酰化合成醋酸烯丙酯催化剂研究进展

张荣凡; 孙浩洋; 邱鹏远; 刘军晓; 张丽斌; 杨运信

doi:10.12434/j.issn.2097-2547.20250221

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丙烯氧酰化合成醋酸烯丙酯催化剂研究进展

低碳分子转化合成 | 更新时间：2026-04-23

- 丙烯氧酰化合成醋酸烯丙酯催化剂研究进展
- Research progress on catalysts for allyl acetate synthesis via propylene oxyacetylation
- 低碳化学与化工 2026, 51(4): 49-58.
- 作者机构：
  
  中石化（上海）石油化工研究院有限公司上海 201208
- 作者简介：
  
  张荣凡（1998—），硕士，助理工程师，研究方向为工业催化，E-mail：zhangrf1970.sshy@sinopec.com。
  邱鹏远（1982—），博士，研究员，研究方向为工业催化及计算化学，E-mail：qiupy.sshy@sinopec.com；
  杨运信（1968—），硕士，正高级工程师，研究方向为工业催化及化学工艺，E-mail：yyxin@sohu.com。
- 基金信息：
  
  中国石油化工股份有限公司资助项目(224062)
- DOI：10.12434/j.issn.2097-2547.20250221
  中图分类号： TQ426.94;O643.36
- 收稿：2025-05-12，
  
  修回：2025-07-03，
  
  纸质出版：2026-04-25
- 稿件说明：
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张荣凡,孙浩洋,邱鹏远等.丙烯氧酰化合成醋酸烯丙酯催化剂研究进展[J].低碳化学与化工,2026,51(4):49-58.

ZHANG Rongfan,SUN Haoyang,QIU Pengyuan,et al.Research progress on catalysts for allyl acetate synthesis via propylene oxyacetylation[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(4):49-58.
张荣凡,孙浩洋,邱鹏远等.丙烯氧酰化合成醋酸烯丙酯催化剂研究进展[J].低碳化学与化工,2026,51(4):49-58. DOI： 10.12434/j.issn.2097-2547.20250221.

ZHANG Rongfan,SUN Haoyang,QIU Pengyuan,et al.Research progress on catalysts for allyl acetate synthesis via propylene oxyacetylation[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(4):49-58. DOI： 10.12434/j.issn.2097-2547.20250221.

摘要

醋酸烯丙酯（AAc）是一种重要的有机化工原料，其下游衍生物在多领域应用广泛。丙烯氧酰化是合成醋酸烯丙酯的重要途径，而催化剂是影响该过程的核心。对醋酸烯丙酯催化剂（主要是Pd-Cu催化剂）的研究进展进行了综述，首先介绍了催化合成AAc的两种主要反应机理，然后总结了载体改性、活性组分优化、助催化剂筛选及制备工艺改进对催化剂催化性能的影响，最后对醋酸烯丙酯催化剂的未来研究方向进行了展望。

Abstract

Allyl acetate (AAc) is an important organic chemical feedstock

and its downstream derivatives find extensive application in multiple fields. Allyl oxylation is an important approach for the synthesis of allyl acetate

and the catalyst is the core factor influencing this process. The research progress on allyl acetate catalysts (mainly Pd-Cu catalysts) was reviewed. Firstly

two main reaction mechanisms for the catalytic synthesis of AAc were introduced. Then

the effects of support modification

optimization of active components

screening of co-catalysts and improvement of preparation processes on the catalytic performances of the catalysts were summarized. Finally

the future research directions of allyl acetate catalysts were prospected.

关键词

Keywords

references

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