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1.榆林学院 化学与化工学院,陕西 榆林 719000
2.榆林学院 陕西省低变质煤洁净利用重点实验室,陕西 榆林 719000
3.中国矿业大学 化工学院,江苏 徐州 221116
陈 娟(1985—),博士,副教授,硕士研究生导师,研究方向为低变质粉煤清洁高效加工利用及煤基固废资源化利用,E-mail:chenjuanchen1985@163.com。
闫 龙(1980—),博士,教授,研究方向为洁净兰炭技术,E-mail:ylyanlong@126.com
武建军(1964—),博士,教授,博士研究生导师,研究方向为固废洁净化处理、煤/生物质热转化与高值化利用和褐煤提质,E-mail:jjuw@163.com;
收稿:2025-05-19,
修回:2025-06-15,
网络出版:2025-12-16,
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陈娟,赵志浩,辛建金等.煤气化细渣主要组分高值化、功能化利用研究进展[J].低碳化学与化工,
CHEN Juan,ZHAO Zhihao,XIN Jianjinn,et al.Research progress on high-value and functional utilization of main components of coal gasification fine slag[J].Low-Carbon Chemistry and Chemical Engineering,
陈娟,赵志浩,辛建金等.煤气化细渣主要组分高值化、功能化利用研究进展[J].低碳化学与化工, DOI:10.12434/j.issn.2097-2547.20250215.
CHEN Juan,ZHAO Zhihao,XIN Jianjinn,et al.Research progress on high-value and functional utilization of main components of coal gasification fine slag[J].Low-Carbon Chemistry and Chemical Engineering, DOI:10.12434/j.issn.2097-2547.20250215.
作为煤气化过程产生的大宗固废之一,煤气化细渣高值化利用是实现其规模化消纳的关键。综述了煤气化细渣理化特性,及其主要组分(残炭和硅铝基矿物质)的高值化、功能化利用途径。残炭可用于类活性炭、吸波材料、电催化剂载体、石墨材料和超级电容器等的制备;矿物质则可用于硅基材料、沸石分子筛、陶瓷材料和铝基净水剂等的制备。此外,残炭-矿物质协同利用还可用于碳/硅复合材料等精细化产品的制备。当前,相关研究仍面临基础理论薄弱、工艺复杂、存在二次污染、产品性能不足等问题。未来,可结合微观机理调控、跨学科技术融合(如人工智能、微波辅助合成)、应用场景拓展(如5G屏蔽、CO
2
捕集-催化一体化),推动煤气化细渣从“环境负担”向“城市矿山”转型,助力实现“碳中和”目标。
As one of the major solid wastes generated during the coal gasification process
the high-value utilization of coal gasification fine slag is the key to realizing its large-scale consumption. The physicochemical characteristics of coal gasification fine slag were reviewed
as well as the hi
gh-value and functional utilization pathways of its main components (residual carbon and silicon-aluminum-based minerals). The residual carbon can be used to prepare activated carbon-like materials
microwave-absorbing materials
electrocatalyst carriers
graphite materials and supercapacitors. The mineral components can be used to prepare silicon-based materials
zeolite molecular sieves
ceramic materials and aluminum-based water purifiers. In addition
the synergistic utilization of residual carbon and minerals can be applied to the preparation of refined products such as carbon/silicon composite materials. At present
related research still faces challenges such as weak fundamental theory
complex processes
secondary pollution and insufficient product performance. In the future
by combining micro-mechanism regulation
interdisciplinary technology integration (such as artificial intelligence and microwave-assisted synthesis)
and the expansion of application scenarios (such as 5G shielding and integrated CO
2
capture-catalysis)
the transformation of coal gasification fine slag from “environmental burden” into “urban mine” can be promoted
contributing to the realization of the “carbon neutrality” goal.
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