Hydrogenation kinetics of 1-methylnaphthalene as single component and in mixture with naphthalene catalyzed by NiMo/<italic style="font-style: italic">γ</italic>-Al<sub>2</sub>O<sub>3</sub>

DANG Taoqun; MA Chenyang; WANG Xingbao

doi:10.12434/j.issn.2097-2547.20260063

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Hydrogenation kinetics of 1-methylnaphthalene as single component and in mixture with naphthalene catalyzed by NiMo/γ-Al₂O₃

更新时间：2026-06-18

- Hydrogenation kinetics of 1-methylnaphthalene as single component and in mixture with naphthalene catalyzed by NiMo/γ-Al₂O₃
- Pages: 1-9(2026)
- 作者机构：
  
  太原理工大学省部共建煤基能源清洁高效利用国家重点实验室，山西太原 030024
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20260063
  CLC： TQ529.1
- Received：05 February 2026，
  
  Revised：2026-03-12，
  
  Online First：13 June 2026，
- 稿件说明：
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党涛群,马晨阳,王兴宝.NiMo/γ-Al₂O₃催化1-甲基萘单组分加氢及与萘混合加氢反应动力学[J].低碳化学与化工,DOI:10.12434/j.issn.2097-2547.20260063.

DANG Taoqun,MA Chenyang,WANG Xingbao.Hydrogenation kinetics of 1-methylnaphthalene as single component and in mixture with naphthalene catalyzed by NiMo/γ-Al₂O₃[J].Low-Carbon Chemistry and Chemical Engineering,DOI:10.12434/j.issn.2097-2547.20260063.
党涛群,马晨阳,王兴宝.NiMo/γ-Al₂O₃催化1-甲基萘单组分加氢及与萘混合加氢反应动力学[J].低碳化学与化工,DOI:10.12434/j.issn.2097-2547.20260063. DOI：

DANG Taoqun,MA Chenyang,WANG Xingbao.Hydrogenation kinetics of 1-methylnaphthalene as single component and in mixture with naphthalene catalyzed by NiMo/γ-Al₂O₃[J].Low-Carbon Chemistry and Chemical Engineering,DOI:10.12434/j.issn.2097-2547.20260063. DOI：

摘要

稠环芳烃加氢生成的部分加氢产物具有良好的供氢性能，可作为供氢溶剂用于煤直接液化过程。以煤液化组分中的1-甲基萘为模型化合物，在NiMo/

-Al

上进行了1-甲基萘单组分加氢及其与萘混合加氢反应，并建立了相应的动力学模型，以考察支链结构对稠环芳烃加氢反应行为的影响。结果表明，在1-甲基萘及其部分加氢产物中，无支链侧芳环对应加氢路径的活化能更低，因此更易发生加氢反应；而在1-甲基萘部分加氢产物中，与支链相连芳环结构的吸附焓和吸附熵均较低，导致进一步加氢受限。

Abstract

Partially hydrogenated products formed during the hydrogenation of polycyclic aromatic hydrocarbons exhibit good hydrogen-donor capacity and can serve as hydrogen-donor solvents in direct coal liquefaction. With 1-methylnaphthalene as the model compound

single-component hydrogenation of 1-methylnaphthalene and its mixed hydrogenation with naphthalene were carried out over NiMo/

-Al

catalyst

and corresponding kinetic models were established to investigate the effects of side-chain structures on the hydrogenation behaviors of polycyclic aromatic hydrocarbons. The results indicate that

for 1-methylnaphthalene and its partially hydrogenated products

the hydrogenation pathway corresponding to the aromatic ring on the unsubstituted side has lower activation energy and is therefore more favorable for hydrogenation. In contrast

for the partially hydrogenated products of 1-methylnaphthalene

the aromatic ring connected to the alkyl substituent shows lower adsorption enth

alpy and adsorption entropy

thus limiting further hydrogenation.

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references

VASIREDDY S , MORREALE B , CUGINI A , et al . Clean liquid fuels from direct coal liquefaction: Chemistry, catalysis, technological status and challenges [J ] . Energy & Environmental Science , 2011 , 4 ( 2 ): 311 - 345 .

AGRAWAL R , SINGH N R , RIBEIRO F H , et al . Sustainable fuel for the transportation sector [J ] . Proceedings of the National Academy of Sciences of the United States of America , 2007 , 104 ( 12 ): 4828 - 4833 .

ROBINSON K K . Reaction engineering of direct coal liquefaction [J ] . Energies , 2009 , 2 ( 4 ): 976 - 1006 .

SHUI H F , CAI Z Y , XU C B . Recent advances in direct coal liquefaction [J ] . Energies , 2010 , 3 ( 2 ): 155 - 170 .

李海军 , 张小彬 , 王兴宝 , 等 . 煤直接液化溶剂研究述评 [J ] . 煤炭学报 , 2022 , 47 ( 10 ): 3791 - 3804 .

LI H J , ZHANG X B , WANG X B , et al . Research progress and prospects of coal direct liquefaction solvents [J ] . Journal of China Coal Society , 2022 , 47 ( 10 ): 3791 - 3804 .

牛犇 . 煤直接液化中溶剂的作用及氢传递机理 [D ] . 大连 : 大连理工大学 , 2017 .

NIU B . Role of solvents and hydrogen transfer mechanism in direct coal liquefaction [D ] . Dalian : Dalian University of Technology , 2017 .

李群花 , 高山松 , 舒歌平 , 等 . 煤直接液化循环溶剂中芳烃的分子组成及分布特点 [J ] . 煤炭转化 , 2021 , 44 ( 1 ): 18 - 25 .

LI Q H , GAO S S , SHU G P , et al . Molecular composition and distribution characteristics of aromatic hydrocarbons in coal direct liquefaction circulating solvent [J ] . Coal Conversion , 2021 , 44 ( 1 ): 18 - 25 .

王薇 , 舒歌平 , 章序文 , 等 . 典型多环芳烃的加氢反应研究进展 [J ] . 煤炭工程 , 2018 , 50 ( 12 ): 141 - 144 .

WANG W , SHU G P , ZHANG X W , et al . Research progress on hydrogenation of polycyclic aromatics [J ] . Coal Engineering , 2018 , 50 ( 12 ): 141 - 144 .

URAZOV K K , SVIRIDENKO N N , IOVIK Y A , et al . Effect of hydrogen-donor of heavy crude oil catalytic aquathermolysis in the presence of a nickel-based catalyst [J ] . Catalysts , 2022 , 12 ( 10 ): 1154 .

BAI J K , ZHANG X B , LI W , et al . Rate constant of hydrogen transfer from H-donor solvents to coal radicals [J ] . Fuel , 2022 , 318 : 123621 .

WANG J L , XIE L Y , PENG Y F , et al . Molecular composition of direct coal liquefaction products obtained from the Shenhua industrial plant [J ] . Fuel , 2024 , 357 : 129735 .

KIRUMAKKI S R , SHPEIZER B G , SAGAR G V , et al . Hydrogenation of naphthalene over NiO/SiO 2 -Al 2 O 3 catalysts: Structure-activity correlation [J ] . Journal of Catalysis , 2006 , 242 ( 2 ): 319 - 331 .

葛泮珠 , 高晓冬 , 任亮 . 不同催化剂体系上的1-甲基萘加氢饱和反应规律 [J ] . 石油炼制与化工 , 2014 , 45 ( 6 ): 36 - 39 .

GE P Z , GAO X D , REN L . Hydrogenation performance of 1-methylnaphthalene on different catalysts [J ] . Petroleum Processing and Petrochemicals , 2014 , 45 ( 6 ): 36 - 39 .

鞠雪艳 , 张毓莹 , 胡志海 , 等 . NiMo加氢催化剂上1-甲基萘的饱和反应规律 [J ] . 石油学报（石油加工） , 2012 , 28 ( 4 ): 538 - 543 .

JU X Y , ZHANG Y Y , HU Z H , et al . Hydrogenation saturation discipline of 1-methylnaphthalene over Ni-Mo catalyst [J ] . Acta Petrolei Sinica (Petroleum Processing Section) , 2012 , 28 ( 4 ): 538 - 543 .

BELTRAMONE A R , RESASCO D E , ALVAREZ W E , et al . Simultaneous hydrogenation of multiring aromatic compounds over NiMo catalyst [J ] . Industrial & Engineering Chemistry Research , 2008 , 47 ( 19 ): 7161 - 7166 .

LYLYKANGAS M S , RAUTANEN P A , KRAUSE A O I . Liquid-phase hydrogenation kinetics of multicomponent aromatic mixtures on Ni/Al 2 O 3 [J ] . Industrial & Engineering Chemistry Research , 2002 , 41 ( 23 ): 5632 - 5639 .

MEI X P , MA Z X , YANG Y J , et al . Competitive effects of compounding aromatic hydrogen storage carriers in low-pressure hydrogenation reactions [J ] . Fuel Processing Technology , 2024 , 265 : 108143 .

马晨阳 , 党涛群 , 王兴宝 . 煤直接液化溶剂典型稠环芳烃的加氢反应动力学 [J/OL ] . 洁净煤技术 : 1 - 12 [ 2026-02-02 ] . DOI: 10.13226/j.issn.1006-6772.24042001 http://dx.doi.org/10.13226/j.issn.1006-6772.24042001 .

MA C Y , DANG T Q , WANG X B . Hydrogenation kinetics of typical polycyclic aromatic hydrocarbons in direct coal liquefaction solvent [J/OL ] . Clean Coal Technology : 1 - 12 [ 2026-02-02 ] . DOI: 10.13226/j.issn.1006-6772.24042001 http://dx.doi.org/10.13226/j.issn.1006-6772.24042001 .

KORRE S C , KLEIN M T , QUANN R J . Polynuclear aromatic hydrocarbons hydrogenation. 1. Experimental reaction pathways and kinetics [J ] . Industrial & Engineering Chemistry Research , 1995 , 34 ( 1 ): 101 - 117 .

SCHACHTL E , YOO J S , GUTIERREZ O Y , et al . Impact of Ni promotion on the hydrogenation pathways of phenanthrene on MoS 2 / γ -Al 2 O 3 [J ] . Journal of Catalysis , 2017 , 352 : 171 - 181 .

PENG C , ZHOU Z M , FANG X C , et al . Thermodynamics and kinetics insights into naphthalene hydrogenation over a Ni-Mo catalyst [J ] . Chinese Journal of Chemical Engineering , 2021 , 39 : 173 - 182 .

PENG C , LIU P , ZHOU Z M , et al . Detailed understanding on thermodynamic and kinetic features of phenanthrene hydroprocessing on Ni-Mo/HY catalyst [J ] . AIChE Journal , 2022 , 68 ( 11 ): e17831 .

LI W B , FU X Y , ZHAI W M , et al . Hydrogenation kinetic of alkenes and aromatics over NiMo hydrotreatment catalysts [J ] . Chinese Journal of Chemical Engineering , 2025 , 79 : 11 - 22 .

MHADESHWAR A B , WANG H , VLACHOS D G . Thermodynamic consistency in microkinetic development of surface reaction mechanisms [J ] . The Journal of Physical Chemistry B , 2003 , 107 ( 46 ): 12721 - 12733 .

JACQUIN M , JONES D J , ROZIERE J , et al . Novel supported Rh, Pt, Ir and Ru mesoporous aluminosilicates as catalysts for the hydrogenation of naphthalene [J ] . Applied Catalysis A: General , 2003 , 251 ( 1 ): 131 - 141 .

DÍAZ E , RAPADO-GALLEGO P , PRIETO I , et al . 1-Methylnaphthalene hydrogenation over supported precious metal catalysts: A kinetic study for deciphering the roles of the metal and support [J ] . Industrial & Engineering Chemistry Research , 2025 , 64 ( 19 ): 9640 - 9649 .

张锐 , 葛泮珠 , 任亮 , 等 . 1-甲基萘加氢饱和反应热力学平衡分析及实验研究 [J ] . 石油学报（石油加工） , 2022 , 38 ( 6 ): 1281 - 1290 .

ZHANG R , GE P Z , REN L , et al . Thermodynamic equilibrium analysis and experimental research on hydrogenation saturation reaction of 1-methylnaphthalene [J ] . Acta Petrolei Sinica (Petroleum Processing Section) , 2022 , 38 ( 6 ): 1281 - 1290 .

KORRE S C , NEUROCK M , KLEIN M T , et al . Hydrogenation of polynuclear aromatic hydrocarbons. 2. Quantitative structure/reactivity correlations [J ] . Chemical Engineering Science , 1994 , 49 ( 24 ): 4191 - 4210 .

SALONIKIDOU E D , GIANNAKOUDAKIS D A , KOSTOGLOU M , et al . Modeling the liquid fuel desulfurization efficiency of activated carbons before and after chemical treatment: The competitive role of mono- and diaromatics [J ] . Industrial & Engineering Chemistry Research , 2022 , 61 ( 43 ): 15933 - 15947 .

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Hydrogenation kinetics of 1-methylnaphthalene as single component and in mixture with naphthalene catalyzed by NiMo/γ-Al2O3

DOI：10.12434/j.issn.2097-2547.20260063

摘要

Abstract

关键词

Keywords

references

Hydrogenation kinetics of 1-methylnaphthalene as single component and in mixture with naphthalene catalyzed by NiMo/γ-Al₂O₃