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陕西氢能研究院有限公司,陕西 西安 712046
Received:26 November 2025,
Revised:2025-12-31,
Online First:02 June 2026,
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杜宇峰,黄晔,郑化安等.绿氨制储输用技术路线研究进展[J].低碳化学与化工,
DU Yufeng,HUANG Ye,ZHENG Huaan,et al.Research progress on technical routes for green ammonia production, storage, transportation and application[J].Low-Carbon Chemistry and Chemical Engineering,
杜宇峰,黄晔,郑化安等.绿氨制储输用技术路线研究进展[J].低碳化学与化工, DOI:10.12434/j.issn.2097-2547.20250451.
DU Yufeng,HUANG Ye,ZHENG Huaan,et al.Research progress on technical routes for green ammonia production, storage, transportation and application[J].Low-Carbon Chemistry and Chemical Engineering, DOI:10.12434/j.issn.2097-2547.20250451.
在可持续发展和全球能源转型的背景下,绿氨作为一种关键的“零碳”化工原料和能源载体,其战略地位日益凸显。首先基于国内外认证标准厘清了绿氨定义,然后综述了绿氨在制备、储运和应用三大环节的技术路线及研究进展,以期为后续技术研发和工程示范提供参考。在制备方面,重点剖析了在热化学哈伯-博世(H-B)工艺合成氨中的绿氢原料替代路径、温和条件热催化路径、柔性/小型化系统路径,并探讨了电化学合成氨、光催化合成氨等新兴技术的机理、优势和挑战。在储运方面,对比分析了道路、管道和海洋运输的技术特点和适用场景。在应用方面,深入探究了绿氨作为含氢载体(直接氨燃料电池、氨分解制氢)、零碳燃料(氨氢/氨煤/氨与高活性燃料混合燃烧)和化工原料(氨法碳捕集)的多场景应用潜力、技术瓶颈和成本趋势。最后,总结并展望了绿氨在构建零碳工业体系中的关键作用及其政策需求。
Against the backdrop of sustainable development and the global energy transition
green ammonia
as a key “zero-carbon” chemical feedstock and energy carrier
is gaining increasing strategic importance. First
the definition of green ammonia was clarified based on domestic and international certification standards. Then
the technical routes and research progress of green ammonia in the three stages of production
storage and transportation
and application were reviewed
aiming to provide references for subsequent technological research and engineering demonstration. In terms of production
green hydrogen feedstock substitution pathways
mild-condition thermocatalytic pathways and flexible/miniaturized system pathways in the thermochemical Haber-Bosch (H-B) ammonia synthesis process were systematically analyzed
and the mechanisms
advantages and challenges of emerging technologies such as electrochemical ammonia synthesis and photocatalytic ammonia synthesis were discussed. In terms of storage and transportation
the technical characteristics and applicable scenarios of road
pipeline and marine transportation were comparatively analyzed. In terms of application
the multi-scenario application potential
technological bottlenecks and cost trends of green ammonia as a hydrogen carrier (direct ammonia fuel cells and ammonia decomposition for hydrogen production)
a zero-carbon fuel (ammonia-hydrogen/ammonia-coal/ammonia-high-reactivity fuel co-combustion) and a chemical feedstock (ammonia-based carbon capture) were systematically investigated. Finally
the key role of green ammonia in constructing a zero-carbon industrial system and its policy requirements were summarized and prospected.
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