Effect of synergistic conditioning using FeCl<sub>3</sub> or CaO with biomass on combustion characteristics of dewatered sludge

YUAN Sijia; GENG Litao; ZHOU Haiyun; XU Zhenjia; ZHAO Peitao

doi:10.12434/j.issn.2097-2547.20250420

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Effect of synergistic conditioning using FeCl₃ or CaO with biomass on combustion characteristics of dewatered sludge

更新时间：2026-05-22

- Effect of synergistic conditioning using FeCl₃ or CaO with biomass on combustion characteristics of dewatered sludge
- Vol. 51, Issue 5, Pages: 77-86(2026)
- 作者机构：
  
  1.江苏省环境工程技术有限公司，江苏南京 210019
  2.中国矿业大学低碳能源与动力工程学院，江苏徐州221116
  3.江苏省重点行业减污降碳协同控制工程研究中心，江苏南京 210019
  4.南京市有机固废资源化利用工程技术研究中心，江苏南京 210019
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20250420
  CLC： TQ038;X705
- Received：06 November 2025，
  
  Revised：2025-12-24，
  
  Published：25 May 2026
- 稿件说明：
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袁思佳,耿李涛,周海云等.FeCl₃或CaO与生物质协同调理对深度脱水污泥燃烧特性的影响[J].低碳化学与化工,2026,51(5):77-86.

YUAN Sijia,GENG Litao,ZHOU Haiyun,et al.Effect of synergistic conditioning using FeCl₃ or CaO with biomass on combustion characteristics of dewatered sludge[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(5):77-86.
袁思佳,耿李涛,周海云等.FeCl₃或CaO与生物质协同调理对深度脱水污泥燃烧特性的影响[J].低碳化学与化工,2026,51(5):77-86. DOI： 10.12434/j.issn.2097-2547.20250420.

YUAN Sijia,GENG Litao,ZHOU Haiyun,et al.Effect of synergistic conditioning using FeCl₃ or CaO with biomass on combustion characteristics of dewatered sludge[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(5):77-86. DOI： 10.12434/j.issn.2097-2547.20250420.

摘要

城市污水处理过程中产生了大量剩余污泥，这些污泥具有含水率高、灰分含量高和热值低等特征，严重制约其焚烧减量与能量回收效果。污泥深度脱水常需引入化学调理剂与生物质骨架构建剂，但上述试剂对脱水污泥后续燃烧行为的影响尚缺乏系统认识。以FeCl

、CaO为典型化学调理剂，以稻秆、玉米秸秆和竹子为生物质骨架构建剂，调理后获得脱水污泥，并利用热重分析研究了脱水污泥燃烧特性。结果表明，FeCl

调理后，污泥的着火温度和表观活化能降低，燃烧特性指数增大，脱水污泥的燃烧反应活性显著提升；而CaO调理后，污泥的着火温度和表观活化能上升，燃烧失重率和燃烧特性指数减小，不利于燃烧。生物质调理时，脱水污泥总失重率和最大失重速率显著增大，着火温度随生物质添加量增大而上升，表观活化能由原污泥的26.60 kJ/mol增大至29.87~41.16 kJ/mol，燃烧活性整体趋于“生物质化”。与添加生物质相比，FeCl

-生物质协同调理后，污泥在保持较大总失重率的同时，表观活化能减小，CaO-生物质协同调理则使污泥的表观活化能增大，表明FeCl

-生物质具有更显著的协同促进作用。

Abstract

In the process of municipal wastewater treatment

a large amount of residual sludge is generated

characterized by high moisture content

high ash content

and low calorific value

which severely restricts the efficiency of sludge incineration for volume reduction and energy recovery. Deep dewatering commonly requires the addition of chemical conditioners and biomass skeletal agents. However

their effects on the subsequent combustion behavior of dewatered sludge remain insufficiently understood. Taking FeCl

and CaO as typical chemical conditioning agents and rice straw

corn stalk and bamboo as biomass skeleton builders

the dewatered sludge was obtained after conditioning. The combustion characteristics of the dewatered sludge were investigated using thermogravimet

ric analysis. The results show that after conditioning with FeCl

the ignition temperature and apparent activation energy of the sludge decreases

while the combustion characteristic parameters increase

significantly enhancing the combustion reactivity of dewatered sludge. In contrast

after conditioning with CaO

the ignition temperature and apparent activation energy of the sludge increase

while the combustion weight loss rate and combustion characteristic parameters decreases

which is unfavorable for combustion. When conditioned with biomas

the total mass loss and maximum mass loss rate increase markedly. However

ignition temperature increases with increasing biomass addition amount

and apparent activation energy rises from 26.60 kJ/mol for raw sludge to 29.87~41.16 kJ/mol

indicating an overall shift of combustion behavior toward biomass-dominated characteristics. Compared to adding biomass alone

FeCl

-biomass synergistic conditioning maintains a high total mass loss while exhibiting a lower apparent activation energy

whereas CaO-biomass synergistic conditioning increases apparent activation energy. These results demonstrate that FeCl

-biomass coupling exhibits a more pronounced synergistic promotion effect on combustion reactivity.

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references

生态环境部 . 2024年中国生态环境统计年报 [EB/OL ] . 北京 : 生态环境部 , ( 2025-11-28 )[ 2026-03-13 ] . https://www.mee.gov.cn/hjzl/sthjzk/sthjtjnb/202511/t20251128_1135226.shtml https://www.mee.gov.cn/hjzl/sthjzk/sthjtjnb/202511/t20251128_1135226.shtml .

Ministry of Ecology and Environment of the People’s Republic of China . China Ecological and environmental statistics annual report 2024 [EB/OL ] . Beijing : Ministry of Ecology and Environment of the People’s Republic of China , ( 2025-11-28 )[ 2026-03-13 ] . https://www.mee.gov.cn/hjzl/sthjzk/sthjtjnb/202511/t20251128_1135226.shtml https://www.mee.gov.cn/hjzl/sthjzk/sthjtjnb/202511/t20251128_1135226.shtml .

LV H X , CHEN X H , MO C H , et al . Occurrence and dissipation mechanism of organic pollutants during the composting of sewage sludge: A critical review [J ] . Bioresource Technology , 2021 , 328 : 124847 .

李赟 . 城市污泥焚烧技术研究进展 [J ] . 东北电力大学学报 , 2022 , 42 ( 3 ): 46 - 56 .

LI Y . Research progress for sewage sludge incineration technology [J ] . Journal of Northeast Electric Power University , 2022 , 42 ( 3 ): 46 - 56 .

HU M , HU H Y , YE Z H , et al . A review on turning sewage sludge to value-added energy and materials via thermochemical conversion towards carbon neutrality [J ] . Journal of Cleaner Production , 2022 , 379 : 134657 .

LIU H B , XIAO H , FU B , et al . Feasibility of sludge deep-dewatering with sawdust conditioning for incineration disposal without energy input [J ] . Chemical Engineering Journal , 2017 , 313 : 655 - 662 .

LIU Y F , DONG L M , CUI G N , et al . Low-field nuclear magnetic resonance detection of changes in the water distribution in citric acid biosludge during dewatering [J ] . International Journal of Environmental Science and Technology , 2022 , 19 ( 5 ): 4153 - 4166 .

李游 , 张小鸿 , 孔芹 , 等 . 调理剂对污泥燃烧处置影响研究综述 [J ] . 节能技术 , 2025 , 43 ( 2 ): 106 - 114+126 .

LI Y , ZHANG X H , KONG Q , et al . A review of influence of dewatering conditioner on combustion performance for disposal of sewage sludge [J ] . Energy Conservation Technology , 2025 , 43 ( 2 ): 106 - 114+126 .

LI H , DAI T L , CHEN J A , et al . Enhanced sludge dewaterability by Fe-rich biochar activating hydrogen peroxide: Co-hydrothermal red mud and reed straw [J ] . Journal of Environmental Management , 2021 , 296 : 113239 .

CHEN C , XIONG Q , JIANG S J . Effect of rice husk flour size on sewage sludge dewaterability during composite conditioning with persulfate [J ] . Desalination and Water Treatment , 2019 , 168 : 340 - 347 .

张晴 , 莫华 , 徐海红 , 等 . 燃煤电厂掺烧废弃物现状及环境管理建议 [J ] . 环境工程 , 2020 , 38 ( 6 ): 202 - 207 .

ZHANG Q , MO H , XU H H , et al . Present situation of co-combustion of waste and coal in power plants and suggestions on environmental management [J ] . Environmental Engineering , 2020 , 38 ( 6 ): 202 - 207 .

BAO P R , DU C Y , LI Y F , et al . Application of skeleton builders to sludge dewatering and disposal: A critical review [J ] . Science of the Total Environment , 2024 , 906 : 167106 .

CHEN K , SUN Y , FAN J , et al . The dewatering performance and cracking-flocculation-skeleton mechanism of bioleaching-coal fly ash combined process for sewage sludge [J ] . Chemosphere , 2022 , 307 : 135994 .

KONG X H , SONG Z R , WU J , et al . Treating waste with waste: 1 h deep-drying of sewage sludge by secondary aluminum ash [J ] . Journal of Cleaner Production , 2025 , 528 : 146703 .

CHAN Y H , LAU D K S , WONG W Y , et al . Progress in thermochemical co-processing of biomass and sludge for sustainable energy, value-added products and circular economy [J ] . Bioresource Technology , 2023 , 370 : 128551 .

全国煤炭标准化技术委员会 . 煤炭燃烧特性试验方法热重分析法 : GB/T 33304-2016 [S ] . 北京 : 中国标准出版社 , 2016 .

National Coal Standardization Technical Committee . Testing method of combustion characteristics of coal—Thermogravimetric analysis : GB/T 33304—2016 [S ] . Beijing : Standards Press of China , 2016 .

NI Z S , ZHANG Y K , LIU X , et al . Co-combustion of sewage sludge with corn stalk based on TG-MS and TG-DSC: Gas products, interaction mechanisms, and kinetic behavior [J ] . Energy , 2024 , 308 : 132747 .

葛仕福 , 赵培涛 , 李扬 , 等 . 污泥-秸秆衍生固体燃料燃烧特性 [J ] ．中国电机工程学报 , 2012 , 32 ( 17 ): 110 - 116 ．

GE S F , ZHAO P T , LI Y , et al . Combustion characteristics of sewage sludge-straw derived fuel [J ] . Proceedings of the CSEE , 2012 , 32 ( 17 ): 110 - 116 .

赵光杰 , 金建龙 , 金亮 , 等 . 废轮胎与生物质共热解特性及产物分布研究 [J ] . 低碳化学与化工 , 2025 , 50 ( 6 ): 74 - 80 .

ZHAO G J , JIN J L , JIN L , et al . Study on characteristics and product distributions of waste tire and biomass co-pyrolysis [J ] . Low-Carbon Chemistry and Chemical Engineering , 2025 , 50 ( 6 ): 74 - 80 .

WANG Z Q , HONG C , XING Y , et al . Combustion behaviors and kinetics of sewage sludge blended with pulverized coal: With and without catalysts [J ] . Waste Management , 2018 , 74 : 288 - 296 .

LIU J Y , ZENG J J , SUN S Y , et al . Combined effects of FeCl 3 and CaO conditioning on SO 2 , HCl and heavy metals emissions during the DDSS incineration [J ] . Chemical Engineering Journal , 2016 , 299 : 449 - 458 .

曾佳俊 , 孙水裕 , 陈楠纬 , 等 . 调理剂FeCl 3 /CaO对深度脱水市政污泥燃烧特性的影响 [J ] . 环境科学学报 , 2015 , 35 ( 6 ): 1842 - 1850 .

ZENG J J , SUN S Y , CHEN N W , et al . Effects of FeCl 3 /CaO as conditioner on th e combustion characteristics of deeply dewatered sewage sludge [J ] . Acta Scientiae Circumstantiae , 2015 , 35 ( 6 ): 1842 - 1850 .

谭中欣 , 严建华 , 蒋旭光 , 等 . 电镀污泥焚烧过程中的热分析以及重金属的迁移规律 [J ] . 环境科学 , 2006 , 27 ( 5 ): 998 - 1002 .

TAN Z X , YAN J H , JIANG X G , et al . Thermal analysis and the distribution rule of heavy metals during electroplating sludge combustion [J ] . Environmental Science , 2006 , 27 ( 5 ): 998 - 1002 .

GUO S , YANG Q Y , LIANG H L , et al . Effect of blending sewage sludge with coal on combustion and ash slagging behavior [J ] . RSC Advances , 2019 , 9 ( 51 ): 29482 - 29492 .

AREEPRASERT C , SCALA F , COPPOLA A , et al . Fluidized bed co-combustion of hydrothermally treated paper sludge with two coals of different rank [J ] . Fuel Processing Technology , 2016 , 144 : 230 - 238 .

方诗雯 , 林延 , 丁力行 , 等 . 造纸污泥与煤掺混燃烧特性及其动力学行为 [J ] . 热科学与技术 , 2023 , 22 ( 6 ): 583 - 590 .

FANG S W , LIN Y , DING L X , et al . The co-combustion characteristics and kinetic behavior of paper sludge and coal [J ] . Journal of Thermal Science and Technology , 2023 , 22 ( 6 ): 583 - 590 .

张慧敏 . 生物质与皮革污泥混合及成型燃料热重分析 [D ] . 济南 : 山东大学 , 2013 .

ZHANG H M . Thermal analysis of biomass and tannery sludge blended briouette fuel [D ] . Jinan : Shandong University , 2013 .

郑植 , 沈骏 , 刘雪松 , 等 . 固体燃料低碳燃烧技术研究进展 [J ] . 低碳化学与化工 , 2024 , 49 ( 11 ): 70 - 80 .

ZHENG Z , SHEN J , LIU X S , et al . Research progress of solid fuel low-carbon combustion technologies [J ] . Low-Carbon Chemistry and Chemical Engineering , 2024 , 49 ( 11 ): 70 - 80 .

CHEN J C , LIU J Y , HE Y , et al . Investigation of co-combustion characteristics of sewage sludge and coffee grounds mixtures using thermogravimetric analysis coupled to artificial neural networks modeling [J ] . Bioresource Technology , 2017 , 225 : 234 - 245 .

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Effect of synergistic conditioning using FeCl3 or CaO with biomass on combustion characteristics of dewatered sludge

DOI：10.12434/j.issn.2097-2547.20250420

摘要

Abstract

关键词

Keywords

references

Effect of synergistic conditioning using FeCl₃ or CaO with biomass on combustion characteristics of dewatered sludge