Simulation study on hydrogen absorption/desorption and purification performances of titanium-manganese hydrogen storage alloys

ZHAO Kun; LI Jianli; ZHAO Feng; LI Jingfa; QIU Lijuan

doi:10.12434/j.issn.2097-2547.20250242

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Simulation study on hydrogen absorption/desorption and purification performances of titanium-manganese hydrogen storage alloys

更新时间：2026-05-22

- Simulation study on hydrogen absorption/desorption and purification performances of titanium-manganese hydrogen storage alloys
- Vol. 51, Issue 5, Pages: 127-138(2026)
- 作者机构：
  
  1.北京石油化工学院机械工程学院，北京 102617
  2.航天沧州能源环保创新研究院，河北沧州 061108
  3.长江大学石油工程学院，湖北武汉 430100
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20250242
  CLC： TK91
- Received：26 May 2025，
  
  Revised：2025-06-24，
  
  Published：25 May 2026
- 稿件说明：
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赵堃,李建立,赵峰等.钛锰系储氢合金吸放氢及纯化性能仿真研究[J].低碳化学与化工,2026,51(5):127-138.

ZHAO Kun,LI Jianli,ZHAO Feng,et al.Simulation study on hydrogen absorption/desorption and purification performances of titanium-manganese hydrogen storage alloys[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(5):127-138.
赵堃,李建立,赵峰等.钛锰系储氢合金吸放氢及纯化性能仿真研究[J].低碳化学与化工,2026,51(5):127-138. DOI： 10.12434/j.issn.2097-2547.20250242.

ZHAO Kun,LI Jianli,ZHAO Feng,et al.Simulation study on hydrogen absorption/desorption and purification performances of titanium-manganese hydrogen storage alloys[J].Low-Carbon Chemistry and Chemical Engineering,2026,51(5):127-138. DOI： 10.12434/j.issn.2097-2547.20250242.

摘要

金属氢化物（MH）储氢条件较温和、体积储氢密度高，且能纯化氢气，在高密度储氢与高效氢气纯化集成应用方面具有独特优势。基于圆柱形储罐、外部循环水控温和中心贯通式网管吸放氢的基本设置，建立了钛锰系储氢合金吸放氢及纯化性能仿真三维模型。通过调节换热流体温度、吸放氢压力和

对流换热系数等参数，开展了针对吸放氢及纯化性能的3因素5水平仿真研究。结果表明，换热流体温度对吸放氢及纯化性能影响最大，其次是吸放氢压力，再次是对流换热系数。当换热流体温度、吸氢压力和对流换热系数分别在283~303 K、0.8~1.2 MPa和500~1000 W/(m

·K)区间时，可获得较佳的吸氢及纯化性能。当换热流体温度、放氢压力和对流换热系数分别在313~333 K、0.08~0.12 MPa和1000~1652 W/(m

·K)区间时，可获得较佳的放氢性能。对于床层半径为20 cm且无内部换热部件的固态储氢罐，吸氢和放氢时间能分别控制在110 min和200 min左右，吸氢和放氢过程中床层最大温差分别在50 K和30 K以内，纯化后放氢过程的氢气回收率可达88%以上。

Abstract

With mild hydrogen storage conditions

high volumetric hydrogen storage density and intrinsic capability for hydrogen purification

metal hydrides (MH) offer unique advantages for the integrated application of high-density hydrogen storage and efficient hydrogen purification. Based on a cylindrical tank configuration with external circulating-water temperature control and a centrally penetrating mesh tube for hydrogen absorption and desorption

a three-dimensional simulation model of the hydrogen absorption/desorption and purification performance of titanium-manganese hydrogen storage alloys was established. By adjusting the temperature of the heat-transfer fluid

the absorption/desorption pressure and the convective heat-transfer coefficient

a three-factor and five-level simulation study on hydrogen absorption

desorption and purification performance was conducted. The results show that the temperature of the heat-transfer fluid has the greatest influence on hydrogen absorption/desorption and purification performance

followed by the absorption/desorption pressure

and then the convective heat-transfer coefficient. When the heat-transfer fluid temperature

hydrogen absorption pressure and convective heat-transfer coefficient range from 283 K to 303 K

0.8 MPa to 1.2 MPa

and 500 W/(m

·K) to 1000 W/(m

·K)

respectively

better hydrogen absorption and purification performance can be achieved. When the heat-transfer fluid temperature

hydrogen desorption pressure and convective heat-transfer coefficient range from 313 K to 333 K

0.08 MPa to 0.12 MPa

and 100

0 W/(m

·K) to 1652 W/(m

·K)

respectively

better hydrogen desorption performance can be achieved. For a solid-state hydrogen storage tank with a bed radius of 20 cm and no internal heat-exchange components

the hydrogen absorption and desorption durations can be controlled at approximately 110 min and 200 min

respectively. The maximum temperature differences within the bed during absorption and desorption can be kept within 50 K and 30 K

respectively. After purification

the hydrogen recovery rate during desorption can reach more than 88%.

关键词

Keywords

references

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