光热催化CO<sub>2</sub>甲烷化Ni基催化剂研究进展

刘洋; 田菊梅; 李海鹏; 宋文龙; 梁洁; 王杰; 雍晓静; 高新华

doi:10.12434/j.issn.2097-2547.20240522

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光热催化CO₂甲烷化Ni基催化剂研究进展

二氧化碳化工与催化转化 | 更新时间：2025-04-28

- 光热催化CO₂甲烷化Ni基催化剂研究进展
- 暂无标题
- 低碳化学与化工 2025, 50: 1-10.
- 作者机构：
  
  1.宁夏大学化学化工学院省部共建煤炭高效利用与绿色化工国家重点实验室，宁夏银川 750021
  2.宁夏计量质量检验检测研究院国家煤及煤化工产品质量检验检测中心（宁夏），宁夏银川 750200
  3.国家能源集团宁夏煤业有限责任公司煤炭化学工业技术研究院，宁夏银川 750411
- 作者简介：
  
  刘洋（1999—），硕士研究生，研究方向为CO2催化转化，E-mail：liuyang271210@163.com。
  雍晓静（1978—），博士，正高级工程师，研究方向为煤化工，E-mail：377748087@qq.com。
  高新华（1990—），博士，研究员，研究方向为碳一化学，E-mail：gxh@nxu.edu.cn；
- 基金信息：
  
  宁夏自然科学基金(2024AAC03407)
- DOI：10.12434/j.issn.2097-2547.20240522
  中图分类号： TQ426;O643.3
- 收稿日期：2024-12-31，
  
  修回日期：2025-03-10，
  
  网络出版日期：2025-04-27，
  
  纸质出版日期：2025-05-25
- 稿件说明：
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刘洋,田菊梅,李海鹏等.光热催化CO₂甲烷化Ni基催化剂研究进展[J].低碳化学与化工,

LIU Yang,TIAN Jumei,LI Haipeng,et al.Research progress on Ni-based catalysts for photothermal catalytic CO₂ methanation[J].Low-Carbon Chemistry and Chemical Engineering,
刘洋,田菊梅,李海鹏等.光热催化CO₂甲烷化Ni基催化剂研究进展[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20240522.

LIU Yang,TIAN Jumei,LI Haipeng,et al.Research progress on Ni-based catalysts for photothermal catalytic CO₂ methanation[J].Low-Carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20240522.

摘要

化石能源的过度利用使CO

排放量逐年增大，光热催化CO

甲烷化为碳资源循环利用提供了新途径。光热催化CO

甲烷化结合了光催化和热催化优势，通过降低反应活化能与温度，突破低温动力学限制，实现CO

的高效催化转化。Ni基催化剂因其活性高、成本低被用于光热催化CO

甲烷化。首先介绍了CO

甲烷化的反应机理和反应路径，然后探讨了不同载体对光热催化CO

甲烷化Ni基催化剂催化性能的调控机制，最后综述了新型负载型单原子Ni基催化剂的研究进展，为光热催化CO

甲烷化催化剂的设计与开发提供了思路。

Abstract

The excessive utilization of fossil energy has increased CO

emissions year by year. Photothermal catalytic CO

methanation is expected to provide a solution for the recycling of carbon resources. Photothermal catalytic CO

methanation combines the advantages of photocatalysis and thermocatalysis

breaking through the low-temperature kinetic limitations by reducing the activation energy barrier and the reaction temperature to achieve efficient catalytic conversion of CO

. Ni-based catalysts are used for photothermal catalytic CO

methanation due to it high activity and low cost. Firstly

the reaction mechanism and reaction path of photothermal catalytic CO

methanation were introduced. Then

the regulation mechanism of different supports on the catalytic performance of Ni-based catalysts for photothermal catalytic CO

methanation was studied. Finally

the research progress on the new monoatomic Ni-based catalysts was reviewed

providing ideas for the design and development of catalysts for photothermal CO

methanation reaction.

关键词

Keywords

references

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DOI：10.12434/j.issn.2097-2547.20240522

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光热催化CO₂甲烷化Ni基催化剂研究进展