浏览全部资源
扫码关注微信
1.河南地矿职业学院 地矿工程学院,河南 郑州 451464
2.河南科技大学 机电工程学院,河南 洛阳 471003
张涛(1983—),硕士,讲师,研究方向为矿物学和煤炭深加工,E-mail:zt195400200@163.com。
薛进学(1965—),博士,副教授,研究方向为煤炭设备加工与设计优化,E-mail:2655350684@qq.com。
收稿日期:2024-12-23,
修回日期:2025-02-19,
网络出版日期:2025-04-02,
移动端阅览
张涛,李丽娟,高东方等.低阶煤微波热解技术研究进展[J].低碳化学与化工,
ZHANG Tao,LI Lijuan,GAO Dongfang,et al.Research progress of low rank coal microwave pyrolysis technology[J].Low-carbon Chemistry and Chemical Engineering,
张涛,李丽娟,高东方等.低阶煤微波热解技术研究进展[J].低碳化学与化工, DOI:10.12434/j.issn.2097-2547.20240508.
ZHANG Tao,LI Lijuan,GAO Dongfang,et al.Research progress of low rank coal microwave pyrolysis technology[J].Low-carbon Chemistry and Chemical Engineering, DOI:10.12434/j.issn.2097-2547.20240508.
低阶煤直接燃烧效率低且污染严重,对煤炭资源造成极大浪费。实现低阶煤的高效清洁利用对缓解我国能源紧缺问题具有重要意义。微波热解技术具有能耗低、热解效率高和安全环保等优点,该技术为低阶煤热解提供了新思路。首先总结了微波热解技术原理及其在煤炭(主要针对低阶煤)热解方面的应用概况,然后分析了影响煤炭微波热解的因素,主要包括煤炭性质、微波吸收剂、热解气氛和共热解。最后对低阶煤微波热解技术发展面临的问题和未来研究方向进行了分析和展望。
The efficiency of direct combustion of low rank coal is low and pollution is serious
which causes great waste of coal resources. Realizing efficient and clean utilization of low rank coal is of great significance to alleviate energy shortage in China. Microwave pyrolysis technology has the advantages of low energy consumption
high pyrolysis efficiency and safety and environmental protection
which provides a new idea for low rank coal pyrolysis. Firstly
the principle of microwave pyrolysis technology and its application in coal (mainly low rank coal) pyrolysis were summarized. Then the factors affecting coal microwave pyrolysis were analyzed
including coal properties
microwave absorbers
pyrolysis atmospheres and co-pyrolysis. Finally
the problems and future research directions of low rank coal microwave pyrolysis technology were analyzed and prospected.
中华人民共和国国家统计局 . 中国统计年鉴 [M ] . 北京 : 中国统计出版社 , 2024 .
National Bureau of Statistics of the People’s Republic of China . China statistical yearbook [M ] . Beijing : China Statistics Press , 2024 .
尚建选 , 张喻 , 刘燕 . 陕煤集团低阶煤分质利用绿色低碳发展研究 [J ] . 中国煤炭 , 2022 , 48 ( 8 ): 39 - 47 .
SHANG J X , ZHANG Y , LIU Y . Research on green and low-carbon development of low-rank coal grading utilization in Shaanxi Coal and Chemical Industry Group [J ] . China Coal , 2022 , 48 ( 8 ): 39 - 47 .
王宁梓 , 徐祥 , 薛晓勇 , 等 . 煤加氢热解及热解焦气化特性试验研究 [J ] . 煤炭科学技术 , 2017 , 45 ( 1 ): 214 - 220 .
WANG N Z , XU X , XUE X Yet al . Experimental study of coal pyrolysis in hydrogen atmosphere and coal char gasification characters [J ] . Coal Science and Technology , 2017 , 45 ( 1 ): 214 - 220 .
刘巧妮 . 低变质煤与塑料微波共热解研究 [D ] . 西安 : 西安建筑科技大学 , 2012 .
LIU Q N . Study on co-pyrolysis of low rank coal and plastic with microwave [D ] . Xi’an : Xi’an University of Architecture and Technology , 2012 .
刘壮 , 田宜水 , 胡二峰 , 等 . 低阶煤热解影响因素及其工艺技术研究进展 [J ] . 洁净煤技术 , 2021 , 27 ( 1 ): 50 - 59 .
LIU Z , TIAN Y S , HU E F , et al . Research progress on influencing factors and process technology of low rank coal pyrolysis [J ] . Clean Coal Technology , 2021 , 27 ( 1 ): 50 - 59 .
李国亮 . CH 4 -CO 2 气氛下低阶煤微波热解研究 [D ] . 焦作 : 河南理工大学 , 2015 .
Li G L . Study on microwave pyrolysis of low rank coal under CH 4 -CO 2 atmosphere [D ] . Jiaozuo : Henan Polytechnic University , 2015 .
邹涛 , 刘军 , 曾梅 , 等 . 煤热解技术进展及工业应用现状 [J ] . 煤化工 , 2017 , 45 ( 1 ): 40 - 44 .
ZOU T , LIU J , ZENG M , et al . Progress of coal pyrolysis technology and its industrial application status [J ] . Coal Chemical Industry , 2017 , 45 ( 1 ): 40 - 44 .
王南 . 印尼褐煤微波热解特性的实验研究 [D ] . 鞍山 : 辽宁科技大学 , 2012 .
WANG N . The experimental study of the characteristics of microwave pyrolysis of Indonesia lignite [D ] . Anshan : University of Science and Technology Liaoning , 2012 .
WANG C G , WANG T , LIU Q , et al . Deep eutectic solvent assisted swell and highly efficient catalytic pyrolysis of raw coal [J ] . Fuel , 2024 , 362 .
刘淑琴 , 脱凯用 , 王莉萍 , 等 . 微波辅助铁催化低阶煤热解特性 [J ] . 煤炭学报 , 2020 , 45 ( 4 ): 1519 - 1526 .
LIU S Q , TUO K Y , WANG L P . Microwave-assisted iron-catalyzed pyrolysis characteristics of low rank coal [J ] . Journal of China Coal Society , 2020 , 45 ( 4 ): 1519 - 1526 .
HUANG J X , XU G , LIANG Y P , et al . Improving coal permeability using microwave heating technology—A review [J ] . Fuel , 2020 , 266 : 117022 .
REDDY R S , VINU R . Evidence of interactions in microwave-assisted co-pyrolysis of different varieties of coals [J ] . Journal of the Energy Institute , 2021 , 95 : 18 - 29 .
JEON S , KIM J , YANG D . Design of large-scale microwave cavity for uniform and efficient plastic heating [J ] . Polymers , 2022 , 14 : 541 .
MENENDEZ J A , ARENILLAS A , FIDALGO B , et al . Microwave heating processes involving carbon materials [J ] . Fuel Processing Technology , 2010 , 91 ( 1 ): 1 - 8 .
郝瑛轩 . 甲烷-低阶煤微波共热解研究 [D ] . 焦作 : 河南理工大学 , 2014 .
HAO Y X . Study on microwave co-pyrolysis of low rank coal and methane [D ] . Jiaozuo : Henan Polytechnic University , 2014 .
SU G C , ONG H C , CHEAH M Y , et al . Microwave-assisted pyrolysis technology for bioenergy recovery: Mechanism, performance, and prospect [J ] . Fuel , 2022 , 326 : 124983 .
MUSHTAQ F , MAT R , ANI F N . A review on microwave assisted pyrolysis of coal and biomass for fuel production [J ] . Renewable & Sustainable Energy Reviews , 2014 , 39 ( 6 ): 555 - 574 .
谢贤 , 吴素芳 . 微波辅助加热在热分解反应中的应用与进展 [J ] . 化学反应工程与工艺 , 2024 , 40 ( 5 ): 452 - 467 .
XIE X , WU S F . Application and progress of microwave-assisted heating in thermal decomposition reactions [J ] . Chemical Reaction Engineering and Technology , 2024 , 40 ( 5 ): 452 - 467 .
兰新哲 , 裴建军 , 宋永辉 , 等 . 一种低变质煤微波热解过程分析 [J ] . 煤炭转化 , 2010 , 33 ( 3 ): 15 - 18 .
LAN X Z , PEI J J , SONG Y H , et al . Analysis of low metamorphic coal during microwave pyrolysis [J ] . Coal Conversion , 2010 , 33 ( 3 ): 15 - 18 .
马红周 , 王耀宁 , 兰新哲 . 微波热解煤的实验研究 [J ] . 洁净煤技术 , 2009 , 15 ( 4 ): 54 - 55+59 .
MA H Z , WANG Y N , LAN X Z . Experimental study on microwave pyrolysis of coal [J ] . Clean Coal Technology , 2009 , 15 ( 4 ): 54 - 55+59 .
SONG Y H , SHI J W , FU J P , et al . Analysis of products by conventional and microwave induced pyrolysis for low rank coal [J ] . Advanced Materials Research , 2012 , 524 : 871 - 875 .
WANG Y F , ZHONG X , ZHAO H , et al . Comparative study of the composition and microstructural properties of semi-coke from microwave and conventional pyrolysis of low rank coal [J ] . Journal of the Energy Institute , 2024 , 116 : 101752 .
ELLISON C , ABDELSAYED V , SMITH M , et al . Comparative evaluation of microwave and conventional gasification of different coal types: Experimental reaction studies [J ] . Fuel , 2022 , 321 : 124055- .
李鹏 , 刘全润 , 方小可 , 等 . 煤的微波热解研究进展 [J ] . 化工进展 , 2016 , 35 ( S1 ): 130 - 134 .
LI P , LIU Q R , FANG X K , et al . Research progress of microwave pyrolysis for coal [J ] . Chemical Industry & Engineering Progress , 2016 , 35 ( S1 ): 130 - 134 .
金钦汉 , 戴树珊 , 黄卡玛 . 微波化学 [M ] . 北京 : 科学出版社 , 1999 .
JIN Q H , DAO S S , HUANG K M . Microwave chemistry [M ] . Beijing : Science Press , 1999 .
YAGMUR E , SKIMSEK E H , AKTAS Z , et al . Effect of CuO receptor on the liquid yield and composition of oils derived from liquefaction of coals by microwave energy [J ] . Energy Conversion & Management , 2008 , 49 ( 11 ): 3043 - 3050 .
XU G , HUANG J X , HU G Z , et al . Experimental study on effective microwave heating/fracturing of coal with various dielectric property and water saturation [J ] . Fuel Processing Technology , 2020 , 202 : 106378 .
LI J , ZHANG J J , XIAO Q L , et al . Experimental study on differential thermal response and pore-fracture structure evolution characteristics of coals under microwave irradiation: A case study of five different rank coals [J ] . Energy & Fuels , 2024 , 38 ( 11 ): 9497 - 9514 .
LIU H Y , XU L , JIN Y , et al . Effect of coal rank on structure and dielectric properties of chars [J ] . Fuel , 2015 , 153 : 249 - 256 .
何选明 . 煤化学 [M ] . 北京 : 冶金工业出版社 , 2010 .
HE X M . Coal chemistry [M ] . Beijing : Metallurgical Industry Press , 2010 .
CHEMERINSKIY M , KUZMIN A , PINCHUK V , et al . Microwave-induced alterations in the structure of coals at different metamorphic stages [J ] . Fuel , 2025 , 381 : 133326 .
COELLO R J . Physics of dielectrics for the engnieer [M ] . New York : Elsevier Scientific Publishing Company , 1979 .
CLARENCE , ZENER H H . A theory of the electrical breakdown of solid dielectrics [J ] . Mathematical Physics in One Dimension , 1966 , 145 ( 855 ): 292 - 298 .
PENG Z W , LIN X L , LI Z Z , et al . Dielectric characterization of Indonesian low-rank coal for microwave processing [J ] . Fuel Processing Technology , 2017 , 156 : 171 - 177 .
PENG Z W , HWANG J Y , KIMB G , et al . Microwave absorption capability of high volatile bituminous coal during pyrolysis [J ] . Energy & Fuels , 2012 , 26 ( 8 ): 5146 - 5151 .
PENG Z W , LIN X L , WU X J , et al . Microwave absorption characteristics of anthracite during pyrolysis [J ] . Fuel Processing Technology , 2016 , 150 : 58 - 63 .
王晴东 . 基于多物理场的褐煤微波热解制气特性及机理研究 [D ] . 武汉 : 武汉科技学 , 2016 .
WANG Q D . The characteristics and mechanism research of lignite microwave pyrolysis gasification based on physical fields [D ] . Wuhan : Wuhan University of Science and Technology , 2016 .
LIU H , XU L , JIN Y , et al . Effect of coal rank on structure and dielectric properties of chars [J ] . Fuel , 2015 , 153 : 249 - 256 .
ZHENG X Z , WANG B Y , GUO J , et al . Factors influencing dielectric properties of coal of different ranks [J ] . Fuel , 2019 , 258 : 811 - 819 .
MAXWELL J C . Treatise on electricity and magnetism [M ] . Oxford : Clarendon , 1881 .
ZHAO X Q , GUO B W , WANG W L , et al . Experimental study on microwave pyrolysis of three Chinese lignite [J ] . Journal of Analytical & Applied Pyrolysis , 2017 , 124 : 303 - 309 .
MUSHTAQ F , MAT R , ANI F N . Fuel production from microwave assisted pyrolysis of coal with carbon surfaces [J ] . Energy Conversion & Management , 2016 , 110 : 142 - 153 .
REDDY B R , VINU R . Microwave assisted pyrolysis of Indian and Indonesian coals and product characterization [J ] . Fuel Processing Technology , 2016 , 154 : 96 - 103 .
LIU H P , CHEN T P , LI Y , et al . Temperature rise characteristics of Zhundong coal during microwave pyrolysis [J ] . Fuel Processing Technology , 2016 , 148 : 317 - 323 .
ZHAO Y , SHI Q , LI Z L , et al . Preparation of carbon-based microwave absorbing materials by hybrid activation pyrolysis of lignin and coal [J ] . Materials Letters , 2022 , 328 : 133155 .
ZHOU F , CHENG J , LIU J Z , et al . Activated carbon and graphite facilitate the upgrading of Indonesian lignite with microwave irradiation for slurryability improvement [J ] . Fuel , 2016 , 170 : 39 - 48 .
YAGMUR E , SIMSEK E H , AKTAS Z , et al . Effect of CuO receptor on the liquid yield and composition of oils derived from liquefaction of coals by microwave energy [J ] . Energy Conversion & Management , 2008 , 49 ( 11 ): 3043 - 3050 .
LIU S Q , TUO K Y , WANG L P , et al . Microwave-assisted metal-catalyzed pyrolysis of low-rank coal: Promising option towards obtaining high-quality products [J ] . Journal of The Energy Institute , 2020 , 93 : 1602 - 1614 .
ZHANG Y J , CHEN G , WANG L P , et al . Microwave-assisted pyrolysis of low-rank coal with K 2 CO 3 , CaCl 2 , and FeSO 4 catalysts [J ] . ACS Omega , 2020 , 5 ( 28 ): 17232 - 17241
WANG N , YU J L , TAHMASEBI A , et al . Experimental study on microwave pyrolysis of an indonesian low-rank coal [J ] . Energy & Fuels , 2014 , 28 ( 1 ): 254 - 263 .
WU L , ZHOU J , YANG R R , et al . Enhanced catalytic microwave pyrolysis of low-rank coal using Fe 2 O 3 @bluecoke absorber prepared by a simple mechanical ball milling [J ] . Journal of the Energy Institute , 2021 , 95 : 193 - 205 .
WU L , ZHOU J , YANG R R , et al . Novel approach for enhanced catalytic microwave pyrolysis of low-rank coal [J ] . Energy & Fuels , 2020 , 34 ( 8 ): 9540 - 9551 .
GE S , YEK P N Y , CHENG Y W , et al . Progress in microwave pyrolysis conversion of agricultural waste to value-added biofuels: A batch to continuous approach [J ] . Renewable and Sustainable Energy Reviews , 2021 , 135 : 110148 .
周军 , 吴雷 , 周晶晶 , 等 . 煤催化微波热解技术及其碳基吸波催化剂研究进展 [J ] . 化工进展 , 2019 , 38 ( 9 ): 4060 - 4074 .
ZHOU J , WU L , ZHOU J J , et al . Research progress on catalytic microwave pyrolysis technology of coal and its carbon-based microwave absorbing catalyst [J ] . Chemical Industry and Engineering Progress , 2019 , 38 ( 9 ): 4060 - 4074 .
GE L C , LIU X Y , FENG H C , et al . The interaction between microwave and coal: A discussion on the state-of-the-art [J ] . Fuel , 2022 , 314 : 123140 .
WU L , ZHOU J , ZHOU J J , et al . Temperature-rising characteristics and product analysis of low-rank coal microwave pyrolysis under CH 4 atmosphere [J ] . Journal of Analytical and Applied Pyrolysis , 2019 , 141 : 104632 .
李国亮 , 刘全润 , 方小可 , 等 . 神木煤CH 4 微波共热解产物生成规律研究 [J ] . 煤炭转化 , 2015 , 38 ( 4 ): 12 - 15 .
LI G L , LIU Q R , FANG X K , et al . Study on product generating rule of Shenmu coal-CH 4 microwave co-pyrolysis [J ] . Coal Conversion , 2015 , 38 ( 4 ): 12 - 15 .
周军 , 杨哲 , 吴雷 , 等 . CO 2 气氛中低变质煤微波热解研究 [J ] . 煤炭学报 , 2015 , 40 ( 10 ): 2465 - 2471 .
ZHOU J , YANG Z , WU L , et al . Study on microwave pyrolysis of low rank coal under CO 2 atmosphere [J ] . Journal of China Coal Society , 2015 , 40 ( 10 ) : 2465 - 2471 .
周军 , 杨哲 , 吴雷 , 等 . H 2 气氛中低变质煤微波热解研究 [J ] . 煤炭转化 , 2015 , 38 ( 3 ): 22 - 26 .
ZHOU J , YANG Z , WU L , et al . Study on microwave pyrolysis of low rank coal under H 2 atmosphere [J ] . Coal Conversion , 2015 , 38 ( 3 ): 22 - 26 .
吴雷 , 周军 . N 2 环境下煤的微波热解研究 [J ] . 辽宁化工 , 2015 , 44 ( 5 ): 526 - 529 .
WU L , ZHOU J . Research on the microwave pyrolysis of coal in N 2 [J ] . Liaoning Chemical Industry , 2015 , 44 ( 5 ): 526 - 529 .
周军 , 杨哲 , 刘晓峰 , 等 . 低变质煤-循环煤气微波共热解研究 [J ] . 光谱学与光谱分析 , 2016 , 36 ( 2 ): 459 - 465 .
ZHOU J , YANG Z , LIU X F , et al . Study on microwave co-pyrolysis of low rank coal and circulating coal gas [J ] . Spectroscopy and Spectral Analysis , 2016 , 36 ( 2 ): 459 - 465 .
ZHOU J , WU L , LIANG K , et al . Spectroscopic analysis of products from low-rank coal microwave pyrolysis: Effect of reaction atmosphere [J ] . Journal of Applied Spectroscopy , 2020 , 87 : 745 - 752 .
SURESH A , ALAGUSUNDARAM A , KUMAR P S , et al . Microwave pyrolysis of coal, biomass and plastic waste: A review [J ] . Environmental Chemistry Letters , 2021 , 19 : 3609 - 3629 .
GU S Q , XU Z Q , REN Y G , et al . Microwave co-pyrolysis of lignite with direct coal liquefaction residue: Synergistic effects and product combustion characteristics [J ] . Journal of cleaner production , 2021 , 325 : 129293
ZHAO X Q , TIAN Y S , GUO B W , et al . Microwave steam gasification of semi-coke derived from co-pyrolysis of fungus chaff and lignite [J ] . International Journal of Coal Preparation and Utilization , 2018 , 41 ( 11 ): 830 – 843
VYAS A , CHELLAPPA T , GOLDFARB J L . Porosity development and reactivity changes of coal-biomass blends during co-pyrolysis at various temperatures [J ] . Journal of Analytical & Applied Pyrolysis , 2017 , 124 : 79 - 88 .
MELENDI-ESPINA S , ALVAREZ R , DIEZ M A , et al . Coal and plastic waste co-pyrolysis by thermal analysis-mass spectrometry [J ] . Fuel Processing Technology , 2015 , 137 : 351 - 358 .
兰新哲 , 刘巧妮 , 宋永辉 . 低变质煤与塑料微波共热解研究 [J ] . 煤炭转化 , 2012 , 35 ( 1 ): 16 - 19 .
LAN X Z , LIU Q N , SONG Y H . Study on co-pyrolysis of low rank coal and plastic with microwave [J ] . Coal Conversion , 2012 , 35 ( 1 ): 16 - 19 .
HUSSAIN Z , KHANK M , BBASHIEER N , et al . Co-liquefaction of Makarwal coal and waste polystyrene by microwave-metal interaction pyrolysis in copper coil reactor [J ] . Journal of Analytical & Applied Pyrolysis , 2011 , 90 ( 1 ): 53 - 55 .
HUSSAIN K , HUSSAIN Z , GULAB H , et al . Production of fuel by co-pyrolysis of Makarwal coal and waste polypropylene through a hybrid heating system of convection and microwaves [J ] . International Journal of Energy Research , 2016 , 40 ( 11 ): 1532 - 1540 .
MISTRY C R , PANDIAN S , CHOKSI H . Investigating the impact of microwave and conventional heating sources on the co-pyrolysis of plastics with non-biomass materials [J ] . Journal of Analytical and Applied Pyrolysis , 2024 , 177 : 106364 .
宋永辉 , 苏婷 , 兰新哲 , 等 . 微波场中长焰煤与焦煤共热解实验研究 [J ] . 煤炭转化 , 2011 , 34 ( 3 ): 7 - 10 .
SONG Y H , SU T , LAN X Z , et al . Microwave co-pyrolysis study on long flame coal and coking coal [J ] . Coal Conversion , 2011 , 34 ( 3 ): 7 - 10 .
宋永辉 , 折建梅 , 兰新哲 , 等 . 微波场中低变质煤与油页岩的热解 [J ] . 煤炭转化 , 2012 , 35 ( 2 ): 22 - 26 .
SONG Y H , SHE J M , LAN X Z , et al . Pyrolysis of low metamorphic coal and oil shale by microwave irradiation [J ] . Coal Conversion , 2012 , 35 ( 2 ): 22 - 26 .
LU Y , WANG Y , ZHANG J , et al . Investigation on the characteristics of pyrolysates during co-pyrolysis of Zhundong coal and Changji oil shale and its kinetics [J ] . Energy , 2020 , 200 : 117529 .
ZHU Y , LI C C , CAO H S , et al . Effects of spatial distribution of tar-rich coal and oil shale and primary factors on product characteristics during microwave co-pyrolysis [J ] . Fuel , 2025 , 385 : 134085 .
WU L , LIU J , XU P , et al . Biomass hydrogen donor assisted microwave pyrolysis of low-rank pulverized coal: Optimization, product upgrade and synergistic mechanism [J ] . Waste Management , 2022 , 143 : 177 - 185 .
WU L , LIU J , ZHOU J , et al . Evaluation of tar from the microwave co-pyrolysis of low-rank coal and corncob using orthogonal-test-based grey relational analysis (GRA) [J ] . Journal of Cleaner Production , 2022 , 337 : 130362 .
WU L , GUAN Y N , ZHOU J , et al . Effects of variable amounts of volatiles in corncob on microwave co-pyrolysis of low-rank coal and corncob [J ] . Fuel , 2023 , 332 : 126133 .
HASSAN H , LIM J K , HAMEED B H . Recent progress on biomass co-pyrolysis conversion into high-quality bio-oil [J ] . Bioresource Technology , 2016 , 221 : 645 - 655 .
0
浏览量
0
下载量
0
CNKI被引量
关联资源
相关文章
相关作者
相关机构