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中国石油大学(华东) 重质油全国重点实验室,山东 青岛 266580
苑馨月(2001—),硕士研究生,研究方向为氢甲酰化催化,E-mail:yuanxinyue_2001@163.com。
潘原(1989—),博士,教授,研究方向为绿色能源催化,E-mail:panyuan@upc.edu.cn。
收稿日期:2024-12-19,
修回日期:2025-01-19,
网络出版日期:2025-03-07,
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苑馨月,国含,潘原.双原子催化剂在加氢反应中的应用研究进展[J].低碳化学与化工,
YUAN Xinyue,GUO Han,PAN Yuan.Research progress on application of diatomic catalysts in hydrogenation reactions[J].Low-carbon Chemistry and Chemical Engineering,
苑馨月,国含,潘原.双原子催化剂在加氢反应中的应用研究进展[J].低碳化学与化工, DOI:10.12434/j.issn.2097-2547.20240502.
YUAN Xinyue,GUO Han,PAN Yuan.Research progress on application of diatomic catalysts in hydrogenation reactions[J].Low-carbon Chemistry and Chemical Engineering, DOI:10.12434/j.issn.2097-2547.20240502.
高效加氢催化剂的设计和开发是推动加氢反应相关应用的关键。双原子催化剂因具有协同的活性位点和双原子间较强的相互作用,成为加氢反应催化剂研究的热点。综述了双原子催化剂在加氢反应中的应用研究进展,总结了影响双原子催化剂加氢反应催化性能的调控机制,并对双原子催化剂在加氢反应中面临的挑战和未来发展进行了分析和展望。
The design and development of high efficiency hydrogenation catalysts is the key to promote the relate application of hydrogenation reaction. Diatomic catalysts have become the research hotspot in hydrogenation catalysts because of their synergistic active sites and strong interactions between diatoms. The research progress on application of diatomic catalysts in hydrogenation reactions were reviewed
the regulatory mechanisms affecting the catalytic performances of diatomic catalysts in hydrogenation reactions were summarized
and the challenges and future development of diatomic catalysts in hydrogenation reactions were analyzed and prospected.
STORCH H H . Chemistry of coal hydrogenation [J ] . Chemical Reviews , 1941 , 29 ( 3 ): 483 - 499 .
ZHANG L L , ZHOU M X , WANG A Q , et al . Selective hydrogenation over supported metal catalysts: From nanoparticles to single atoms [J ] . Chemical Reviews , 2020 , 120 ( 2 ): 683 - 733 .
REVUNOVA K , NIKONOV G I . Main group catalysed reduction of unsaturated bonds [J ] . Dalton Transactions: An International Journal of Inorganic Chemistry , 2015 , 44 ( 3 ): 840 - 866 .
LIU G F , CHEN C J , CHEN J J . Catalytic and electrocatalytic hydrogenation of nitroarenes [J ] . Journal of Physical Chemistry C , 2023 , 127 ( 9 ): 4375 - 4386 .
闫冰洁 , 曹佳慧 , 孙晓颖 , 等 . 二氧化碳催化加氢金属有机框负载型金属催化剂的研究进展 [J ] . 中国科学: 化学 , 2024 , 12 ( 54 ): 2499 - 2520 .
YAN B J , CAO J H , SUN X Y , et al . Recent developments of MOF-supported metal catalysts for CO 2 hydrogenation [J ] . Scientia Sinica Chimica , 2024 , 12 ( 54 ): 2499 - 2520 .
CHEN M D , GUPTA G , ORDONEZ C W , et al . Intermetallic nanocatalyst for highly active heterogeneous hydroformylation [J ] . Journal of the American Chemical Society , 2021 , 143 ( 49 ): 20907 - 20915 .
QIAO B T , WANG A Q , YANG X F , et al . Single-atom catalysis of CO oxidation using Pt 1 /FeO x [J ] . Nature Chemistry , 2011 , 3 ( 8 ): 634 - 641 .
SHI Y T , ZHAO C Y , WEI H S , et al . Single-atom catalysis in mesoporous photovoltaics: The principle of utility maximization [J ] . Advanced Materials , 2014 , 26 ( 48 ): 8147 - 8153 .
ZHANG L L , WANG A Q , MILLER J T , et al . Efficient and durable Au alloyed Pd single-atom catalyst for the ullmann reaction of aryl chlorides in water [J ] . ACS Catalysis , 2014 , 4 ( 5 ): 1546 - 1553 .
YANG X F , WANG A Q , QIAO B T , et al . Single-atom catalysts: A new frontier in heterogeneous catalysis [J ] . Accounts of Chemical Research , 2013 , 46 ( 8 ): 1740 - 1748 .
CHEN Z W , YAN J M , JIANG Q . Single or double: Which is the altar of atomic catalysts for nitrogen reduction reaction? [J ] . Small Methods , 2019 , 3 ( 6 ): 1800291 .
BAKANDRITSOS A , KADAM R G , KUMAR P , et al . Mixed-valence single-atom catalyst derived from functionalized graphene [J ] . Advanced Materials , 2019 , 31 ( 17 ): 1900323 .
LI L B , YUAN K , CHEN Y W . Breaking the scaling relationship limit: From single-atom to dual-atom catalysts [J ] . Accounts of Materials Research , 2022 , 3 ( 6 ): 584 - 596 .
ZHANG J , HUANG Q A , WANG J , et al . Supported dual-atom catalysts: Preparation, characterization, and potential applications [J ] . Chinese Journal of Catalysis , 2020 , 41 ( 5 ): 783 - 798 .
HU Y F , LI Z S , LI B L , et al . Recent progress of diatomic catalysts: General design fundamentals and diversified catalytic applications [J ] . Small , 2022 , 18 ( 46 ): 2203589 .
ZHANG W Y , CHAO Y G , ZHANG W S , et al . Emerging dual-atomic-site catalysts for efficient energy catalysis [J ] . Advanced Materials , 2021 , 33 ( 36 ): 2102576 .
YING Y R , LUO X , QIAO J L , et al . “ More is different”: Synergistic effect and structural engineering in double-atom catalysts [J ] . Advanced Functional Materials , 2021 , 31 ( 3 ): 2007423 .
ZHU H D , REN X F , YANG X X , et al . Fe-based catalysts for nitrogen reduction toward ammonia electrosynthesis under ambient conditions [J ] . Susmat , 2022 , 2 ( 3 ): 214 - 242 .
HEPBURN C , ADLEN E , BEDDINGTON J , et al . The technological and economic prospects for CO 2 utilization and removal [J ] . Nature , 2019 , 575 ( 7781 ): 87 - 97 .
JIANG F , WANG S S , LIU B , et al . Insights into the influence of CeO 2 crystal facet on CO 2 hydrogenation to methanol over Pd/CeO 2 catalysts [J ] . ACS Catalysis , 2020 , 10 ( 19 ): 11493 - 11509 .
GAO M B , LIH , LIU W J , et al . Imaging spatiotemporal evolution of molecules and active sites in zeolite catalyst during methanol-to-olefins reaction [J ] . Nature Communications , 2020 , 11 ( 1 ): 3641 .
KANG J C , HE S , ZHOU W , et al . Single-pass transformation of syngas into ethanol with high selectivity by triple tandem catalysis [J ] . Nature Communications , 2020 , 11 ( 1 ): 827 .
CUI M , QIAN Q L , HE Z H , et al . Bromide promoted hydrogenation of CO 2 to higher alcohols using Ru-Co homogeneous catalyst [J ] . Chemical Science , 2016 , 7 ( 8 ): 5200 - 5205 .
QIAN Q L , CUI M , HE Z H , et al . Highly selective hydrogenation of CO 2 into C 2+ alcohols by homogeneous catalysis [J ] . Chemical Science , 2015 , 6 ( 10 ): 5685 - 5689 .
CHEN J , ZHANG D J , LIU B , et al . Photoinduced precise synthesis of diatomic Ir 1 Pd 1 -In 2 O 3 for CO 2 hydrogenation to methanol via angstrom-scale-distance dependent synergistic catalysis [J ] . Angewandte Chemie International Edition , 2024 , 63 ( 13 ): e202401168 .
YUAN F F , WANG X , MA T , et al . Enhanced conversion of CO 2 into C 2 H 4 on single atom Cu-anchored graphitic carbon nitride: Synergistic diatomic active sites interaction [J ] . Journal of Colloid and Interface Science , 2024 , 667 : 291 - 302 .
MO S P , ZHAO X Y , LI S D , et al . Non-interacting Ni and Fe dual-atom pair sites in N-doped carbon catalysts for efficient concentrating solar-driven photothermal CO 2 reduction [J ] . Angewandte Chemie International Edition , 2023 , 62 ( 50 ): e202313868 .
LI Y Z , WEI B , ZHU M H , et al . Synergistic effect of atomically dispersed Ni-Zn pair sites for enhanced CO 2 electroreduction [J ] . Advanced Materials , 2021 , 33 ( 41 ): e2102212 .
WANG X H , MAO Z C , WEI G P , et al . Synergistic effect of nickel and calcium dual-atomic sites to facilitate electrochemical CO 2 reduction to methanol: Combining high activity and selectivity [J ] . Applied Surface Science , 2023 , 639 : 158243 .
YOON C , YANG M X , SOMORJAI G A , et al . Hydrogenation of 1,3-butadiene on platinum surfaces of different structures [J ] . Catalysis Letters , 1997 , 46 : 37 - 41 .
HOU R J , POROSOFF M D , CHEN J G , et al . Effect of oxide supports on Pd-Ni bimetallic catalysts for 1,3-butadiene hydrogenation [J ] . Applied Catalysis A: General , 2015 , 490 : 17 - 23 .
ZHENG K , WU Y , HU Z X , et al . Progress and perspective for conversion of plastic wastes into valuable chemicals [J ] . Chemical Society Reviews , 2023 , 52 ( 1 ): 8 - 29 .
LI H L , WANG L B , DAI Y Z , et al . Synergetic interaction between neighbouring platinum monomers in CO 2 hydrogenation [J ] . Nature Nanotechnology , 2018 , 13 ( 5 ): 411 - 417 .
BAI L C , HSU C S , ALEXANDER D T L , et al . Double-atom catalysts as a molecular platform for heterogeneous oxygen evolution electrocatalysis [J ] . Nature Energy , 2021 , 6 ( 11 ): 1054 - 1066 .
LI R Z , WANG D S . Superiority of dual-atom catalysts in electrocatalysis: One step further than single‐atom catalysts [J ] . Advanced Energy Materials , 2022 , 12 ( 9 ): 2103564 .
LI R Z , ZHANG Z D , LIANG X , et al . Polystyrene waste thermochemical to ethylbenzene by a N-bridged Co, Ni dual-atom catalyst [J ] . Journal of the American Chemical Society , 2023 , 145 ( 29 ): 16218 - 16227 .
FU J H , DONG J H , SI R , et al . Synergistic effects for enhanced catalysis in a dual single-atom catalyst [J ] . ACS Catalysis , 2021 , 11 ( 4 ): 1952 - 1961 .
ZHAO L M , QIN X T , ZHANG X R , et al . A magnetically separable Pd single-atom catalyst for efficient selective hydrogenation of phenylacetylene [J ] . Advanced Materials , 2022 , 34 ( 20 ): e2110455 .
YANG L , YU S Y , PENG C , et al . Semihydrogenation of phenylacetylene over nonprecious Ni-based catalysts supported on AlSBA-15 [J ] . Journal of Catalysis , 2019 , 370 : 310 - 320 .
DENG X , BAI R H , CHAI Y C , et al . Homogeneous-like alkyne selective hydrogenation catalyzed by cationic nickel confined in zeolite [J ] . CCS Chemistry , 2022 , 4 : 949 - 962 .
LIU K L , QIN R X , ZHENG N F . Insights into the interfacial effects in heterogeneous metal nanocatalysts toward selective hydrogenation [J ] . Journal of the American Chemical Society , 2021 , 143 ( 12 ): 4483 - 4499 .
JORGENSEN M , GRONBRCK H . Selective acetylene hydrogenation over single-atom alloy nanoparticles by kinetic monte carlo [J ] . Journal of the American Chemical Society , 2019 , 141 ( 21 ): 8541 - 8549 .
LI Z X , HU M L , LIU J H , et al . Mesoporous silica stabilized MOF nanoreactor for highly selective semi-hydrogenation of phenylacetylene via synergistic effect of Pd and Ru single site [J ] . Nano Research , 2022 , 15 ( 3 ): 1983 - 1992 .
LIU H , ZHU P , YANG D , et al . Pd-Mn/NC dual single-atomic sites with hollow mesopores for the highly efficient semihydrogenation of phenylacetylene [J ] . Journal of the American Chemical Society , 2024 , 146 ( 3 ): 2132 - 2140 .
MARTÍN A J , MONDELLI C , JAYDEV S D , et al . Catalytic processing of plastic waste on the rise [J ] . Chem , 2021 , 7 ( 6 ): 1487 - 1533 .
BU J , LIU Z P , MA W X , et al . Selective electrocatalytic semihydrogenation of acetylene impurities for the production of polymer-grade ethylene [J ] . Nature Catalysis , 2021 , 4 ( 7 ): 557 - 564 .
STUDT F , ABILD-PEDERSEN F , BLIGAARD T , et al . Identification of non-precious metal alloy catalysts for selective hydrogenation of acetylene [J ] . Science , 2008 , 320 ( 5881 ): 1320 - 1322 .
YUE Y X , WANG B L , JIN C X , et al . Tailoring Cu-Zn dual-atom sites with reordering d-orbital splitting manner for highly efficient acetylene semihydrogenation [J ] . ACS Catalysis , 2024 , 14 ( 6 ): 3900 - 3911 .
HUANG F , PENG M , CHEN Y L , et al . Low-temperature acetylene semi-hydrogenation over the Pd 1 -Cu 1 dual-atom catalyst [J ] . Journal of the American Chemical Society , 2022 , 144 ( 40 ): 18485 - 18493 .
李雪峰 . 芳硝基化合物选择性加氢催化剂的开发及反应机理研究 [D ] . 杭州 : 浙江大学 , 2018 .
LI X F . Catalyst designs and mechanism studies for selective hydrogenation of nitroarenes [D ] . Hangzhou : Zhejiang University , 2018 .
蔡宇晨 , 徐子涵 , 王丽丽 , 等 . 芳硝基化合物加氢催化剂研究进展 [J ] . 山东化工 , 2023 , 52 ( 12 ): 84 - 86 .
CAI Y C , XU Z H , WANG L L , et al . Advances in hydrogenation catalysts for aromatic nitro compounds [J ] . Shandong Chemical Industry , 2023 , 52 ( 12 ): 84 - 86 .
MCGARRIGLE E M , GILHEANY D G . Chromium- and manganese-salen promoted epoxidation of alkenes [J ] . Chemical Reviews , 2005 , 105 ( 5 ): 1563 - 1602 .
BAUER I , KNÖLKER H . Iron catalysis in organic synthesis [J ] . Chemical Reviews , 2015 , 115 ( 9 ): 3170 - 3387 .
NIE R F , WANG J H , WANG L N , et al . Platinum supported on reduced graphene oxide as a catalyst for hydrogenation of nitroarenes [J ] . Carbon , 2012 , 50 ( 2 ): 586 - 596 .
LI Z , MENG F C , YANG X C , et al . The role of Mo single atoms and clusters in enhancing Pt catalyst for benzene hydrogenation: Distinguishing between benzene spillover and electronic effect [J ] . ACS Catalysis , 2024 , 14 ( 7 ): 5016 - 5026 .
DENG P C , DUAN J L , LIU F L , et al . Atomic insights into synergistic nitroarene hydrogenation over nanodiamond-supported Pt 1 -Fe 1 dual single atom catalyst [J ] . Angewandte Chemie International Edition , 2023 , 135 ( 36 ): e202307853 .
TIAN S B , WANG B X , GONG W B , et al . Dual-atom Pt heterogeneous catalyst with excellent catalytic performances for the selective hydrogenation and epoxidation [J ] . Nature Communications , 2021 , 12 ( 1 ): 3181 .
ZHANG Y , CHENG Y J , WANG X L , et al . Enhanced hydrogenation properties of Pd single atom catalysts with atomically dispersed Ba sites as electronic promoters [J ] . ACS Catalysis , 2022 , 12 ( 24 ): 15091 - 15096 .
ZHANG B X , KUBIS C , FRANKE R . Hydroformylation catalyzed by unmodified cobalt carbonyl under mild conditions [J ] . Science , 2022 , 377 ( 6611 ): 1223 - 1227 .
LI H Q , WU J Y , JIANG Z , et al . Hydroformylation of pyrolysis oils to aldehydes and alcohols from polyolefin waste [J ] . Science , 2023 , 381 ( 6658 ): 660 - 666 .
蔡力宏 , 梁雪美 . 高碳醇的市场应用及煤基费托合成高碳醇的生产工艺 [J ] . 合成材料老化与应用 , 2017 , 46 ( 6 ): 123 - 127 .
CAI L H , LIANG X M . Application of higher alcohol and technology of fischer-tropsch higher alcohol [J ] . Synthetic Materials Aging and Application , 2017 , 46 ( 6 ): 123 - 127 .
魏岚 , 贺德华 . 高碳烯烃氢甲酰化研究 [J ] . 化学进展 , 2005 , 17 ( 2 ): 217 - 224 .
WEI L , HE X H . Studies of hydroformylation of higher olefins [J ] . Progress in Chemistry , 2005 , 17 ( 2 ): 217 - 224 .
PÜSCHEL S , STÖRTTE S , TOPPHOFF J , et al . Green process design for reductive hydroformylation of renewable olefin cuts for drop-in diesel fuels [J ] . ChemSusChem , 2021 , 14 ( 23 ): 5226 - 5234 .
FURST M R L , KORKMAZ V , GAIDE T , et al . Tandem reductive hydroformylation of castor oil derived substrates and catalyst recycling by selective product crystallization [J ] . ChemCatChem , 2017 , 9 ( 23 ): 4319 - 4323 .
JESKE K , RÖSLER T , BELLEFLAMME M , et al . Direct conversion of syngas to higher alcohols via tandem integration of Fischer-Tropsch synthesis and reductive hydroformylation [J ] . Angewandte Chemie International Edition , 2022 , 61 ( 31 ): e202201004 .
ZHANG Y , LIU L Y , WANG Z Y , et al . Tandem hydroformylation/hydrogenation of olefins to alcohols using atomically dispersed bifunctional catalysts [J ] . Science China Chemistry , 2024 , 67 ( 11 ): 3706 - 3711 .
RO I , QI J , LEE S , et al . Bifunctional hydroformylation on heterogeneous Rh-WO x pair site catalysts [J ] . Nature , 2022 , 609 ( 7926 ): 287 - 292 .
YANG D , TAO S , ZHU H Y , et al . Construction of Rh-N 4 single atoms and Rh clusters dual-active sites for synergistic heterogeneous hydroformylation of olefins with ultra-high turnover frequency [J ] . Chemical Engineering Journal , 2024 , 479 : 147505 .
龙庆兴 , 许思维 . 重油加氢技术特点和发展趋势研究 [J ] . 中国石油和化工标准与质量 , 2020 , 40 ( 14 ): 247 - 248 .
LONG Q X , XU S W . Research on the characteristics and development trend of heavy oil hydrogenation technology [J ] . China Petroleum and Chemical Standards and Quality , 2020 , 40 ( 14 ): 247 - 248 .
RANA M S , SÁMANO V , ANCHEYTA J , et al . A review of recent advances on process technologies for upgrading of heavy oils and residua [J ] . Fuel , 2007 , 86 ( 9 ): 1216 - 1231 .
SUN G X , LIU D Y , SHI H F , et al . Oxygen-vacancy-induced built-in electric field across MoCo dual-atomic site catalyst for promoting hydrogen spillover in hydrocracking and hydrodesulfurization [J ] . ACS Catalysis , 2024 , 14 ( 5 ): 3208 - 3217 .
REN W H , TAN X , YANG W F , et al . Isolated diatomic Ni-Fe metal-nitrogen sites for synergistic electroreduction of CO 2 [J ] . Angewandte Chemie International Edition , 2019 , 131 ( 21 ): 7046 - 7050 .
SHAN J Q , LIAO J W , YE C , et al . The dynamic formation from metal-organic frameworks of high-density platinum single-atom catalysts with metal-metal interactions [J ] . Angewandte Chemie International Edition , 2022 , 61 ( 48 ): e202213412 .
ZHANG Y Q , YAN J S , YOU R S , et al . The effect of the interaction between Cu single atoms and Pt nanoparticles on the selective hydrogenation of epichlorohydrin to chloro-propanol [J ] . Applied Surface Science , 2023 , 628 : 157382 .
LIANG M H , WANG X D , LIU H Q , et al . Excellent catalytic properties over nanocomposite catalysts for selective hydrogenation of halonitrobenzenes [J ] . Journal of Catalysis , 2008 , 255 ( 2 ): 335 - 342 .
WANG D , VILLA A , PORTA F , et al . Bimetallic gold/palladium catalysts: Correlation between nanostructure and synergistic effects [J ] . The Journal of Physical Chemistry C , 2008 , 112 ( 23 ): 8617 - 8622 .
DOSTAGIR N H M , TOMUSCHAT C R , OSHIRO K , et al . Mitigating the poisoning effect of formate during CO 2 hydrogenation to methanol over Co-containing dual-atom oxide catalysts [J ] . JACS Au , 2024 , 4 ( 3 ): 1048 - 1058 .
LIU T , CHEN Y D , XU A R , et al . Regulating atomic Fe-Rh site distance for efficient oxygen reduction reaction [J ] . Science China Chemistry , 2024 , 67 ( 4 ): 1352 - 1359 .
TANG M H , SHEN J , WANG Y D , et al . Highly efficient recycling of polyester wastes to diols using Ru and Mo dual-atom catalyst [J ] . Nature Communications , 2024 , 15 ( 1 ): 5630 - 5640 .
ZHAO Y , GU Q Q , SUN X , et al . Steric-confinement Rh 2 /MoS 2 dual-atom catalyst directionally modulating adsorption configuration of ester group to boost ethanol synthesis [J ] . Chem , 2024 , 10 ( 11 ): 3342 - 3363 .
YAO Z B , CHENG H , XU Y F , et al . Hydrogen radical-boosted electrocatalytic CO 2 reduction using Ni-partnered heteroatomic pairs [J ] . Nature Communications , 2024 , 15 ( 1 ): 9881 .
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