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CO2加氢制CH4/CO的负载型金属催化剂界面调控研究进展
Research progress on interfacial modulation of supported metal catalysts for CO2 hydrogenation to CH4/CO
- 低碳化学与化工 2025, 50(4): 19-28.
- 作者机构：
1.浙江师范大学 化学与材料科学学院，浙江 金华 321004
2.中国科学院 山西煤炭化学研究所，山西 太原 030001
- 作者简介：
何悦（1999—），硕士研究生，研究方向为CO2加氢催化剂设计，E-mail：18903063285@163.com。
李瑞英（1995—），博士后，研究方向为工业催化，E-mail：liruiying@sxicc.ac.cn。
- 基金信息：山西省基础研究计划青年项目(202403021222488)
DOI：10.12434/j.issn.2097-2547.20240494
中图分类号： TQ426;O643.36收稿：2024-12-15，
修回：2025-01-17，
纸质出版：2025-04-25
- 稿件说明：
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何悦,李瑞英.CO2加氢制CH4/CO的负载型金属催化剂界面调控研究进展[J].低碳化学与化工,2025,50(04):19-28.
HE Yue,LI Ruiying.Research progress on interfacial modulation of supported metal catalysts for CO2 hydrogenation to CH4/CO[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(04):19-28.
何悦,李瑞英.CO2加氢制CH4/CO的负载型金属催化剂界面调控研究进展[J].低碳化学与化工,2025,50(04):19-28. DOI： 10.12434/j.issn.2097-2547.20240494.
HE Yue,LI Ruiying.Research progress on interfacial modulation of supported metal catalysts for CO2 hydrogenation to CH4/CO[J].Low-Carbon Chemistry and Chemical Engineering,2025,50(04):19-28. DOI： 10.12434/j.issn.2097-2547.20240494.
摘要
为实现“双碳”目标以及缓解环境污染问题，CO
2
利用成为了当前研究的热点之一。由于受到CO
2
分子结构以及复杂的加氢路线限制，开发高活性、高选择性的催化剂是CO
2
高值化利用的关键。负载型金属催化剂因具有大比表面积和高分散度等优势，在CO
2
加氢制CH
4
/CO反应中应用广泛。为提高催化剂的催化活性和产物选择性，需要了解负载型金属催化剂在CO
2
加氢制CH
4
/CO反应过程中的界面调控作用。其中，影响界面结构的因素包括金属结构、载体性质和金属-载体相互作用，这些因素共同决定了催化剂催化性能。总结了CO
2
加氢制CH
4
/CO反应的热力学和机理，重点综述了负载型金属催化剂的研究进展，并讨论了负载型金属催化剂在CO
2
加氢制CH
4
/CO反应中的界面调控作用和催化剂未来的发展方向。
Abstract
To achieve the goal of “dual carbon” and alleviate environmental pollution
utilization of CO
2
has become a focal point in current research. Due to the limitations of CO
2
molecular structure and the complexity of hydrogenation routes
the development of highly active and selective catalysts is crucial for achieving high-value utilization of CO
2
. Supported metal catalysts are widely used in CO
2
hydrogenation to CH
4
/CO reaction due to the advantages of large specific surface area and high dispersion. To enhance the catalytic activity and product selectivity of catalysts
it is essential to understand the role of interfacial modulation in supported metal catalysts during CO
2
hydrogenation to CH
4
/CO reaction. The interfacial structure is influenced by m
etal structures
carrier properties and metal-carrier interactions
which determine the catalytic performance of catalysts. The thermodynamics and reaction mechanisms of CO
2
hydrogenation to CH
4
/CO were summarized
with a focus on the research progress on supported metal catalysts. The interfacial modulation and future development direction of supported metal catalysts for CO
2
hydrogenation to CH
4
/CO were discussed.
关键词
Keywords
references
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