丙烷脱氢制丙烯催化剂研究进展

苏聪龙; 侯朝鹏; 李红伟

doi:10.12434/j.issn.2097-2547.20240486

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丙烷脱氢制丙烯催化剂研究进展

更新时间：2025-04-21

- 丙烷脱氢制丙烯催化剂研究进展
- Research progress of propane dehydrogenation to propylene catalysts
- 低碳化学与化工 2025: 1-18.
- 作者机构：
  
  中石化石油化工科学研究院有限公司，北京 100083
- 作者简介：
  
  苏聪龙（2000—），硕士研究生，研究方向低碳烷烃脱氢，E-mail：su3197978004@163.com。
  侯朝鹏（1974—），博士，教授级高级工程师，研究方向为费托合成，E-mail：houcp.ripp@sinopec.com；
  李红伟（1989—），博士，副研究员，研究方向资源循环利用，E-mail：lihongwei.ripp@sinopec.com。
- 基金信息：
  
  国家重点研发计划课题(2021YFA1501302)
- DOI：10.12434/j.issn.2097-2547.20240486
  中图分类号： TK028
- 收稿日期：2024-11-25，
  
  修回日期：2025-01-15，
  
  网络出版日期：2025-04-21，
- 稿件说明：
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苏聪龙,侯朝鹏,李红伟.丙烷脱氢制丙烯催化剂研究进展[J].低碳化学与化工,

SU Conglong,HOU Chaopeng,LI Hongwei.Research progress of propane dehydrogenation to propylene catalysts[J].Low-Carbon Chemistry and Chemical Engineering,
苏聪龙,侯朝鹏,李红伟.丙烷脱氢制丙烯催化剂研究进展[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20240486.

SU Conglong,HOU Chaopeng,LI Hongwei.Research progress of propane dehydrogenation to propylene catalysts[J].Low-Carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20240486.

摘要

丙烷脱氢制丙烯是重要的丙烯供应来源之一。重点针对两类丙烷脱氢制丙烯催化剂的性能影响因素和催化机理进行了综述，对近年来各类催化剂的载体筛选、助剂优化、载体与活性组分的相互作用以及失活等问题进行了总结。丙烷氧化脱氢工艺中，V基催化剂绿色环保但失活快、起活温度高；Mo/W基催化剂首先要突破活性问题并阐明催化机理；Co基催化剂反应条件温和但还应探索适合工业生产的工艺条件；C基催化剂应在进一步验证碳载体高温耐受性的同时进一步提高碳载体上官能团的数量和分散度。丙烷直接脱氢工艺中，Cr基催化剂要在保持活性基础上降低Cr含量并寻求可替代的活性组分；Pt基催化剂应在提高Pt颗粒分散度的同时最大限度降低积炭量；Ga基催化剂应在提高活性的同时尽可能延长活性物种稳定存在的时间。

Abstract

Propane dehydrogenation to propylene is one of the important sources of propylene supply. The factors affecting the performance and catalytic mechanism of two kinds of catalysts for propane dehydrogenation to propylene were reviewed. The problems of carrier screening

auxiliary optimization

interaction between carrier and active component and deactivation of various catalysts in recent years were summarized. In the process of oxidative dehydrogenation of propane

the V-based catalyst is environmentally friendly

but the deactivation is fast and the activation temperature is high. The activity problem of Mo/W-based catalyst should be solved and the catalytic mechanism should be clarified. The reaction condition of Co-based catalyst is mild

but the process condition suitable for industrial production should be explored. The C-based catalyst should further verify the high temperature tolerance of carbon support and further increase the number and dispersion of functional groups on carbon support. In the process of direct dehydrogenation of propane

the Cr-based catalyst should reduce Cr content while maintaining activity and seek alternative active components. The Pt-based catalyst should increase the dispersion of Pt particles and minimize coking amount. When increasing the activity of Ga-based catalyst

the stable existence time of active specie should be prolonged as much as possible.

关键词

Keywords

references

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