甲烷干重整制合成气反应水滑石衍生Ni基催化剂的研究进展

钟家伟; 林炜婷; 黄心宇; 翁福建; 卢鹏印; 黄振

doi:10.12434/j.issn.2097-2547.20240451

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甲烷干重整制合成气反应水滑石衍生Ni基催化剂的研究进展

更新时间：2025-02-27

- 甲烷干重整制合成气反应水滑石衍生Ni基催化剂的研究进展
- Research progress of hydrotalcite-derived Ni-based catalysts in methane dry reforming to syngas
- 低碳化学与化工 2025: 1-9.
- 作者机构：
  
  1.广东省可再生能源重点实验室，广东广州 510640
  2.华南农业大学生物质工程研究院，广东广州 510642
- 作者简介：
  
  钟家伟（1988—），博士，副教授，研究方向为碳基能源化学，E-mail： zhongjiaweiv@163.com。
- 基金信息：
  
  国家自然科学基金面上项目(22478143);广东省基础与应用基础研究基金省市联合基金(2022A1515110028);广州市基础研究计划基础与应用基础研究(2023A04JOO58);广东省新能源和可再生能源研究开发与应用重点实验室资助(E339kf0701)
- DOI：10.12434/j.issn.2097-2547.20240451
  中图分类号： TK6
- 收稿日期：2024-11-07，
  
  修回日期：2024-12-23，
  
  网络出版日期：2025-02-26，
- 稿件说明：
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钟家伟,林炜婷,黄心宇等.甲烷干重整制合成气反应水滑石衍生Ni基催化剂的研究进展[J].低碳化学与化工,

ZHONG Jiawei,LIN Weiting,HUANG Xinyu,et al.Research progress of hydrotalcite-derived Ni-based catalysts in methane dry reforming to syngas[J].Low-carbon Chemistry and Chemical Engineering,
钟家伟,林炜婷,黄心宇等.甲烷干重整制合成气反应水滑石衍生Ni基催化剂的研究进展[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20240451.

ZHONG Jiawei,LIN Weiting,HUANG Xinyu,et al.Research progress of hydrotalcite-derived Ni-based catalysts in methane dry reforming to syngas[J].Low-carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20240451.

摘要

甲烷干重整是利用两种温室气体（CH

、CO

）生成高附加值合成气的反应，对缓解温室气体排放和提高CH

、CO

利用程度具有重要意义。Ni基催化剂是最为常见的甲烷干重整催化剂，但面临着积碳、烧结，从而导致催化剂失活的问题。水滑石衍生Ni基催化剂的比表面积较大、酸碱性和组分可调节，被广泛应用于甲烷干重整反应。首先，系统讨论了甲烷干重整反应的机理及甲烷干重整催化剂的失活机制。接下来，深入阐述了水滑石衍生Ni基催化剂的制备方法及其在甲烷干重整反应中的应用，具体分析了水滑石衍生Ni基催化剂的组成、助剂组分和制备方法与条件对催化剂抗积碳和抗烧结能力的影响。最后，从Ni基亚纳米/单原子催化

剂、少层/单层水滑石衍生Ni基催化剂和水滑石衍生Ni基多功能催化剂等方面出发，提出了水滑石衍生Ni基催化剂研究方向，为开发适用于C1小分子（CH

、CO

等）催化转化的高效稳定Ni基纳米/亚纳米催化剂提供进一步的指导。

Abstract

Methane dry reforming is a reaction that utilizes two greenhouse gas (CH

and CO

) to generate high value-added syngas

which is of great significance for mitigating greenhouse gas emissions and enhancing the utilization of CH

and CO

. Ni-based catalysts are the common used catalysts in methane dry reforming reaction

but they suffer from problems such as carbon deposition and sintering

which can lead to catalyst deactivation. Due to the large specific surface area and adjustable acidity and composition

hydrotalcite-derived Ni-based catalysts are widely used in methane dry reforming reaction. Firstly

the mechanism of methane dry reforming reaction and deactivation mechanism of catalysts were systematically discussed. Next

the synthesis of hydrotalcite-derived Ni-based catalysts and their application in methane dry reforming reaction were comprehensively illustrated

and the effect of the composition

additive components and preparation methods and conditions on the resistance to carbon deposition and sintering performance of hydrotalcite-derived Ni-based catalysts were analyzed. Finally

from the aspects of Ni-based nano/single atom catalysts

few-/mono-layered hydrotalcite-derived Ni-based catalysts and hydrotalcite-derived Ni-based multi-functional catalysts

the research direction of hydrotalcite-derived Ni-based catalysts in methane dry reforming reaction were proposed

which can provide further insightful guidance for the development of efficient and stable Ni-based nano/subnano-catalysts for the catalytic conversion of C1 molecules (CH

etc.).

关键词

Keywords

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