Fe基分子筛催化剂应用于NH<sub>3</sub>选择性催化还原和N<sub>2</sub>O直接催化分解反应的研究进展

明淑君; 李新楠; 庞磊; 苏长罗; 程春晖; 杨小东; 李涛

doi:10.12434/j.issn.2097-2547.20240446

您当前的位置：

首页 >

文章列表页 >

Fe基分子筛催化剂应用于NH₃选择性催化还原和N₂O直接催化分解反应的研究进展

更新时间：2025-05-19

- Fe基分子筛催化剂应用于NH₃选择性催化还原和N₂O直接催化分解反应的研究进展
- Research progress on Fe-based zeolite catalysts for NH₃-selective catalytic reduction and direct catalytic decomposition of N₂O
- 低碳化学与化工 2025: 1-16.
- 作者机构：
  
  1.黄冈师范学院化学化工学院催化材料制备及应用湖北省重点实验室，湖北黄冈438000
  2.华中科技大学化学与化工学院能量转换与存储材料化学教育部重点实验室，材料化学与服役失效湖北省重点实验室，湖北武汉 430074
  3.东风商用车有限公司技术中心，湖北武汉 430056
  4.陕西煤业化工技术研究院有限责任公司，陕西西安 710100
- 作者简介：
  
  明淑君（1994—），博士，讲师，研究方向为环境催化，E-mail：mingshujun@hgnu.edu.cn。
  杨小东（1991—），博士，副教授，研究方向为有机方法学，E-mail：yangxd2014@lzu.edu.cn；
  李涛（1969—），博士，教授，研究方向为环境催化，E-mail：taoli@hust.edu.cn。
- 基金信息：
  
  国家自然科学基金(22406062);湖北省教育厅科学研究计划青年人才项目(Q20232903)
- DOI：10.12434/j.issn.2097-2547.20240446
  中图分类号： TQ426.94;O643.3;
- 收稿日期：2024-11-05，
  
  修回日期：2024-12-30，
  
  网络出版日期：2025-05-15，
- 稿件说明：
移动端阅览
明淑君,李新楠,庞磊等.Fe基分子筛催化剂应用于NH₃选择性催化还原和N₂O直接催化分解反应的研究进展[J].低碳化学与化工,

MING Shujun,LI Xinnan,PANG Lei,et al.Research progress on Fe-based zeolite catalysts for NH₃-selective catalytic reduction and direct catalytic decomposition of N₂O[J].Low-Carbon Chemistry and Chemical Engineering,
明淑君,李新楠,庞磊等.Fe基分子筛催化剂应用于NH₃选择性催化还原和N₂O直接催化分解反应的研究进展[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20240446.

MING Shujun,LI Xinnan,PANG Lei,et al.Research progress on Fe-based zeolite catalysts for NH₃-selective catalytic reduction and direct catalytic decomposition of N₂O[J].Low-Carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20240446.

摘要

柴油车排放的氮氧化物（NO

）和氧化亚氮（N

O）对人类健康和生态环境造成了显著危害。NH

选择性催化还原（NH

-SCR）技术是当前控制柴油车尾气中NO

排放的有效方法之一，而N

O的直接催化分解（简称“N

O分解”）则被认为是减少N

O排放的最具潜力的技术。这两种技术的核心均依赖于催化剂的开发与应用。Fe基分子筛催化剂在NH

-SCR和N

O分解反应中展现出了卓越的催化性能，为实现NO

和N

O的同步高效去除提供了一条有前途的路径。为了深入理解Fe基分子筛催化剂在这两种催化反应中的作用机理，综述了Fe基分子筛催化剂

在NH

-SCR和N

O分解反应中的催化机理，探讨了Fe基分子筛催化剂的制备方法、拓扑结构、助剂金属掺杂，以及反应环境中共存气体对其理化性质、NH

-SCR活性和N

O分解性能的影响。具体而言，Fe基分子筛催化剂的Fe物种形成与分布受到制备方法和分子筛拓扑结构的显著影响。助剂金属的引入不仅能够增大催化剂的酸性位点含量，还能改善Fe物种的分散性，从而优化其催化性能。此外，共存气体（如NO、O

和H

O）对Fe基分子筛催化剂的N

O分解活性产生不同程度的影响。最后，对Fe基分子筛催化剂的未来研究方向进行了展望，并为其在催化剂设计优化与性能提升方面提供了建议。

Abstract

Nitrogen oxides (NO

) and nitrous oxide (N

O) emissions from diesel vehicles pose significant threats to human health and the ecological environment. NH

-selective catalytic reduction (NH

-SCR) technology is one of the most effective methods for controlling NO

emissions from diesel vehicle exhaust

while the direct catalytic decomposition of N

O (abbreviated as “N

O decomposition”)is considered the most promising technology for reducing N

O emissions. The core of both technologies lies in the development and application of catalysts. Fe-based zeolite catalysts exhibit excellent catalytic performance in NH

-SCR and N

O decomposition reactions

providing a promising pathway for the simultaneous and efficient removal of NO

and N

O. To gain a deeper understanding of the role of Fe-based zeolite catalysts in these two catalytic reactions

the catalytic mechanisms of Fe-based zeolite catalysts in NH

-SCR and N

O decomposition reactions were summarized

and the effects of preparation methods

topological structures

doped metal additives and coexisting gases on their physicochemical properties

-SCR activity and N

O decomposition performance were discusses. Specifically

the formation and distribution of Fe species in Fe-based zeolite catalysts are significantly influenced by the preparation methods and zeolite topological structures. The introduction of metal additive

s not only increases the number of acid sites in the catalyst but also improves the dispersion of Fe species

thereby optimizing catalytic performance. Furthermore

coexisting gases such as NO

and H

O have varying degrees of impact on the N

O decomposition activity of Fe-based zeolite catalysts. Finally

an outlook on future research directions for Fe-based zeolite catalysts was provided

and recommendations for catalyst design optimization and performance enhancement were offered.

关键词

Keywords

references

ZHANG R D , LIU N , LEI Z G , et al . Selective transformation of various nitrogen-containing exhaust gases toward N 2 over zeolite catalysts [J ] . Chemical Reviews , 2016 , 116 ( 6 ): 3658 - 3721 .

JIA L F , LIU J X , HUANG D Q , et al . Interface engineering of a bifunctional Cu-SSZ-13@CZO Core-Shell catalyst for boosting potassium ion and SO 2 tolerance [J ] . ACS Catalysis , 2022 , 12 ( 18 ): 11281 - 11293 .

单玉龙 , 彭悦 , 楚碧武 , 等 . 我国重点行业氮氧化物管控现状及减排策略 [J ] . 环境科学研究 . 2023 , 36 : 431 - 438 .

SHAN Y L , PENG Y , CHU B W , et al . Control status and emission reduction strategies of nitrogen oxides in key industries in China [J ] . Research of Environmental Sciences , 2023 , 36 : 431 - 438 .

ZHUANG Z Q , GUAN B , CHEN J Y , et al . Review of nitrous oxide direct catalytic decomposition and selective catalytic reduction catalysts [J ] . Chemical Engineering Journal , 2024 , 486 : 150374 .

李佳 , 樊星 , 陈莉 , 等 . 硝酸生产尾气中NO x 和N 2 O联合脱除技术研究进展 [J ] . 化工进展 . 2023 , 42 : 3770 - 3779 .

LI J , FAN X , CHEN L , et al . Research progress of simultaneous removal of NO x and N 2 O from the tail gas of nitric acid production [J ] . Chemical Industry and Engineering Progress , 2023 , 42 : 3770 - 3779 .

MENG D M , ZHAN W C , GUO Y , et al . A highly effective catalyst of Sm-MnO x for the NH 3 -SCR of NO x at low temperature: Promotional role of Sm and its catalytic performance [J ] . ACS Catalysis , 2015 , 5 ( 10 ): 5973 - 5983 .

XU Y F , WU X D , LIN Q W , et al . SO 2 promoted V 2 O 5 -MoO 3 /TiO 2 catalyst for NH 3 -SCR of NO at low temperatures [J ] . Applied Catalysis A: General , 2019 , 570 : 42 - 50 .

WANG A Y , ARORA P , BERNIN D , et al . Investigation of the robust hydrothermal stability of Cu/LTA for NH 3 -SCR reaction [J ] . Applied Catalysis B: Environmental , 2019 , 246 : 242 - 253 .

DU J P , SHAN Y L , SUN Y , et al . Unexpected increase in low-temperature NH 3 -SCR catalytic activity over Cu-SSZ-39 after hydrothermal aging [J ] . Applied Catalysis B: Environmental , 2021 , 294 : 120237 .

ZHANG T , LI J , LIU J , et al . High activity and wide temperature window of Fe-Cu-SSZ-13 in the selective catalytic reduction of NO with ammonia [J ] . AIChE Journal , 2015 , 61 : 3825 - 3837 .

YUE Y Y , LIU B , QIN P , et al . One-pot synthesis of FeCu-SSZ-13 zeolite with superior performance in selective catalytic reduction of NO by NH 3 from natural aluminosilicates [J ] . Chemical Engineering Journal , 2020 , 398 : 125515 .

SHAN Y L , SUN Y , DU J P , et al . Hydrothermal aging alleviates the inhibition effects of NO 2 on Cu-SSZ-13 for NH 3 -SCR [J ] . Applied Catalysis B: Environmental , 2020 , 275 : 119105 .

SHAN Y L , SHAN W P , SHI X Y , et al . A comparative study of the activity and hydrothermal stability of Al-rich Cu-SSZ-39 and Cu-SSZ-13 [J ] . Applied Catalysis B: Environmental , 2020 , 264 : 118511 .

GAO F , ZHENG Y , KUKKADAPU R K , et al . Iron loading effects in Fe/SSZ-13 NH 3 ‑SCR catalysts: Nature of the Fe ions and Structure-Function relationships [J ] . ACS Catalysis , 2016 , 6 ( 5 ): 2939 - 2954 .

MING S J , YU S Q , PANG L , et al . Regulation of Si/Al ratios of Fe-SSZ-13: Impact on NH 3 -SCR activity and hydrothermal stability [J ] . Applied Surface Science , 2024 , 654 : 159492 .

WANG Y Y , WAN J , CHEN J W , et al . New insight into the doping effect of transition metals (Fe, Ti, Mn, and Ce) on the structure and catalytic performance of Cu-SSZ-13 zeolite catalysts for the NH 3 -SCR reaction [J ] . Industrial Engineering Chemistry Research , 2022 , 61 ( 41 ): 15066 - 15075 .

YANG Z , WANG Z P , LIU W , et al . Highly efficient MnO x catalysts supported on Mg-Al spinel for low temperature NH 3 -SCR [J ] . Journal of Environmental Chemical Engineering , 2023 , 11 ( 5 ): 110873 .

PIETROGIACOMI D , CAMPA M C , CARBONE L R , et al . N 2 O decomposition and reduction on Co-MOR, Fe-MOR and Ni-MOR catalysts: In situ UV-vis DRS and operando FTIR investigation. An insight on the reaction pathways [J ] . Applied Catalysis B: Environmental , 2019 , 240 : 19 - 29 .

陈标华 , 田梦 , 徐瑞年 . 化工生产中温室气体N 2 O排放与工业化减排技术 [J ] . 环境工程 , 2023 , 10 ( 41 ): 82 - 90 .

CHEN B H , TIAN M , XU R N , et al . Greenhouse gas N 2 O emissions in chemical production and industrial abatement technologies [J ] . Environmental Engineering , 2023 , 10 ( 41 ): 82 - 90 .

WEI X , YANG X F , WANG A Q , et al . Bimetallic Au-Pd alloy catalysts for N 2 O decomposition: Effects of surface structures on catalytic activity [J ] . The Journal of Physical Chemistry C , 2012 , 116 : 6222 - 6232 .

RICHARDS N , CARTER H J , NOWICK E , et al . Structure-sensitivity of alumina supported palladium catalysts for N 2 O decomposition [J ] . Applied Catalysis B: Environmental , 2020 , 264 : 118501 .

XIONG S C , CHEN J J , HUANG N , et al . Balance between reducibility and N 2 O adsorption capacity for the N 2 O decomposition: Cu x Co y catalysts as an example [J ] . Environmental Science & Technology , 2019 , 53 ( 17 ): 10379 - 10386 .

ZHAO F L , WANG D D , LI X , et al . Enhancement of Cs on Co 3 O 4 for N 2 O catalytic decomposition: N 2 O activation and O 2 desorption [J ] . Industrial & Engineering Chemistry Research , 2022 , 61 ( 37 ): 13854 - 13862 .

WANG A Y , WANG Y L , WALTER D E , et al . Catalytic N 2 O decomposition and reduction by NH 3 over Fe/Beta and Fe/SSZ-13 catalysts [J ] . Journal of Catalysis , 2018 , 358 : 199 - 210 .

MELIÁN C I , ECK R H E , ESPINOSA S , et al . Tail gas catalyzed N 2 O decomposition over Fe-beta zeolite. On the promoting role of framework connected AlO 6 sites in the vicinity of Fe by controlled dealumination during exchange [J ] . Applied Catalysis B: Environmental , 2017 , 203 : 218 - 226 .

DOI K , WU Y , TAKEDA R , et al . Catalytic decomposition of N 2 O in medical operating rooms over Rh/Al 2 O 3 , Pd/Al 2 O 3 , and Pt/Al 2 O 3 [J ] . Applied Catalysis B: Environmental , 2001 , 35 : 43 - 51 .

XIONG Y , ZHAO Y M , QI X K , et al . Strong structural modification of Gd to Co 3 O 4 for catalyzing N 2 O decomposition under simulated real tail gases [J ] . Environmental Science & Technology , 2021 , 55 ( 19 ): 13335 - 13344 .

LIN F , ANDANA T , WU Y Q , et al . Catalytic site requirements for N 2 O decomposition on Cu-, Co-, and Fe-SSZ-13 zeolites [J ] . Journal of Catalysis , 2021 , 401 : 70 - 80 .

WU X , DU J X , GAO Y X , et al . Progress and challenges in nitrous oxide decomposition and valorization [J ] . Chemical Society Reviews , 2024 , 53 ( 16 ): 8379 - 8423 .

MA L , CHANG H Z , YANG S J , et al . Relations between iron sites and performance of Fe/HBEA catalysts prepared by two different methods for NH 3 -SCR [J ] . Chemical Engineering Journal , 2012 , 209 : 652 - 660 .

IWASAKI M , YAMAZAKI K , SHINJOH H . NO x reduction performance of fresh and aged Fe-zeolites prepared by CVD: Effects of zeolite structure and Si/Al 2 ratio [J ] . Applied Catalysis B: Environmental , 2011 , 102 ( 1/2 ): 302 - 309 .

LIM J B , CHA S H , HONG S B . Direct N 2 O decomposition over iron-substituted small-pore zeolites with different pore topologies [J ] . Applied Catalysis B: Environmental , 2019 , 243 : 750 - 759 .

LYU L Q , SUN W Q , FENG P , et al . NH 3 and N 2 O emission durability of the heavy-duty diesel engine with DOC, DPF, SCR, and ASC through the accelerated aging method [J ] . Fuel , 2023 , 339 : 126950 .

ZHANG T , QIU Y , LIU G H , et al . Nature of active Fe species and reaction mechanism over high-efficiency Fe/CHA catalysts in catalytic decomposition of N 2 O [J ] . Journal of Catalysis , 2020 , 392 : 322 - 335 .

PARK Y , KIM B . Catalytic removal of nitrogen oxides (NO, NO 2 , N 2 O) from ammonia-fueled combustion exhaust: A review of applicable technologies [J ] . Chemical Engineering Journal , 2023 , 461 : 141958 .

BRANDENBERGER S , CHER O K , TISSLER A , et al . The determination of the activities of different iron species in Fe-ZSM-5 for SCR of NO by NH 3 [J ] . Applied Catalysis B: Environmental , 2010 , 95 : 348 - 357 .

LIU Q , BIAN C , MING S J , et al . The opportunities and challenges of iron-zeolite as NH 3 -SCR catalyst in purification of vehicle exhaust [J ] . Applied Catalysis A: General , 2020 , 607 : 117865 .

LI J , LI S H . A DFT study toward understanding the high activity of Fe-Exchanged zeolites for the “Fast” selective catalytic reduction of nitrogen oxides with ammonia [J ] . Journal of Physical Chemistry C , 2008 , 112 ( 43 ): 16938 - 16944 .

WANG P , YU D , ZHANG L D , et al . Evolution mechanism of NO x in NH 3 -SCR reaction over Fe-ZSM-5 catalyst: Species-performance relationships [J ] . Applied Catalysis A: General , 2020 , 607 : 117806 .

VÉLEZ R P , ELLMERS I , HUANG H , et al . Identifying active sites for fast NH 3 -SCR of NO/NO 2 mixtures over Fe-ZSM-5 by operando EPR and UV-vis spectroscopy [J ] . Journal of Catalysis , 2014 , 316 : 103 - 111 .

DELAHAY G , VALADE D , GUZMA N V A , et al . Selective catalytic reduction of nitric oxide with ammonia on Fe-ZSM-5 catalysts prepared by different methods [J ] . Applied Catalysis B: Environmental , 2005 , 55 : 149 - 155 .

SHI X Y , WANG Y J , SHAN Y L , et al . Investigation of the common intermediates over Fe-ZSM-5 in NH 3 -SCR reaction at low temperature by in situ DRIFTS [J ] . Journal of Environmental Sciences , 2020 , 94 : 32 - 39 .

SHI X Y , LIU F D , XIE L J , et al . NH 3 -SCR performance of fresh and hydrothermally aged Fe-ZSM-5 in standard and fast selective catalytic reduction reactions [J ] . Environmental Science & Technology , 2013 , 47 ( 7 ): 3293 - 3298 .

IWASAKI M , YAMAZAKI K , BANNO K , et al . Characterization of Fe/ZSM-5 DeNO x catalysts prepared by different methods: Relationships between active Fe sites and NH 3 -SCR performance [J ] . Journal of Catalysis , 2008 , 260 ( 2 ): 205 - 216 .

MARTÍN N , VENNESTRØM N R P , THØGERSEN R J , et al . Iron-Containing SSZ-39 (AEI) zeolite: An active and stable High-Temperature NH 3 -SCR catalyst [J ] . ChemCatChem , 2017 , 9 ( 10 ): 1754 - 1757 .

MARTURANO P , DROZDOVA L , PIRNGRUBER D G , et al . The mechanism of formation of the Fe species in Fe/ZSM-5 prepared by CVD [J ] . Physical Chemistry Chemical Physics , 2001 , 3 ( 24 ): 5585 - 5595 .

BOROŃ P , CHMIELARZ L , GURGUL J , et al . The influence of the preparation procedures on the catalytic activity of Fe-BEA zeolites in SCR of NO with ammonia and N 2 O decomposition [J ] . Catalysis Today , 2014 , 235 : 210 - 225 .

LIU Q , BIAN C , JIN Y F , et al . Influence of calcination temperature on the evolution of Fe species over Fe-SSZ-13 catalyst for the NH 3 -SCR of NO [J ] . Catalysis Today , 2022 , 388-389 : 158 - 167 .

ZHANG T , QIN X , PENG Y , et al . Effect of Fe precursors on the catalytic activity of Fe/SAPO-34 catalysts for N 2 O decomposition [J ] . Catalysis Communications , 2019 , 128 : 105706 .

CAO K P , FAN D , LI L Y , et al . Insights into the Pyridine-Modified MOR zeolite catalysts for DME carbonylation [J ] . ACS Catalysis , 2020 , 10 ( 5 ): 3372 - 3380 .

BEERDSEN E , DUBBELDAM D , SMIT B . Understanding diffusion in nanoporous materials [J ] . Physical Review Letters , 2006 , 96 ( 4 ): 44501 .

李懿 , 刘宁 , 张润铎 , 等 . NO与NH 3 在不同构型分子筛催化剂中吸附和扩散的分子模拟 [J ] . 工业催化 , 2016 , 24 : 33 - 40 .

LI Y , LIU N , ZHANG R D , et al . Molecular simulations of adsorption and diffusion of NO and NH 3 over zeolite catalysts with various structure configurations [J ] . Industrial Catalysis , 2016 , 24 : 33 - 40 .

TAN X C , GARCIA A P , SASTRE G , et al . Hydrothermal aging enhances nitrogen oxide reduction over iron-Exchanged zeolites at 150 ℃ [J ] . Journal of the American Chemical Society , 2024 , 146 ( 9 ): 6352 - 6359 .

RYU T , HONG S B . Iron-exchanged UZM-35: An active NH 3 -SCR catalyst at low temperatures [J ] . Applied Catalysis B: Environmental , 2020 , 266 : 118622 .

HU X Y , CHEN J L , HE S K , et al . Study on the catalytic activity and hydrothermal stability of one-pot synthesized Fe-based FER zeolites for NH 3 -SCR [J ] . Catalysis Science & Technology , 2023 , 13 ( 18 ): 5435 - 5448 .

YU D , WANG P , LI X J , et al . Study on the role of Fe species and acid sites in NH 3 -SCR over the Fe-based zeolites [J ] . Fuel , 2023 , 336 : 126759 .

USUI T , LIU Z D , IBE S , et al . Improve the hydrothermal stability of Cu-SSZ-13 zeolite catalyst by loading a small amount of Ce [J ] . ACS Catalysis , 2018 , 8 ( 10 ): 9165 - 9173 .

GUAN B , JIANG H , PENG X S , et al . Promotional effect and mechanism of the modification of Ce on the enhanced NH 3 -SCR efficiency and the low temperature hydrothermal stability over Cu/SAPO-34 catalysts [J ] . Applied Catalysis A: General , 2021 , 617 : 118110 .

DENG J L , LIU J X , SONG W Y , et al . Selective catalytic reduction of NO with NH 3 over Mo-Fe/beta catalysts: The effect of Mo loading amounts [J ] . RSC Advances , 2017 , 7 ( 12 ): 7130 - 7139 .

CHEN Z , LIU Q , GUO L , et al . The promoting mechanism of in situ Zr doping on the hydrothermal stability of Fe-SSZ-13 catalyst for NH 3 -SCR reaction [J ] . Applied Catalysis B: Environmental , 2021 , 286 : 119816 .

QIAO Y H , GUAN Z Z , ZHANG M Y , et al . Promoting effect of Cu and Mn doping on the Fe/ZSM-5 catalyst for selective catalytic reduction of NO with NH 3 [J ] . Fuel , 2024 , 357 : 129947 .

YAKOVLEV L A , ZHIDOMIROV M G , SANTEN A R . DFT calculations on N 2 O decomposition by binuclear Fe complexes in Fe/ZSM-5 [J ] . The Journal of Physical Chemistry B , 2001 , 105 ( 49 ): 12297 - 12302 .

PIRNGRUBER G D , LUECHINGER M , ROY P K , et al . N 2 O decomposition over iron-containing zeolites prepared by different methods: A comparison of the reaction mechanism [J ] . Journal of Catalysis , 2004 , 224 ( 2 ): 429 - 440 .

KONDRATENKO E V , PÉREZ R J . Mechanism and kinetics of direct N 2 O decomposition over Fe-MFI zeolites with different iron speciation from temporal analysis of products [J ] . The Journal of Physical Chemistry B , 2006 , 110 ( 45 ): 22586 - 22595 .

CHEN B H , LIU N , LIU X Y , et al . Study on the direct decomposition of nitrous oxide over Fe-beta zeolites: From experiment to theory [J ] . Catalysis Today , 2011 , 175 ( 1 ): 245 - 255 .

PIETERSE J . A Z, BOONEVELD S, BRINK R W V. Evaluation of Fe-zeolite catalysts prepared by different methods for the decomposition of N 2 O [J ] . Applied Catalysis B: Environmental , 2004 , 51 ( 4 ): 215 - 228 .

MELIANCABRERA I , ESPINOSA S , GROEN J , et al . Utilizing full-exchange capacity of zeolites by alkaline leaching: Preparation of Fe-ZSM5 and application in N 2 O decomposition [J ] . Journal of Catalysis , 2006 , 238 ( 2 ): 250 - 259 .

XIE P F , LUO Y J , MA Z , et al . Catalytic decomposition of N 2 O over Fe-ZSM-11 catalysts prepared by different methods: Nature of active Fe species [J ] . Journal of Catalysis , 2015 , 330 : 311 - 322 .

ATES A . Influence of treatment conditions on decomposition activity of N 2 O over FeZSM-5 with high iron content [J ] . Catalysis Science Technology , 2014 , 4 ( 7 ): 231 - 241 .

PEREZ-RAMIREZ J , KAPTEIJN F , GROEN J C , et al . Steam-activated FeMFI zeolites. Evolution of iron species and activity in direct N 2 O decomposition [J ] . Journal of Catalysis , 2003 , 214 ( 1 ): 33 - 45 .

CAO H H , YUAN X , DU J P , et al . High-temperature treatment promotes N 2 O decomposition over Fe-impregnated Al-rich SSZ-13 zeolites [J ] . Catalysis today , 2024 , 433 : 114670 .

LIANG X L , TANG H L , YANG F F , et al . Ammonia-steam treated FeZSM-5 for direct N 2 O decomposition [J ] . Microporous and Mesoporous Materials , 2019 , 290 : 109655 .

BORON P , CHMIELARZ L , GURGUL J , et al . Influence of iron state and acidity of zeolites on the catalytic activity of FeHBEA, FeHZSM-5 and FeHMOR in SCR of NO with NH 3 and N 2 O decomposition [J ] . Microporous and Mesoporous Materials , 2015 , 203 : 73 - 85 .

SÁDOVSKÁ G , BERNAUER M , BERNAUER B , et al . On the mechanism of high-temperature N 2 O decomposition over Fe-FER in the presence of NO [J ] . Catalysis communications , 2018 , 112 : 58 - 62 .

GOKCE I , OZBEK M O , IPEK B . Conditions for higher methanol selectivity for partial CH 4 oxidation over Fe-MOR using N 2 O as the oxidant and comparison to Fe-SSZ-13, Fe-SSZ-39, Fe-FER, and Fe-ZSM-5 [J ] . Journal of Catalysis , 2023 , 427 : 115113 .

SÁDOVSKÁG , TABOR E , SAZAMA P , et al . High temperature performance and stability of Fe-FER catalyst for N 2 O decomposition [J ] . Catalysis Communications , 2017 , 89 : 133 - 137 .

SHEN Q , WU M F , WANG H , et al . The influence of desilication on high-silica MFI and its catalytic performance for N 2 O decomposition [J ] . Applied Surface Science , 2018 , 441 : 474 - 481 .

LEE J K , KIM Y J , LEE H J , et al . Iron-substituted TNU-9, TNU-10, and IM-5 zeolites and their steam-activated analogs as catalysts for direct N 2 O decomposition [J ] . Journal of Catalysis , 2011 , 284 ( 1 ): 23 - 33 .

XIA H A , SUN K Q , LIU Z M , et al . The promotional effect of NO on N 2 O decomposition over the bi-nuclear Fe sites in Fe/ZSM-5 [J ] . Journal of Catalysis , 2010 , 270 ( 1 ): 103 - 109 .

KAPTEIJN F , MARBÁN G , RODRIGUEZ M J , et al . Kinetic analysis of the decomposition of nitrous oxide over ZSM-5 catalysts [J ] . Journal of Catalysis , 1997 , 167 ( 1 ): 256 - 265 .

SANG C , KIM H B , LUND R F C . Effect of NO upon N 2 O decomposition over Fe/ZSM-5 with low iron loading [J ] . The Journal of Physical Chemistry B , 2005 , 109 ( 6 ): 2295 - 2301 .

KAUCKY D , SOBALIK Z , SCHWARZE M , et al . Effect of FeH-zeolite structure and Al-lewis sites on N 2 O decomposition and NO/NO 2 -assisted reaction [J ] . Journal of Catalysis , 2006 , 238 ( 2 ): 293 - 300 .

PÉREZ R J , KAPTEIJN F , MUL G , et al . Superior performance of ex-framework FeZSM-5 in direct N 2 O decomposition in tail-gases from nitric acid plants [J ] . Chemical Communications , 2001 ( 8 ): 693 - 694 .

BULUSHEV A D , PRECHTL M P , RENKEN A , et al . Water vapor effects in N 2 O decomposition over Fe-ZSM-5 catalysts with low iron content [J ] . Industrial & Engineering Chemistry Research , 2007 , 46 ( 12 ): 4178 - 4185 .

XIA H A , SUN K Q , FENG Z C , et al . Effect of water on active iron sites for N 2 O decomposition over Fe/ZSM-5 catalyst [J ] . Journal of Physical Chemistry C , 2011 , 115 ( 2 ): 542 - 548 .

浏览量

下载量

CNKI被引量

文章被引用时，请邮件提醒。

提交

工具集

关联资源

暂无数据

Fe基分子筛催化剂应用于NH3选择性催化还原和N2O直接催化分解反应的研究进展

Research progress on Fe-based zeolite catalysts for NH3-selective catalytic reduction and direct catalytic decomposition of N2O

DOI：10.12434/j.issn.2097-2547.20240446

摘要

Abstract

关键词

Keywords

references

Fe基分子筛催化剂应用于NH₃选择性催化还原和N₂O直接催化分解反应的研究进展

Research progress on Fe-based zeolite catalysts for NH₃-selective catalytic reduction and direct catalytic decomposition of N₂O