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中国石油石油化工研究院兰州化工研究中心,甘肃 兰州 730060
王甜(1998—),硕士,助理工程师,研究方向为催化剂开发,E-mail:wangtian123@petrochina.com.cn。
孙世林(1977—),硕士,高级工程师,研究方向为炼油化工,E-mail:sunshilin@petrochina.com.cn。
收稿日期:2024-10-29,
修回日期:2024-12-30,
网络出版日期:2025-04-25,
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王甜,卜婷婷,杨淑萍等.含氧烃类尾气脱氧催化剂研究进展[J].低碳化学与化工,
WANG Tian,BU Tingting,YANG Shuping,et al.Research progress on deoxidation catalysts for oxygen-containing hydrocarbon tail gases[J].Low-Carbon Chemistry and Chemical Engineering,
王甜,卜婷婷,杨淑萍等.含氧烃类尾气脱氧催化剂研究进展[J].低碳化学与化工, DOI:10.12434/j.issn.2097-2547.20240439.
WANG Tian,BU Tingting,YANG Shuping,et al.Research progress on deoxidation catalysts for oxygen-containing hydrocarbon tail gases[J].Low-Carbon Chemistry and Chemical Engineering, DOI:10.12434/j.issn.2097-2547.20240439.
工业生产中含氧烃类尾气因含氧量高,通常无法循环利用。常见的脱氧技术主要包括化学吸附脱氧、焦炭燃烧脱氧、催化脱氧和物理变压吸附脱氧等。贵金属(Pt、Pd和Ag)和非贵金属(Cu、Mn、Ni、Mo和Fe)催化剂在含氧烃类尾气脱氧领域被广泛研究。介绍了多种含氧烃类尾气脱氧方法,综述了贵金属和非贵金属脱氧催化剂的研究进展,并展望了脱氧催化剂发展面临的挑战与趋势。贵金属脱氧催化剂工业应用成熟,但存在催化剂成本高、原料气组分含量要求严格,以及污染环境等问题。由于高效且绿色环保的特点,非贵金属脱氧催化剂已逐渐成为研究热点,并有望成为未来脱氧催化剂的发展方向。
Oxygen-containing hydrocarbon tail gases in industrial production often cannot be recycled due to their high oxygen contents. Common deoxidation technologies include chemical adsorption deoxidation
coke combustion deoxidation
catalytic deoxidation and physical pressure swing adsorption deoxidation. Precious metal (Pt
Pd and Ag) and non-precious metal (Cu
Mn
Ni
Mo and Fe) catalysts have been widely studied in the field of oxygen-containing hydrocarbon tail gas deoxidation. Various deoxidation methods for oxygen-containing hydrocarbon tail gases were introduced
the research progress of both precious and non-precious metal deoxidation catalysts was reviewed
and the challenges and trends in the development of deoxidation catalysts were anticipated. While precious metal deoxidation catalysts are mature for industrial applications
they face challenges such as high catalyst costs
strict feed gas composition requirements and environmental pollution. Due to their efficiency and environmentally friendly characteristics
non-precious metal deoxidation catalysts have gradually become a research hotspot and are expected to be the future direction for the development of deoxidation catalysts.
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