活性炭基变湿吸附剂的亲疏水改性及其空气中CO<sub>2</sub>吸附性能研究

贾长青; 郑世强; 张佳燚; 张雪莹; 刘海强; 宋晓健; 李强; 朱亮亮

doi:10.12434/j.issn.2097-2547.20240427

您当前的位置：

首页 >

文章列表页 >

活性炭基变湿吸附剂的亲疏水改性及其空气中CO₂吸附性能研究

更新时间：2025-02-24

- 活性炭基变湿吸附剂的亲疏水改性及其空气中CO₂吸附性能研究
- Study on hydrophilic/hydrophobic modification of activated carbon-based moisture-swing adsorbents and their CO₂ adsorption performances in air
- 低碳化学与化工 2025: 1-9.
- 作者机构：
  
  1.中国石油天然气股份有限公司西南油气田公司，四川成都 610051
  2.西北大学化工学院，陕西西安 710127
- 作者简介：
  
  贾长青（1970—），硕士，高级工程师，研究方向为油气田开发，E-mail：jiacq@petrochina.com.cn。
  朱亮亮（1990—），博士，副教授，研究方向为CO2捕集与资源化利用，E-mail：zhu.liangliang@nwu.edu.cn。
- 基金信息：
  
  国家重点研发计划(2024YFE0206600)
- DOI：10.12434/j.issn.2097-2547.20240427
  中图分类号： TQ09;X511
- 收稿日期：2024-10-20，
  
  修回日期：2024-11-25，
  
  网络出版日期：2025-02-24，
- 稿件说明：
移动端阅览
贾长青,郑世强,张佳燚等.活性炭基变湿吸附剂的亲疏水改性及其空气中CO₂吸附性能研究[J].低碳化学与化工,

JIA Changqing,ZHENG Shiqiang,ZHANG Jiayi,et al.Study on hydrophilic/hydrophobic modification of activated carbon-based moisture-swing adsorbents and their CO₂ adsorption performances in air[J].Low-carbon Chemistry and Chemical Engineering,
贾长青,郑世强,张佳燚等.活性炭基变湿吸附剂的亲疏水改性及其空气中CO₂吸附性能研究[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20240427.

JIA Changqing,ZHENG Shiqiang,ZHANG Jiayi,et al.Study on hydrophilic/hydrophobic modification of activated carbon-based moisture-swing adsorbents and their CO₂ adsorption performances in air[J].Low-carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20240427.

摘要

在CO

直接空气捕集（DAC）技术中，寻求廉价且湿度稳定性较好的变湿吸附材料，对于提高变湿吸附剂的实用性和环境适应性十分重要。以活性炭（AC）为基材，通过负载碳酸钾制备了多孔复合变湿吸附剂K

/AC，研究对比了木质、煤质和椰壳活性炭基复合变湿吸附剂的物理性质和CO

吸附性能，并进一步对价廉的木质活性炭基复合变湿吸附剂进行了亲疏水改性，研究了环境湿度对其性能的影响。结果表明，椰壳活性炭基复合变湿吸附剂具有最优的湿度稳定性，在常温、相对湿度为30%时其吸附容量达到最大值（0.85 mmol/g），这主要得益于其更优的孔隙结构和相对较高的疏水性。亲水改性的木质活性炭基复合变湿吸附剂在湿度增大时吸附容量迅速减小，而疏水改性的吸附剂则具有更好的湿度稳定性，在相对湿度为30%时，其CO

吸附容量最大（0.81 mmol/g）。通过疏水改性提高变湿吸附剂的CO

吸附性能及环境适应性，有利于促进DAC技术的广泛应用。

Abstract

In the CO

direct air capture (DAC) technology

finding low-cost and humidity-stable moisture-swing adsorption materials is crucial for enhancing the practicality and environmental adaptability of the adsorbents. The porous composite humidity adsorbent K

/AC was prepared by loading potassium carbonate on activated carbon (AC). The physical properties and CO

adsorption performance of the adsorbents based on wood

coal

and coconut shell activated carbon were studied and compared. Furthermore

hydrophilic and hydrophobic modifications on the low-cost wood activated carbon based adsorbent were conducted and the impact of ambient humidity on adsorbent performance was investigated. The results show that the coconut shell activated carbon based composite moisture adsorbent has the best humidity stability

and its adsorption capacity reaches the

maximum value (0.85 mmol/g) at room temperature and relative humidity of 30%. This is primarily attributed to its superior pore structure and relatively high hydrophobicity. Besides

the hydrophilic modified wood activated carbon-based adsorbent exhibits a rapid decline in adsorption performance as humidity increases

whereas the hydrophobic modified adsorbent demonstrates better humidity stability

with optimal CO

adsorption performance reaching 0.81 mmol/g at room temperature and relative humidity of 30%. Enhancing the CO

adsorption performance and environmental adaptability of moisture-swing adsorbents through hydrophobic modification holds great potential for promoting the wider application of DAC technology.

关键词

Keywords

references

邢伟 , 徐汝隆 , 高贺同 , 等 . 专利视角下空气中直接捕集CO 2 技术发展分析 [J ] . 洁净煤技术 , 2023 , 29 ( 4 ): 86 - 97 ．

XING W , XU R L , GAO H T , et al . Analysis of the development of direct capture of carbon dioxide in the air from patent perspective [J ] . Clean Coal Technology , 2023 , 29 ( 4 ): 86 - 97 ．

曹元辉 , 方群 , 王勇 , 等 . 国内外工业二氧化碳排放在线监测概况及在我国水泥行业应用前景 [J ] . 中国水泥 , 2022 , ( 6 ): 12 - 16 .

CAO Y H , FANG Q , WANG Y . Overview of online monitoring of industrial carbon dioxide emissions at home and abroad and its application prospects in China's cement industry [J ] . China Cement , 2022 , ( 6 ): 12 - 16 .

王鼎 , 张杰 , 杨伯伦 , 等 . 直接空气捕集CO 2 典型工艺分析及技术经济研究进展 [J ] . 煤炭科学技术 , 2023 , 51 ( S1 ): 215 - 221 .

WANG D , ZHANG J , YANG B L , et al . Research progress of typical process analysis and techno-economic research on direct air capture of carbon dioxide [J ] . Coal Science and Technology , 2023 , 51 ( S1 ): 215 - 221 .

National Academies of Sciences , Engineering , and Medicine . Negative emissions technologies and reliable sequestration: A research agenda [R ] . Washington DC : The National Academies Press , 2019 .

IEA . Direct air capture: A key technology for net zero [R ] . Paris : OECD Publishing , 2022 .

赵萌 , 胡飞扬 , 张一川 , 等 . 直接空气捕集CO 2 技术及应用进展 [J ] . 云南化工 , 2024 , 51 ( 4 ): 8 - 11+43 .

ZHAO M , HU F Y , ZHANG Y C , et al . Progress in direct air CO 2 capture technology and application [J ] . Yunnan Chemcial Technology , 2024 , 51 ( 4 ): 8 - 11+43 .

李德强 , 张琦 , 淦思瑄 , 等 . 化学吸收法直接空气碳捕集技术研究进展 [J/OL ] . 低碳化学与化工 : 1 - 14 [ 2024-08-13 ] . DOI: 10.12434/j.issn.2097-2547.20240186 http://dx.doi.org/10.12434/j.issn.2097-2547.20240186 .

LI D Q , ZHANG Q , GAN S X , et al . Research progress on chemical absorption direct air carbon caputure technology [J/OL ] . Low-Carbon Chemistry and Chemical Engineering : 1 - 14 [ 2024-08-13 ] . DOI: 10.12434/j.issn.2097-2547.20240186 http://dx.doi.org/10.12434/j.issn.2097-2547.20240186 .

OSCHATZ M , ANTONIETTI M . A search for selectivity to enable CO 2 capture with porous adsorbents [J ] . Energy & Environmental Science , 2018 , 11 ( 1 ): 57 - 70 .

SHI X Y , XIAO H , AZARABADI H , et al . Sorbents for the direct capture of CO 2 from ambient air [J ] . Angewandte Chemie International Edition , 2020 , 59 ( 18 ): 6984 - 7006 .

LIU R S , XU S , HAO G P , et al . Recent advances of porous solids for ultradilute CO 2 capture [J ] . Chemical Research in Chinese Universities , 2022 , 38 : 1 - 13 .

SHI X Y , XIAO H , KANAMORI K , et al . Moisture-driven CO 2 sorbents [J ] . Joule , 2020 , 4 ( 8 ): 1823 - 1837 .

SHI X Y , XIAO H , LACKNER K S , et al . Capture CO 2 from ambient air using nanoconfined ion hydration [J ] . Angewandte Chemie International Edition , 2016 , 128 ( 12 ): 4094 - 4097 .

高云芳 , 宋新山 . 季铵基吸附剂CO 2 变湿捕集-释放机制及相关材料研究进展 [J ] . 低碳化学与化工 , 2024 , 49 ( 11 ): 104 - 112 .

GAO Y F , SONG X S . Research progress on CO 2 moisture swing capture-release mech anism of quaternary ammonium-based adsorbents and related materials [J ] . Low-Carbon Chemistry and Chemical Engineering , 2024 , 49 ( 11 ): 104 - 112 .

SHI X Y , XIAO H , CHEN X , et al . The effect of moisture on the hydrolysis of basic salts [J ] . Chemistry-A European Journal , 2016 , 22 ( 51 ): 18326 - 18330 .

王凯 , 李锋 , 郑世强 , 等 . 负载 <math id="M19"><mi mathvariant="normal">P</mi><msubsup><mrow><mi mathvariant="normal">O</mi></mrow><mrow><mn mathvariant="normal">4</mn></mrow><mrow><mn mathvariant="normal">3</mn><mo>-</mo></mrow></msubsup></math> https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=74086825&type= 3.30200005 https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=74086826&type= 6.18066692 的离子交换树脂膜在烟气中变湿吸附CO 2 的性能研究 [J ] . 低碳化学与化工 , 2023 , 48 ( 3 ): 140 - 147 .

WANG K , LI F , ZHENG S Q , et al . Study on performance of ion exchange resin membranes loaded with PO <math id="M20"><msubsup><mrow/><mrow><mn mathvariant="normal">4</mn></mrow><mrow><mn mathvariant="normal">3</mn><mo>-</mo></mrow></msubsup></math> https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=74086808&type= 3.64066648 https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=74086827&type= 2.37066650 for moisture-swing adsorption of CO 2 from flue gas [J ] . Low-Carbon Chemistry and Chemical Engineering , 2023 , 48 ( 3 ): 140 - 147 .

WANG X R , CHEN Y , XU W Q , et al . Development o f high capacity moisture-swing DAC sorbent for direct air capture of CO 2 [J ] . Separation and Purification Technology , 2023 , 324 : 124489 .

侯成龙 . 季铵修饰聚合物的制备及空气二氧化碳捕集性能研究 [D ] . 杭州 : 浙江大学 , 2021 .

HOU C L . Synthesis of quaternary ammonium functionalized polymers and their application in direct air capture [D ] . Hangzhou : Zhejiang University , 2021 .

CHENG X Y , SUN X Y , ZHENG S Q , et al . Quaternized plant-based porous biochar for direct air capture of CO 2 by moisture-swing adsorption [J ] . Industrial & Engineering Chemistry Research , 2024 , 63 ( 5 ): 2320 - 2328 .

MASOUD N , BORDANABA-FLORIT G , VAN HAASTERECHT T , et al . Effect of support surface properties on CO 2 capture from air by carbon-supported potassium carbonate [J ] . Industrial & Engineering Chemistry Research , 2021 , 60 ( 38 ): 13749 - 13755 .

ZHENG S Q , CHENG X Y , ZHOU W J , et al . K 2 CO 3 on porous supports for moisture-swing CO 2 capture from ambient air [J ] . Asia-Pacific Journal of Chemical Engineering , 2024 , 19 ( 3 ): e3058 .

YAO X L , LI L Q , LI H L , et al . A new method for preparing hydrophilic-activated carbon through ester hydrolysis in an alkaline environment [J ] . Journal of Materials Science , 2014 , 49 : 4807 - 4815 .

LI X Q , ZHANG L , YANG Z Q , et al . Hydrophobic modified activated carbon using PDMS for the adsorption of VOCs in humid condition [J ] . Separation and Purification Technology , 2020 , 239 : 116517 .

WANG X R , SONG J Z , CHEN Y , et al . CO 2 absorption over ion exchange resins: The effect of amine functional groups and microporous structures [J ] . Industrial & Engineering Chemistry Research , 2020 , 59 ( 38 ): 16507 - 16515 .

HEIDARINEJAD Z , DEHGHANI M H , HEIDARI M , et al . Methods for preparation and activation of activated carbon: A review [J ] . Environmental Chemistry Letters , 2020 , 18 ( 2 ): 393 - 415 .

WANG T , LACKNER K S , WRIGHT A . Moisture swing sorbent for carbon dioxide capture from ambient air [J ] . Environmental Science & Technology 2011 , 45 ( 15 ): 6670 - 6675 .

LI F , ZHANG Y F , ZHENG S Q , et al . CO 2 removal in humid environment by ion exchange membranes [J ] . Asia-Pacific Journal of Chemical Engineering , 2022 , 17 ( 5 ): e2816 .

SONG J Z , LIU J , ZHAO W , et al . Quaternized chitosan/PVA aerogels for reversible CO 2 capture from ambient air [J ] . Industrial & Engineering Chemistry Research , 2018 , 57 ( 14 ): 4941 - 4948 .

HE H K , ZHONG M J , KONKOLEWICZ D , et al . Three-dimensionally ordered macroporous polymeric materials by colloidal crystal templating for reversible CO 2 capture [J ] . Advanced Functional Materials , 2013 , 23 ( 37 ): 4720 - 4728 .

浏览量

下载量

CNKI被引量

文章被引用时，请邮件提醒。

提交

工具集

关联资源

活性炭负载双金属催化剂的乙醇气相羰基化反应性能研究

基于K循环的KOH活化石油焦制高比表面积活性炭联产氢气

Ag/Ag₂CO₃宽电势催化剂电催化还原CO₂制CO性能研究

密度泛函理论用于新型相变吸收剂机理研究的进展分析

醇胺法吸收烟道气中二氧化碳的研究进展

活性炭基变湿吸附剂的亲疏水改性及其空气中CO2吸附性能研究

Study on hydrophilic/hydrophobic modification of activated carbon-based moisture-swing adsorbents and their CO2 adsorption performances in air

DOI：10.12434/j.issn.2097-2547.20240427

摘要

Abstract

关键词

Keywords

references

活性炭基变湿吸附剂的亲疏水改性及其空气中CO₂吸附性能研究

Study on hydrophilic/hydrophobic modification of activated carbon-based moisture-swing adsorbents and their CO₂ adsorption performances in air