含氟温室气体分离用膜材料研究进展

杨明山; 肖浩; 缪光武; 王传钊; 朱佳栋; 吴江平; 刘武灿

doi:10.12434/j.issn.2097-2547.20240404

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含氟温室气体分离用膜材料研究进展

更新时间：2025-02-17

- 含氟温室气体分离用膜材料研究进展
- Research progress on membrane materials for separation of fluorinated greenhouse gases
- 低碳化学与化工 2025: 1-9.
- 作者机构：
  
  浙江省化工研究院有限公司含氟温室气体替代及控制处理国家重点实验室，浙江杭州 310032
- 作者简介：
  
  杨明山（1998—），硕士，助理工程师，研究方向为含氟温室气体捕集，E-mail：yangmingshan@sinochem.com。
  朱佳栋（1991—），博士，高级工程师，研究方向为含氟气体吸附分离与纯化，E-mail：zhujiadong01@sinochem.com。
- 基金信息：
  
  “含氟温室气体替代及控制处理国家重点实验室建设”项目资助(2024ZY01038)
- DOI：10.12434/j.issn.2097-2547.20240404
  中图分类号： TQ028
- 网络出版日期：2025-02-17，
  
  收稿日期：2024-09-30，
  
  修回日期：2024-11-12，
- 稿件说明：
移动端阅览
杨明山,肖浩,缪光武等.含氟温室气体分离用膜材料研究进展[J].低碳化学与化工,

YANG Mingshan,XIAO Hao,MIAO Guangwu,et al.Research progress on membrane materials for separation of fluorinated greenhouse gases[J].Low-carbon Chemistry and Chemical Engineering,
杨明山,肖浩,缪光武等.含氟温室气体分离用膜材料研究进展[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20240404.

YANG Mingshan,XIAO Hao,MIAO Guangwu,et al.Research progress on membrane materials for separation of fluorinated greenhouse gases[J].Low-carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20240404.

摘要

随着人类活动的增加和工业化进程的加速，温室气体排放导致的包括全球变暖等气候变化问题日益严重。含氟温室气体具有极高的全球变暖潜能值（

GWP

），会造成严重的温室效应，已受到国际公约的严格管控。综述了多种含氟温室气体（SF

、NF

、全氟化碳（PFCs）和三氟甲烷（R23）等）的膜分离技术及分离用膜材料的研究进展，重点分析了不同膜材料的选择性、渗透性和稳定性，探讨了通过优化膜组件结构与工艺参数升高含氟温室气体回收率和纯度的可行性。开发具有高选择性

和稳定性的新型膜材料、优化膜组件设计以及探究复杂气体的分离方法是高性能膜材料的研发方向。

Abstract

With the increase of human activities and the acceleration of industrializatio

climate change problems caused by greenhouse gas emissions

including global warming

are becoming increasingly serious. Fluorinated greenhouse gases have extremely high global warming potentials (

GWP

)

causing serious greenhouse effects

and have been strictly regulated by international conventions. The research progress on membrane separation technologies and membrane materials for various fluorinated greenhouse gases (SF

perfluocarbon (PFCs) and trifluoromethane (R23)

etc.) was reviewed

with a focus on analyzing the selectivity

permeability and stability of different membrane materials. The feasibility of improving the recovery rate and purity of fluorinated greenhouse gases by optimizing membrane component structure and process parameters was explored. Developing new membrane materials with high selectivity and stability

optimizing membrane module design and exploring separation methods for complex gases are the research directions for high-performance membrane materials.

关键词

Keywords

references

PETER S C . Reduction of CO 2 to chemicals and fuels: A solution to global warming and energy crisis [J ] . ACS Energy Letters , 2018 , 3 ( 7 ): 1557 - 61 .

杨斌彬 , 何丽燕 , 梁家榞 , 等 . 非二氧化碳温室气体管控政策与减排技术研究综述 [J ] . 广东化工 , 2023 , 50 ( 3 ): 116 - 119 .

YANG B B , HE L Y , LIANG J Y , et al . Non-CO 2 greenhouse gas control policies and emission reduction technologies: A review [J ] . Guangdong Chemical Industry , 2023 , 50 ( 3 ): 116 - 119 .

张艳利 , 黄晓晴 , 王仪 , 等 . 中国消耗臭氧层物质和含氟温室气体研究进展 [J ] . 矿物岩石地球化学通报 , 2024 , 43 ( 5 ): 921 - 945 .

ZHANG Y L , HUANG X Q , WANG Y , et al . A review of ozone-depleting substances and fluorinated greenhouse gases in China [J ] . Bulletin of Mineralogy, Petrology and Geochemistry , 2024 , 43 ( 5 ): 921 - 945 .

SOVACOOL B K , GRIFFITHS S , KIM J S , et al . Climate change and industrial F-gases: A critical and systematic review of developments, sociotechnical systems and policy options for reducing synthetic greenhouse gas emissions [J ] . Renewable and Sustainable Energy Reviews , 2021 , 141 ( 3 ): 110759 .

LI J R , KUPPLER R J , ZHOU H C . Selective gas adsorption and separation in metal-organic frameworks [J ] . Chemical Society Reviews , 2009 , 38 , 1477 - 1504 .

刘春燕 , 刘凯 . 深冷分离技术在气体分离中的应用研究 [J ] . 石化技术 , 2024 , 31 ( 7 ): 213 - 215 .

LIU C Y , LIU K . Research on the application of deep-cooling separation technology in gas separation [J ] . Petrochemical Industry Technology , 2024 , 31 ( 7 ): 213 - 215 .

CHUAH C Y , LEE Y , BAE T H . Potential of adsorbents and membranes for SF 6 capture and recovery: A review [J ] . Chemical Engineering Journal , 2021 , 404 : 126577 .

CHEN S R , SHEN Y H , GUAN Z B , et al . Adsorption properties of SF 6 on zeolite NaY, 13X, activated carbon, and silica gel [J ] . Journal of Chemical & Engineering Data , 2020 , 65 ( 8 ): 4044 - 4051 .

LI S , ZHU S P , ZHOU Q , et al . Adsorption mechanism of decomposition gas of SF 6 circuit breaker on MOF-505 analogue [J ] . Vacuum , 2021 , 183 ( 1 ): 109816 .

SKARMOUTSOS I , KOUKARAS E N , GALIOTIS C , et al . Porous carbon nanotube networks and pillared graphene materials exhibiting high SF 6 adsorption uptake and separation selectivity of SF 6 /N 2 fluid mixtures: A comparative molecular simulation study [J ] . Microporous and Mesoporous Materials , 2020 , 307 : 110464 .

WANG S M , LAN H L , GUAN G W , et al . Amino-functionalized microporous MOFs for capturing greenhouse gases CF 4 and NF 3 with record selectivity [J ] . ACS Applied Materials & Interfaces , 2022 , 14 ( 35 ): 40072 - 40081 .

MU Y B , CHEN H H , XIANG H , et al . Defects-healing of SAPO-34 membrane by post-synthesis modification using organosilica for selective CO 2 separation [J ] . Journal of Membrane Science , 2019 , 575 : 80 - 88

胡凡 , 钟建铭 , 张宇 , 等 . 聚酰亚胺气体分离膜材料的结构与性能 [J ] . 高分子通报 , 2023 , 36 ( 8 ): 941 - 958 .

HU F , ZHONG J Y , ZHNAG Y , et al . Structures and properties of polyimide materials for membrane-based gas separation [J ] . Polymer Bulletin , 2023 , 36 ( 8 ): 941 - 958 .

赵辉 . 气体分离膜技术及其在石油化工领域的应用 [J ] . 石油化工 , 2023 , 52 ( 3 ): 412 - 417 .

ZHAO H . Gas separation membrane technology and its application in petrochemical industry [J ] . Petrochemical Technology , 2023 , 52 ( 3 ): 412 - 417 .

高克利 , 杨圆 , 周文俊 , 等 . SF 6 替代型环保绝缘气体: 研究、应用和展望 [J ] . 中国电机工程学报 , 2024 , 44 ( 18 ): 7395 - 7412 .

GAO K L , YANG Y , ZHOU W J , et al . SF 6 alternative environmentally friendly insulating gas: Research, application and outlook [J ] . Proceedings of the CSEE , 2024 , 44 ( 18 ): 7395 - 7412 .

陈雨亭 . 金属-有机框架及其成型材料吸附分离低浓度六氟化硫研究 [D ] . 杭州 : 浙江大学 , 2022 .

CHENG Y T . Study on adsorption separation of low concentration SF 6 on metal-organic frameworks and its shaping materials [D ] . Hangzhou : Zhejiang University , 2022 .

LI X W , ZHAO H , MURPHY A B . SF 6 -alternative gases for application in gas-insulated switchgear [J ] . Journal of Physics D: Applied Physics , 2018 , 51 ( 15 ): 115037 .

KIM K , KIM K S , LEE J E , et al . Status of SF 6 separation/refining technology development for electric industry in Korea [J ] . Separation and Purification Technology , 2018 , 200 : 29 - 35 .

KIM M B , YOON T U , HONG D Y , et al . High SF 6 /N 2 selectivity in a hydrothermally stable zirconium-based metal-organic framework [J ] . Chemical Engineering Journal , 2015 , 276 : 315 - 321 .

钟桂云 , 高林娜 , 吁苏云 , 等 . 膜法分离N 2 /SF 6 气体研究进展 [J ] . 浙江化工 , 2024 , 55 ( 9 ): 25 - 29 .

ZHONG G Y , GAO L N , YU S Y , et al . Research progress on membrane separation of N 2 /SF 6 gas [J ] . Zhejiang Chemical Industry , 2024 , 55 ( 9 ): 25 - 29 .

KIM M B , KIM K M , KIM T H , et al . Highly selective adsorption of SF 6 over N 2 in a bromine-functionalized zirconium-based metal-organic framework [J ] . Chemical Engineering Journal , 2018 , 339 : 223 - 229 .

YAMAMOTO O , TAKUMA T , KINOUCHI M . Recovery of SF 6 from N 2 /SF 6 gas mixtures by using a polymer membrane [J ] . IEEE Electrical Insulation Magazine , 2002 , 18 ( 3 ): 32 - 37 .

WOLIŃSKA-GRABCZYK A , JANKOWSKI A , SEKUŁA R , et al . Separation of SF 6 from binary mixtures with N 2 using commercial poly(4-methyl-1-pentene) films [J ] . Separation Science and Technology , 2011 , 46 ( 8 ): 1231 - 1240 .

LEE S J , LEE J S , LEE M W , et al . Separation of sulfur hexafluoride (SF 6 ) from ternary gas mixtures using commercial polysulfone (PSf) hollow fiber membranes [J ] . Journal of Membrane Science , 2014 , 452 : 311 - 318 .

CHOI J W , LEE S J , AN B , et al . Separation of sulfur hexafluoride from a nitrogen/sulfur hexafluoride mixture using a polymer hollow fiber membrane [J ] . Water , Air, & Soil Pollution, 2014 , 225 ( 2 ): 1807 .

LI Q , GUO M G , HE G H , et al . Movable membrane-based separation system with high SF 6 retention for large-scale gas-insulated transmission lines during maintenance [J ] . Separation and Purification Technology , 2021 , 264 : 118438 .

KIM D H , KO Y H , KIM T H , et al . Separation of N 2 /SF 6 binary mixtures using polyethersulfone (PESf) hollow fiber membrane [J ] . Korean Journal of Chemical Engineering , 2012 , 29 ( 8 ): 1081 - 1085 .

LEE W G , KANG S W . Highly selective polymer electrolyte membranes consisting of poly(2-ethyl-2-oxazoline) and Cu(NO 3 ) 2 for SF 6 separation [J ] . Scientific Reports , 2016 , 6 ( 1 ): 20430 .

DAI Y , LI Q , RUAN X H , et al . Fabrication of defect-free Matrimid ® asymmetric membranes and the elevated temperature application for N 2 /SF 6 separation [J ] . Journal of Membrane Science , 2019 , 577 : 258 - 265 .

NOURI A , JAFARI M , KAZMINMOGHADAM M , et al . Potential separation of SF 6 from air usi ng chabazite zeolite membranes [J ] . Chemical Engineering & Technology , 2014 , 37 ( 2 ): 317 - 324 .

ZHANG H X , OH Y J , TIKUE E T , et al . Enrichment of spent SF 6 gas by zeolite membranes for direct reuse in gas-insulated switchgear units [J ] . Separation and Purification Technology , 2022 , 303 : 122223 .

ZHU G H , ZHANG F Y , RIVERA P . Met al. Molecularly mixed composite membranes for advanced separation processes [J ] . Angewandte Chemie International Edition , 2019 , 58( 9 ) 2638 - 2643 .

周言 , 钟强 , 刘倩 , 等 . NF 3 与CF 4 分离纯化技术路线研究进展 [J ] . 应用化工 , 2023 , 52 ( 1 ): 266 - 272 .

ZHOU Y , ZHONG Q , LIU Q , et al . Progress on technology route for separation and purification of NF 3 and CF 4 [J ] . Applied Chemical Industry , 2023 , 52 ( 1 ): 266 - 272 .

邹震雷 , 李和寅 , 黄梦君 , 等 . 关于惰性含氟温室气体转化与利用的研究进展 [J ] . 有机化学 , 2024 , 44 ( 6 ): 1831 - 1852 .

ZOU Z L , LI H Y , HUANG M J , et al . Recent advances in conversion and use of inert fluorinated greenhouse gases [J ] .

Chinese Journal of Organic Chemistry , 2024 , 44 ( 6 ): 1831 - 1852 .

尹强 , 许俊斌 , 周瑾艳 , 等 . 三氟化氮气体的制备及纯化方法综述 [J ] . 广东化工 , 2019 , 46 ( 8 ): 112 - 113 .

YIN Q , XU J B , ZHOU J Y , et al . Preparation and purification of nitrogen trifluoride [J ] . Guangdong Chemical Industry , 2019 , 46 ( 8 ): 112 - 113 .

KIM H S , KIM E Y , LEE P S . Study of the enrichment of NF 3 waste gas using zeolite and polymeric membranes [J ] . Separation and Purification Technology , 2019 , 220 : 1 - 7 .

LEE P S , LIM M S , PARK A , et al . A zeolite membrane module composed of SAPO-34 hollow fibers for use in fluorinated gas enrichment [J ] . Journal of Membrane Science , 2017 , 542 : 123 - 132 .

PARK S H , KANG W R , KWON H T , et al . The polymeric upper bound for N 2 /NF 3 separation and beyond; ZIF-8 containing mixed matrix membranes [J ] . Journal of Membrane Science , 2015 , 486 : 29 - 39 .

KIM S J , PARK Y I , NAM S-E , et al . Separations of F-gases from nitrogen through thin carbon membranes [J ] . Separation and Purification Technology , 2016 , 158 : 108 - 114 .

张宇婷 . 铝电解生产过程全氟化碳排放现状与分析 [J ] . 绿色矿冶 , 2023 , 39 ( 4 ): 36 - 40 .

ZHANG Y T . Current situation and analysis of perfluorocarbon emissions from aluminum electrolysis production process [J ] . Sustainable Mining and Metallurgy , 2023 , 39 ( 4 ): 36 - 40 .

相震 . 减排全氟化碳应对全球气候变化 [J ] . 三峡环境与生态 , 2011 , 33 ( 4 ): 15 - 18 .

XIANG Z . PFCs emission reduction to deal with the global climate change [J ] . Environment and Ecology in the Three Gorges , 2011 , 33 ( 4 ): 15 - 18 .

TRUDINGER C M , FRASER P J , ETHERIDGE D M , et al . Atmospheric abundance and global emissions of perfluorocarbons CF 4 , C 2 F 6 and C 3 F 8 since 1800 inferred from ice core, firn, air archive and in situ measurements [J ] . Atmospheric Chemistry and Physics , 2016 , 16 : 11733 - 11754 .

曹军 , 汪琦 , 徐政 , 等 . 我国环境空气中温室气体监测技术研究进展 [J ] . 环境监控与预警 , 2022 , 14 ( 1 ): 1 - 6 .

CAO J , WANG Q , XU Z , et al . Research progress in monitoring technology for atmospheric greenhouse gases in China [J ] . Environmental Monitoring and Forewarning , 2022 , 14 ( 1 ): 1 - 6 .

宋彦敏 , 周连宁 , 郝文龙 , 等 . 全氟化合物的污染现状及国内外研究进展 [J ] . 环境工程 2017 , 35 ( 10 ): 82 - 86 .

SONG Y M , ZHOU L N , HAO W L , et al . Pollution status and related research progress of perfluorinated compounds [J ] . Environmental Engineering . 2017 , 35 ( 10 ): 82 - 86 .

夏萌 . 电解铝生产温室气体减排对策研究 [D ] . 北京 : 清华大学 , 2014 .

XIA M . Reasearch on greenhouse gases reduction countermeasures of aluminum production [D ] . Beijing : Tsinghua University , 2014 .

WIJMANS J G , HE Z , SU T T , et al . Recovery of perfluoroethane from chemical vapor deposition operations in the semiconductor industry [J ] . Separation and Purification Technology 2004 , 35 ( 3 ): 203 - 213 .

BISSETT H , KRIEG H M . Synthesis of a composite inorganic membrane for the separation of nitrogen, tetrafluoromethane and hexafluoropropylene [J ] . South African Journal of Science , 2013 , 109 ( 9/10 ): 20130028 .

王术成 , 刘武灿 , 周飞翔 , 等 . 温室气体三氟甲烷资源化转化技术研究进展 [J ] . 应用化工 , 2021 , 50 ( 4 ): 1118 - 1123 .

WANG S C , LIU W C , ZHOU F X , et al . Research progress on resource utilization of potent greenhouse CHF 3 gas [J ] . Applied Chemical Industry , 2021 , 50 ( 4 ): 1118 - 1123 .

蒲雨灵 . 低共熔溶剂分离氯化氢和三氟甲烷气体的性能研究 [D ] . 北京 : 北京化工大学 , 2023 .

PU Y L . On absorptive separation of HCl and trifluoromethane by deep eutectic solvents [D ] . Beijing : Beijing University of Chemical Technology , 2023 .

程伟 . 二氟一氯甲烷合成装置中三氟甲烷的精制回收工艺研究 [J ] . 有机氟工业 , 2022 , ( 2 ): 23 - 25 .

CHENG W . Study on purification and recovery process of trifluoromethane in difluorochloromethane synthesis unit [J ] .

Organic-Fluorine Industry , 2022 , ( 2 ): 23 - 25 .

MCCULLOH A , MIDGLEY P M , LINDLEY A A . Recent changes in the production and global atmospheric emissions of chlorodifluoromethane (HCFC-22) [J ] . Atmospheric Environment , 2006 , 40 ( 5 ): 936 - 942 .

王跃 . 膜法分离二氟一氯甲烷/三氟甲烷混合气的研究 [D ] . 大连理工大学 , 2008 .

WANG Y . Study on the separation of HCHC-22/HFC-23 gas mixture by membrane [D ] . Dalian : Dalian University of

Technology , 2008 .

RUAN X H , DAI Y , DU L , et al . Further separation of HFC-23 and HCFC-22 by coupling multi-stage PDMS membrane unit to cryogenic distillation [J ] . Separation & Purification Technology , 2015 , 156 : 673 - 682 .

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