费托合成直接制航空煤油中双功能催化剂的研究进展

刘津旭; 吕帅帅; 李红伟; 周秋明; 牛丛丛; 徐润; 李新刚

doi:10.12434/j.issn.2097-2547.20240152

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费托合成直接制航空煤油中双功能催化剂的研究进展

C1化学与催化转化

- 费托合成直接制航空煤油中双功能催化剂的研究进展
- Research progress on bifunctional catalysts for direct synthesis of jet fuel from Fischer-Tropsch synthesis
- 低碳化学与化工 2025, 50(1): 13-19.
- 作者机构：
  
  1.中石化石油化工科学研究院有限公司，北京 100083
  2.天津大学化工学院，化学工程联合国家重点实验室，化学化工协同创新中心（天津），海河可持续化学转化实验室，天津市应用催化科学与工程重点实验室，天津 300350
  3.天津大学浙江研究院（绍兴），浙江绍兴 312300
- 作者简介：
  
  刘津旭（1998—），硕士研究生，研究方向为碳一化学，E-mail：liujinxu.ripp@sinopec.com。
  吕帅帅（1993—），博士，副研究员，研究方向为碳一化学，E-mail：lvshuaishuai.ripp@sinopec.com；
  徐润（1976—），博士，高级工程师，研究方向为石油炼制和煤化工工艺，E-mail：xurun.ripp@sinopec.com；
  李新刚（1975—），博士，教授，研究方向为多相催化，E-mail：xingang_li@tju.edu.cn。
- 基金信息：
  
  国家重点研发计划(2021YFE0191200)
- DOI：10.12434/j.issn.2097-2547.20240152
  中图分类号： TQ426;O643.3
- 纸质出版日期：2025-01-25，
  
  收稿日期：2024-04-10，
  
  修回日期：2024-05-09，
- 稿件说明：
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刘津旭, 吕帅帅, 李红伟, 等. 费托合成直接制航空煤油中双功能催化剂的研究进展[J]. 低碳化学与化工, 2025,50(1):13-19.

LIU JINXU, LV SHUAISHUAI, LI HONGWEI, et al. Research progress on bifunctional catalysts for direct synthesis of jet fuel from Fischer-Tropsch synthesis. [J]. Low-carbon chemistry and chemical engineering, 2025, 50(1): 13-19.
刘津旭, 吕帅帅, 李红伟, 等. 费托合成直接制航空煤油中双功能催化剂的研究进展[J]. 低碳化学与化工, 2025,50(1):13-19. DOI： 10.12434/j.issn.2097-2547.20240152.

LIU JINXU, LV SHUAISHUAI, LI HONGWEI, et al. Research progress on bifunctional catalysts for direct synthesis of jet fuel from Fischer-Tropsch synthesis. [J]. Low-carbon chemistry and chemical engineering, 2025, 50(1): 13-19. DOI： 10.12434/j.issn.2097-2547.20240152.

摘要

费托合成可将生物质来源的合成气直接转化为航空煤油（简称“航煤”），是最具应用前景的生物航煤生产技术之一。受Anderson-Schulz-Flory（ASF）分布规律的限制，费托合成直接制航煤的产物选择性有限，如何提高航煤选择性仍是当前该领域面临的重要挑战。利用双功能催化剂可将费托合成活性中心与分子筛酸中心耦合，可实现CO加氢与裂解、异构化等二次反应的接力，进而达到有效调控特定馏分选择性的目的。介绍了双功能催化剂的作用机理，对比了现有报道中费托合成的反应性能，阐述了尺寸效应、孔结构调控、酸性质调控和助剂效应在不同催化体系中的调控策略及构效关系，并对双功能催化剂在费托合成直接制航煤中的应用进行了展望。

Abstract

Fischer-Tropsch synthesis (FTS) can directly convert syngas derived from biomass into jet fuel

making it one of the most promising technologies for producing bio-based jet fuel. However

the selectivity of jet fuel in direct FTS is limited by the Anderson-Schulz-Flory (ASF) distribution law

posing a significant challenge in improving selectivity of jet fuel. Bifunctional catalysts

which couple FTS active centers with zeolite acid centers

enable the relay of CO hydrogenation with secondary reactions such as hydrocracking and isomerization

effectively controlling the selectivity for specific fractions. The mechanisms of bifunctional catalysts were introduced

and the reaction performances reported in existing studies were compared. The synthetic strategy and structure-performance relationship in different catalytic systems were emphasized

including the size effect

pore structure and acidity control of zeolites

as well as promoter effect. An outlook on the application of bifunctional catalysts for direct synthesis of jet fuel from FTS was provided.

关键词

费托合成航空煤油双功能催化剂

Keywords

Fischer-Tropsch synthesisjet fuelbifunctional catalysts

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