Research progress on oxidative cracking catalysts of light alkanes to light olefins

ZHANG Guoxia; HAO Pengbo; JIAO Nianming; WANG Hui

doi:10.12434/j.issn.2097-2547.20240341

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Research progress on oxidative cracking catalysts of light alkanes to light olefins

- Research progress on oxidative cracking catalysts of light alkanes to light olefins
- Pages: 1-9(2024)
- 作者机构：
  
  1.郑州中科新兴产业技术研究院，河南郑州 450003
  2.河南大学，郑州中科新兴产业技术研究院龙子湖新能源实验室，河南郑州 450003
  3.中国科学院过程工程研究所离子液体清洁过程北京市重点实验室，北京 100190
- 作者简介：
- 基金信息：
- DOI：10.12434/j.issn.2097-2547.20240341
  CLC： TQ032
- Published Online：26 December 2024，
  
  Received：16 August 2024，
  
  Revised：19 September 2024，
- 稿件说明：
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张国霞,郝鹏波,焦念明等.轻质烷烃氧化裂解制低碳烯烃催化剂研究进展[J].低碳化学与化工,

ZHANG Guoxia,HAO Pengbo,JIAO Nianming,et al.Research progress on oxidative cracking catalysts of light alkanes to light olefins[J].Low-carbon Chemistry and Chemical Engineering,
张国霞,郝鹏波,焦念明等.轻质烷烃氧化裂解制低碳烯烃催化剂研究进展[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20240341.

ZHANG Guoxia,HAO Pengbo,JIAO Nianming,et al.Research progress on oxidative cracking catalysts of light alkanes to light olefins[J].Low-carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20240341.

摘要

轻质烷烃（C

烷烃）氧化裂解工艺是生产低碳烯烃的路线之一，氧化裂解分为催化氧化裂解（COC）和氧化还原氧化裂解（ROC）两类。COC催化体系因存在氧气，容易引起过度氧化，导致CH

和CO

收率升高、烯烃收率降低；ROC催化体系虽降低了过度氧化问题，但操作温度和工艺复杂性限制了实际应用。概述了COC反应机理，并详细总结了应用于该体系的多种催化剂，包括稀土金属、贵金属、碱金属及其他催化剂。同时，介绍了ROC反应机理及用于该体系的钒基、钙钛矿催化剂。基于对现有研究的分析，总结了氧化裂解催化剂面临的挑战，对未来发展方向进行了展望，以期为新型氧化裂解高效催化剂开发提供参考。

Abstract

Oxidative cracking process of light alkanes (C

alkanes) is one of the key pathways for producing light olefins. Oxidative cracking can be divided into two types: Catalytic oxidative cracking (COC) and redox oxidative cracking (ROC). In COC systems

the presence of oxygen often leads to over-oxidation

resulting in higher yields of CH₄ and CO

and lower olefin yields. Although ROC systems decreases the issue of over-oxidation

their high operating temperatures and process complexity limit broader industrial application. The reaction mechanism of COC process was summarized

and catalysts used in this system were summarized

including rare-earth metals

noble metals

alkali metals and other catalysts. Meanwhile

the ROC reaction mechanism was discussed

along with the vanadium-based and perovskite catalysts. Based on analysis of current research

the challenges faced by oxidative cracking catalysts were summarized

and the future development direction was proposed

aiming to provide reference for the development of new and highly efficient oxidative cracking catalysts.

关键词

轻质烷烃氧化裂解催化剂低碳烯烃反应机理

Keywords

light alkanesoxidative crackingcatalystlight olefinsreaction mechanism

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