CO<sub>2</sub>氧化低碳烷烃脱氢非贵金属基催化剂研究进展

殷铭昊; 王海燕; 郭新闻

doi:10.12434/j.issn.2097-2547.20260188

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CO₂氧化低碳烷烃脱氢非贵金属基催化剂研究进展

更新时间：2026-08-04

- CO₂氧化低碳烷烃脱氢非贵金属基催化剂研究进展
- Research progress of non-noble metal-based catalysts for CO₂oxidative dehydrogenation of low-carbon alkanes
- 低碳化学与化工 2026: 1-15.
- 作者机构：
  
  大连理工大学化工海洋与生命生学院，辽宁盘锦 115004
- 作者简介：
  
  殷铭昊（2002—），硕士研究生，研究方向为低碳烷烃脱氢，E-mail：jjy810975@163.com。
  王海燕（1988—），博士，副教授，研究方向为能源小分子转化、生物质高值转化和VOCs催化氧化，E-mail：haiyanwang@dlut.edu.cn；
  郭新闻（1967—），博士，教授，研究方向为多功能材料设计合成和小分子催化转化，E-mail：guoxw@dlut.edu.cn。
- 基金信息：
  
  国家自然科学基金青年科学基金(22202028);引进人才科研专题项目(DUT24RC(3)061);博士后国际交流计划引进项目(YJ20210238);博士后科学基金面上项目(2022M720638);国家重点研发计划(ZX20241035);中石化企业项目(322068)
- DOI：10.12434/j.issn.2097-2547.20260188
  中图分类号： TQ116.3
- 收稿：2026-04-23，
  
  修回：2026-06-05，
  
  网络首发：2026-07-30，
- 稿件说明：
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殷铭昊,王海燕,郭新闻.CO₂氧化低碳烷烃脱氢非贵金属基催化剂研究进展[J].低碳化学与化工,DOI:10.12434/j.issn.2097-2547.20260188.

YIN Minghao,WANG Haiyan,GUO Xinwen.Research progress of non-noble metal-based catalysts for CO₂oxidative dehydrogenation of low-carbon alkanes[J].Low-Carbon Chemistry and Chemical Engineering,DOI:10.12434/j.issn.2097-2547.20260188.
殷铭昊,王海燕,郭新闻.CO₂氧化低碳烷烃脱氢非贵金属基催化剂研究进展[J].低碳化学与化工,DOI:10.12434/j.issn.2097-2547.20260188. DOI：

YIN Minghao,WANG Haiyan,GUO Xinwen.Research progress of non-noble metal-based catalysts for CO₂oxidative dehydrogenation of low-carbon alkanes[J].Low-Carbon Chemistry and Chemical Engineering,DOI:10.12434/j.issn.2097-2547.20260188. DOI：

摘要

低碳烯烃作为重要的化工平台产品，其市场需求持续增长。传统烯烃生产工艺不仅高度依赖化石资源，还会造成环境污染。页岩气和天然气资源的大规模开发与利用为烯烃生产提供了丰富的低碳烷烃资源，低碳烷烃脱氢制烯烃技术成为具有广阔应用前景的烯烃制备路线。近年来，CO

氧化低碳烷烃脱氢（CO

-ODH）受到广泛关注，开发具有高催化活性和稳定性的非贵金属基催化剂是CO

-ODH领域的重要研究方向。对比分析了典型非贵金属基CO

-ODH催化剂的催化性能，归纳了催化机理，并对非贵金属基CO

-ODH催化剂面临的主要挑战和相应改进策略进行了探讨。

Abstract

Low-carbon olefins

as the important platform products in chemical industry

have witnessed a continuous increase in market demand. The traditional olefin production process not only relies heavily on fossil resources

but also causes environmental pollution. The increased utilization of shale gas and natural gas has provided abundant light alkane resources to olefin production

thus making dehydrogenation of low-carbon alkanes a promising route for olefin production. In recent years

-assisted oxidative dehydrogenation (CO

-ODH) has attracted considerable attention

and developing highly active and stable non-noble metal-based catalysts is proved to be a key research target in CO

-ODH. The catalytic performances of typical non-noble metal-based catalysts were compared and analyzed

and t

he catalytic mechanisms were summarized

and the main challenges faced by non-noble metal-based CO

-ODH catalysts along with corresponding improvement strategies were discussed.

关键词

Keywords

references

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CO2氧化低碳烷烃脱氢非贵金属基催化剂研究进展

Research progress of non-noble metal-based catalysts for CO2 oxidative dehydrogenation of low-carbon alkanes

DOI：10.12434/j.issn.2097-2547.20260188

摘要

Abstract

关键词

Keywords

references

CO₂氧化低碳烷烃脱氢非贵金属基催化剂研究进展

Research progress of non-noble metal-based catalysts for CO₂oxidative dehydrogenation of low-carbon alkanes