逆水煤气变换反应催化剂及其动态结构演变研究进展

刘强; 胡亦工; 张淼; 刘宇龙; 张光辉; 郭新闻

doi:10.12434/j.issn.2097-2547.20250424

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逆水煤气变换反应催化剂及其动态结构演变研究进展

更新时间：2026-04-01

- 逆水煤气变换反应催化剂及其动态结构演变研究进展
- Research progress on catalysts for reverse water-gas shift reaction and their dynamic structural evolution
- 低碳化学与化工 2026: 1-11.
- 作者机构：
  
  1.山东电力工程咨询院有限公司，山东济南 250013
  2.大连理工大学化工学院，精细化工全国重点实验室，教育部智能材料化工前沿科学中心，辽宁大连 116024
- 作者简介：
  
  刘强（1979—），本科，高级工程师，研究方向为绿色氢基能源领域工程设计，E-mail：liuqiang08@spic.com.cn。
  郭新闻（1967—），博士，教授，研究方向为绿色能源催化，E-mail：guoxw@dlut.edu.cn。
- 基金信息：
  
  国家自然科学基金(22372022);中央高校基本科研业务费专项资金(DUT22LAB602);兴辽英才计划青年拔尖人才项目(XLYC2203126);卓越共创计划国际交流基金(DUTIO-ZG-202505)
- DOI：10.12434/j.issn.2097-2547.20250424
  中图分类号： TQ426
- 收稿：2025-11-10，
  
  修回：2025-12-09，
  
  网络首发：2026-03-24，
- 稿件说明：
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刘强,胡亦工,张淼等.逆水煤气变换反应催化剂及其动态结构演变研究进展[J].低碳化学与化工,

LIU Qiang,HU Yigong,ZHANG Miao,et al.Research progress on catalysts for reverse water-gas shift reaction and their dynamic structural evolution[J].Low-Carbon Chemistry and Chemical Engineering,
刘强,胡亦工,张淼等.逆水煤气变换反应催化剂及其动态结构演变研究进展[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20250424.

LIU Qiang,HU Yigong,ZHANG Miao,et al.Research progress on catalysts for reverse water-gas shift reaction and their dynamic structural evolution[J].Low-Carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20250424.

摘要

逆水煤气变换（RWGS）反应是实现CO

资源化利用和“双碳”目标的有效途径

，将CO

加氢转化为CO是合成高附加值化学品的有效方法。系统综述了RWGS反应机理、催化剂研究进展及其在反应过程中的动态结构演变。反应机理主要包括氧化-还原机理和缔合反应机理，其主导路径受催化剂组成与反应条件调控。在催化剂方面，贵金属（如Pt、Au）、非贵金属（如Cu、Ni和Fe）及过渡金属碳化物（如Mo

C）均展现出良好的RWGS反应催化性能，其中金属-载体相互作用、助剂修饰及界面结构调控是提升催化活性的关键策略。在高温及复杂反应气氛中，催化剂常发生动态结构演变，如晶相转变、渗碳和元素迁移等，影响着催化剂的真实活性位点与催化活性。通过探究RWGS反应催化剂动态结构演变，可为其他反应（如烷烃脱氢反应）的催化剂设计提供有效策略。最后总结了目前RWGS反应催化剂面临的挑战并提出了未来发展的方向。

Abstract

The reverse water-gas shift (RWGS) reaction is as an effective approach to achieving CO

resource utilization and the “dual carbon” goals

and CO

hydrogenation to produce CO serves as a viable method for synthesizing high-value chemicals. The RWGS reaction mechanisms

research progress on catalysts and their dynamic structural evolution during the reaction were systematically summarized. Reaction mechanisms primarily include the redox mechanism and the associative mechanism

and its dominant pathway is regulated by catalyst compositions and reaction conditions. In terms of catalysts

noble metals (such as Pt and Au)

non-noble metals (such as Cu

Ni and Fe) and transition metal carbides (such as Mo

C) exhibit excellent catalytic performances. Among these

metal-support interactions

promoter modification

and interfacial structure regulation are key strategies for enhancing catalytic activities. Under high temperatures and complex atmospheres

catalysts often undergo dynamic structural evolution

such as phase transformation

carburization and elemental migration. These changes profoundly influence the real active sites and catalytic activities of the catalysts. By exploring the dynamic structural evolution of catalysts for RWGS reaction

effective strategies can be provided for designing catalysts for other reactions

such as alkane dehydrogenation reactions. Finally

the current challenges of the catalysts for RWGS reaction were summarized

and future research directions were proposed.

关键词

Keywords

references

BP . BP energy outlook 2025 edition [R ] . BP , 2025 .

FRIEDLINGSTEIN P , O’SULLIVAN M , JONES M W , et al . Global carbon budget 2024 [J ] . Earth System Science Data , 2025 , 17 ( 3 ): 965 - 1039 .

RAVAL A , RAMANATHAN V . Observational determination of the greenhouse effect [J ] . Nature , 1989 , 342 : 758 - 761 .

PIELKE R A , MARLAND G , BETTS R A , et al . The influence of land-use change and landscape dynamics on the climate system: Relevance to climate-change policy beyond the radiative effect of greenhouse gases [J ] . Philosophical Transactions of the Royal Society A , 2002 , 360 : 1705 - 1719 .

中国气象局 . 中国气候变化蓝皮书（2022） [M ] . 北京 : 科学出版社 , 2022 .

China Meteorological Administration . Blue book on climate change in China (2022) [M ] . Beijing : Science Press , 2022 .

刘玲玲 . 以更强有力的行动应对气候变化 [N ] . 人民日报 , 2023-01-30 (15).

LIU L L . Take stronger action to address climate change [N ] . People’s Daily , 2023-01-30 (15).

YE J Y , DIMITRATOS N , ROSSI L M , et al . Hydrogenation of CO 2 for sustainable fuel and chemical production [J ] . Science , 2025 , 387 ( 6737 ): eadn9388 .

WANG J Y , ZHANG G H , ZHU J , et al . CO 2 hydrogenation to methanol over In 2 O 3 -based catalysts: From mechanism to catalyst development [J ] . ACS Catalysis , 2021 , 11 ( 3 ): 1406 - 1423 .

WANG D , XIE Z H , POROSOFF M D , et al . Recent advances in carbon dioxide hydrogenation to produce olefins and aromatics [J ] . Chem , 2021 , 7 ( 9 ): 2277 - 2311 .

BAHMANPOUR A M , SIGNORILE M , KRÖCHER O , Recent progress in syngas production via catalytic CO 2 hydrogenation reaction [J ] . Applied Catalysis B: Environmental , 2021 , 295 : 120319 .

RA E C , KIM K Y , KIM E H , et al . Recycling carbon dioxide through catalytic hydrogenation: Recent key developments and perspectives [J ] . ACS Catalysis , 2020 , 10 ( 19 ): 11318 - 11345 .

SAEIDI S , NAJARI S , FAZLOLLAHI F , et al . Mechanisms and kinetics of CO 2 hydrogenation to value-added products: A detailed review on current status and future trends [J ] . Renewable and Sustainable Energy Reviews , 2017 , 80 : 1292 - 1311 .

ANSARI M B , PARK S E . Carbon dioxide utilization as a soft oxidant and promoter in catalysis [J ] . Energy Environmental Science , 2012 , 5 ( 11 ): 9419 .

BIAN K , ZHANG G H , ZHU J , et al . Promoting propane dehydrogenation with CO 2 over the PtFe bimetallic catalyst by eliminating the non-selective Fe(0) phase [J ] . ACS Catalysis , 2022 , 12 ( 11 ): 6559 - 6569 .

GU Y W , ZHANG G H , WANG H , et al . The role of CO 2 in oxidative propane dehydrogenation over Ga 2 O 3 /SiO 2 catalysts [J ] . Energy & Fuels , 2025 , 39 ( 40 ): 19400 - 19410 .

RO I , SENER C , STADELMAN T M , et al . Measurement of intrinsic catalytic activity of Pt monometallic and Pt-MoO x interfacial sites over visible light enhanced PtMoO x /SiO 2 catalyst in reverse water gas shift reaction [J ] . Journal of Catalysis , 2016 , 344 : 784 - 794 .

ASHOK J , PATI S , HONGMANOROM P , et al . A review of recent catalyst advances in CO 2 methanation processes [J ] . Catalysis Today , 2020 , 356 : 471 - 489 .

MIAO B , MA S S K , WANG X , et al . Catalysis mechanisms of CO 2 and CO methanation [J ] . Catalysis Science & Technology , 2016 , 6 ( 12 ): 4048 - 4058 .

KIM S S , LEE H H , HONG S C . The effect of the morphological characteristics of TiO 2 supports on the reverse water-gas shift reaction over Pt/TiO 2 catalysts [J ] . Applied Catalysis B: Environmental , 2012 , 119/120 : 100 - 108 .

PETTIGREW D J , TRIMM D L , CANT N W . The effects of rare earth oxides on the reverse water-gas shift reaction on palladium/alumina [J ] . Catalysis Letters , 1994 , 28 ( 2 ): 313 - 319 .

ISHITO N , HARA K , NAKAJIMA K , et al . Selective synthesis of carbon monoxide via formates in reverse water-gas shift reaction over alumina-supported gold catalyst [J ] . Journal of Energy Chemistry , 2016 , 25 ( 2 ): 306 - 310 .

LIU H X , LI S Q , WANG W W , et al . Partially sintered copper-ceria as excellent catalyst for the high-temperature reverse water gas shift reaction [J ] . Nature Communications , 2022 , 13 : 867 .

LIANG H J , ZHANG B , GAO P , et al . Strong Co-O-Si bonded ultra-stable single-atom Co/SBA-15 catalyst for selective hydrogenation of CO 2 to CO [J ] . Chem Catalysis , 2022 , 2 ( 3 ): 610 - 621 .

KIM K Y , JANG W , BYUN W J , et al . Highly efficient layered double hydroxide-derived bimetallic Cu-Co alloy catalysts for the reverse water-gas shift reaction [J ] . ACS Catalysis , 2024 , 14 ( 9 ): 7020 - 7031 .

SU X , YANG X L , ZHAO B , et al . Designing of highly selective and high-temperature endurable RWGS heterogeneous catalysts: Recent advances and the future directions [J ] . Journal of Energy Chemistry , 2017 , 26 ( 5 ): 854 - 867 .

WANG L , WANG H Y , HUANG H L , et al . Transition metal carbides: Emerging CO 2 hydrogenation catalysts, from recent advance to future exploration [J ] . Advanced Functional Materials , 2024 , 34 ( 7 ): 2309850 .

GONZÁLEZ-CASTAÑO M , DORNEANU B , ARELLANO-GARCÍA H . The reverse water gas shift reaction: A process systems engineering perspective [J ] . Reaction Chemistry & Engineering , 2021 , 6 ( 6 ): 954 - 976 .

GINÉS M J L , MARCHI A J , APESTEGUIA C R . Kinetic study of the reverse water-gas shift reaction over CuO/ZnO/Al 2 O 3 catalysts [J ] . Applied Catalysis A: General , 1997 , 154 : 155 - 171 .

SUN X T , YU J F , ZADA H , et al . Reaction-induced unsaturated Mo oxycarbides afford highly active CO 2 conversion catalysts [J ] . Nature Chemistry , 2024 , 16 ( 12 ): 2044 - 2053 .

GOGUET A , MEUNIER F C , TIBILETTI D , et al . Spectrokinetic investigation of reverse water-gas-shift reaction intermediates over a Pt/CeO 2 catalyst [J ] . The Journal of Physical Chemistry B , 2004 , 108 : 20240 - 20246 .

BOBADILLA L F , SANTOS J L , IVANOVA S , et al . Unravelling the role of oxygen vacancies in the mechanism of the reverse water-gas shift reaction by operando DRIFTS and ultraviolet-visible spectroscopy [J ] . ACS Catalysis , 2018 , 8 ( 8 ): 7455 - 7467 .

KIM S S , LEE H H , HONG S C . A study on the effect of support’s reducibility on the reverse water-gas shift reaction over Pt catalysts [J ] . Applied Catalysis A: General , 2012 , 423-424 : 100 - 107 .

YANG X L , SU X , CHEN X D , et al . Promotion effects of potassium on the activity and selectivity of Pt/zeolite catalysts for reverse water gas shift reaction [J ] . Applied Catalysis B: Environmental , 2017 , 216 : 95 - 105 .

RABEE A I M , ZHAO D , CISNEROS S , et al . Role of interfacial oxygen vacancies in low-loaded Au-based catalysts for the low-temperature reverse water gas shift reaction [J ] . Applied Catalysis B: Environmental , 2023 , 321 : 122083 .

UPADHYE A A , RO I , ZENG X , et al . Plasmon-enhanced reverse water gas shift reaction over oxide supported Au catalysts [J ] . Catalysis Science & Technology , 2015 , 5 ( 5 ): 2590 - 2601 .

CHEN C S , CHENG W H , LIN S S . Enhanced activity and stability of a Cu/SiO 2 catalyst for the reverse water gas shift reaction by an iron promoter [J ] . Chemical Communications , 2001 , ( 18 ): 1770 - 1771 .

CHEN C S , CHENG W H , LIN S S . Study of reverse water gas shift reaction by TPD, TPR and CO 2 hydrogenation over potassium-promoted Cu/SiO 2 catalyst [J ] . Applied Catalysis A: General , 2003 , 238 : 55 - 67 .

SUN F M , YAN C F , WANG Z D , et al . Ni/Ce-Zr-O catalyst for high CO 2 conversion during reverse water gas shift reaction (RWGS) [J ] . International Journal of Hydrogen Energy , 2015 , 40 ( 46 ): 15985 - 15993 .

PARK S W , JOO O S , JUNG K D , et al . Development of ZnO/Al 2 O 3 catalyst for reverse-water-gas-shift reaction of CAMERE (carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction) process [J ] . Applied Catalysis A: General , 2001 , 211 : 81 - 90 .

SAKHAEI Z , REZAEI M . Mechanochemical synthesis of ZnO.Al 2 O 3 powders with various Zn/Al molar ratios and their applications in reverse water-gas shift reaction [J ] . Environmental Science and Pollution Research , 2021 , 28 : 13790 - 13799 .

KOVACEVIC M , MOJET B L , VAN OMMEN J G , et al . Effects of morphology of cerium oxide catalysts for reverse water gas shift reaction [J ] . Catalysis Letters , 2016 , 146 : 770 - 777 .

LIU Y J , LI Z F , XU H B , et al . Reverse water-gas shift reaction over ceria nanocube synthesized by hydrothermal method [J ] . Catalysis Communications , 2016 , 76 : 1 - 6 .

SUN Q D , YE J Y , LIU C J , et al . In 2 O 3 as a promising catalyst for CO 2 utilization: A case study with reverse water gas shift over In 2 O 3 [J ] . Greenhouse Gases: Science and Technology , 2014 , 4 ( 1 ): 140 - 144 .

GHOUSSOUB M , YADAV S , GHUMAN K K , et al . Metadynamics-biased ab initio molecular dynamics study of heterogeneous CO 2 reduction via surface frustrated lewis pairs [J ] . ACS Catalysis , 2016 , 6 ( 10 ): 7109 - 7117 .

WANG J Y , LIU C Y , SENFTLE T P , et al . Variation in the In 2 O 3 crystal phase alters catalytic performance toward the reverse water gas shift reaction [J ] . ACS Catalysis , 2019 , 10 ( 5 ): 3264 - 3273 .

SILVA-CALPA L D R , ZONETTI P C , RODRIGUES C P , et al . The Zn x Zr 1- x O 2 -y solid solution on m-ZrO 2 : Creating O vacancies and improving the m -ZrO 2 redox properties [J ] . Journal of Molecular Catalysis A: Chemical , 2016 , 425 : 166 - 173 .

POSADA P S , VIÑES F , RODRIGUEZ J A , et al . Fundamentals of methanol synthesis on metal carbide based catalysts: Activation of CO 2 and H 2 [J ] . Topics in Catalysis , 2014 , 58 ( 2/3 ): 159 - 173 .

POSADA P S , VINES F , RAMIREZ P J , et al . The bending machine: CO 2 activation and hydrogenation on delta-MoC(001) and beta-Mo 2 C(001) surfaces [J ] . Physical Chemistry Chemical Physics , 2014 , 16 ( 28 ): 14912 - 14921 .

POROSOFF M D , KATTEL S , LI W , et al . Identifying trends and descriptors for selective CO 2 conversion to CO over transition metal carbides [J ] . Chemical Communications , 2015 , ( 32 ): 6988 - 6991 .

POROSOFF M D , YANG X , BOSCOBOINIK J A , et al . Molybdenum carbide as alternative catalysts to precious metals for highly selective reduction of CO 2 to CO [J ] . Angewandte Chemie International Edition , 2014 , 53 ( 26 ): 6705 - 6709 .

MA Y , GUO Z L , JIANG Q , et al . Molybdenum carbide clusters for thermal conversion of CO 2 to CO via reverse water-gas shift reaction [J ] . Journal of Energy Chemistry , 2020 , 50 : 37 - 43 .

ZHANG X , LIU Y , ZHANG M T , et al . Synergy between β -Mo 2 C nanorods and non-thermal plasma for selective CO 2 reduction to CO [J ] . Chem , 2020 , 6 ( 12 ): 3312 - 3328 .

PAJARES A , PRATS H , ROMERO A , et al . Critical effect of carbon vacancies on the reverse water gas shift reaction over vanadium carbide catalysts [J ] . Applied Catalysis B: Environmental , 2020 , 267 : 118719 .

ANJU R S , KUMAR P , NAIKWADI D R , et al . Beyond metals: Tailored metal-free boron-oxy-carbide catalysts for CO 2 hydrogenation [J ] . Applied Catalysis B: Environment and Energy , 2025 , 384 : 126153 .

XIN H , LIN L , LI R T , et al . Overturning CO 2 hydrogenation selectivity with high activity via reaction-induced strong metal-support interactions [J ] . Journal of the American Chemical Society , 2022 , 144 ( 11 ): 4874 - 4882 .

KANG H , ZHU L , LI S Y , et al . Generation of oxide surface patches promoting H-spillover in Ru/(TiO x )MnO catalysts enables CO 2 reduction to CO [J ] . Nature Catalysis , 2023 , 6 ( 11 ): 1062 - 1072 .

LI X Y , LIN J , LI L , et al ., Controlling CO 2 hydrogenation selectivity by metal-supported electron transfer [J ] . Angewandte Chemie International Edition 2020 , 59 ( 45 ): 19983 - 19989 .

BAO S D , YANG L Q , FU H Y , et al . Fine Ru-Ru 2 P heterostructure enables highly active and selective CO 2 hydrogenation to CO [J ] . ACS Catalysis , 2024 , 14 ( 23 ): 18134 - 18144 .

ZOU S B , LIANG Y H , ZHANG X M , et al . Manufacturing single-atom alloy catalysts for selective CO 2 hydrogenation via refinement of isolated-alloy-islands [J ] . Angewandte Chemie International Edition , 2025 , 64 ( 1 ): e202412835 .

LIU H X , LI J Y , QIN X T , et al . Pt n -O v synergistic sites on MoO x / γ -Mo 2 N heterostructure for low-temperature reverse water-gas shift reaction [J ] . Nature Communications , 2022 , 13 ( 1 ): 5800 .

CHEN X D , SU X , DUAN H M , et al . Catalytic performance of the Pt/TiO 2 catalysts in reverse water gas shift reaction: Controlled product selectivity and a mechanism study [J ] . Catalysis Today , 2017 , 281 : 312 - 318 .

LIANG B L , DUAN H M , SU X , et al . Promoting role of potassium in the reverse water gas shift reaction on Pt/mullite catalyst [J ] . Catalysis Today , 2017 , 281 : 319 - 326 .

DU P F , QI R , ZHANG Y F , et al . Single-atom-driven dynamic carburization over Pd 1 -FeO x catalyst boosting CO 2 conversion [J ] . Chem , 2022 , 8 ( 12 ): 3252 - 3262 .

YAO S Y , LIN L L , LIAO W J , et al . Exploring metal-support interactions to immobilize subnanometer Co clusters on γ -Mo 2 N: A highly selective and stable catalyst for CO 2 activation [J ] . ACS Catalysis , 2019 , 9 ( 10 ): 9087 - 9097 .

LI Y H , ZHAO Z A , LU W , et al . Single-atom Co-N-C catalysts for high-efficiency reverse water-gas shift reaction [J ] . Applied Catalysis B: Environmental , 2023 , 324 : 122298 .

LI S Y , LIU X , MA J , et al . Develop high-performance Cu-based RWGS catalysts by controlling oxide-oxide interface [J ] . ACS Catalysis , 2025 , 15 ( 4 ): 3475 - 3486 .

BAHMANPOUR A M , HÉROGUEL F , KILIÇ M , et al . Cu-Al spinel as a highly active and stable catalyst for the reverse water gas shift reaction [J ] . ACS Catalysis , 2019 , 9 ( 7 ): 6243 - 6251 .

LIU H X , LI S Q , WANG W W , et al . Partially sintered copper-ceria as excellent catalyst for the high-temperature reverse water gas shift reaction [J ] . Nature Communications , 2022 , 13 ( 1 ): 867 .

BELGAMWAR R , VERMA R , DAS T , et al . Defects tune the strong metal-support interactions in copper supported on defected titanium dioxide catalysts for CO 2 reduction [J ] . Journal of the American Chemical Society , 2023 , 145 ( 15 ): 8634 - 8646 .

ZHANG X , ZHU X B , LIN L L , et al . Highly dispersed copper over β -Mo 2 C as an efficient and stable catalyst for the reverse water gas shift (RWGS) reaction [J ] . ACS Catalysis 2017 , 7 ( 1 ): 912 - 918 .

ZHENG Z Y , SHANG X , WANG W J , et al . Boosting C—O bond cleavage and reverse water-gas shift activity via enriched in-plane sulfur vacancies in single-layer molybdenum disulfide [J ] . Angewandte Chemie International Edition , 2025 , 64 ( 17 ): e202422953 .

AHMADI K M , WANG X J , VITALE G , et al . An active, stable cubic molybdenum carbide catalyst for the high-temperature reverse water-gas shift reaction [J ] . Science , 2024 , 384 ( 6695 ): 540 - 546 .

DU X Z , LI R T , XIN H , et al . In-situ dynamic carburization of Mo oxide with unprecedented high CO formation rate in reverse water-gas shift reaction [J ] . Angewandte Chemie International Edition , 2024 , 63 ( 51 ): e202411761 .

ZHU J , WANG P , ZHANG X B , et al . Dynamic structural evolution of iron catalysts involving competitive oxidation and carburization during CO 2 hydrogenation [J ] . Science Advances , 2022 , 8 ( 5 ): eabm3629 .

WANG M R , WANG P , ZHANG G H , et al . Stabilizing Co 2 C with H 2 O and K promoter for CO 2 hydrogenation to C 2+ hydrocarbons [J ] . Science Advances , 2023 , 9 ( 24 ): eadg0167 .

LI W B , LIU B , GUO Q , et al . Reaction-indu ced regioselective reconstruction of Ni-doped Ce(OH) 3 /CeO 2 enables exceptional activity and selectivity for reverse water-shift reaction [J ] . Nature Communications , 2025 , 16 ( 1 ): 7335 .

LIU Y , MURTHY P R , ZHANG X , et al . Phase transformation of iron oxide to carbide and Fe 3 C as an active center for the RWGS reaction [J ] . New Journal of Chemistry , 2021 , 45 ( 47 ): 22444 - 22449 .

CHEN H M , ZHAO Z Y , WANG G Y , et al . Dynamic phase transition of iron oxycarbide facilitated by Pt nanoparticles for promoting the reverse water gas shift reaction [J ] . ACS Catalysis , 2021 , 11 ( 23 ): 14586 - 14595 .

ZHANG X B , HAN S B , ZHU B E , et al . Reversible loss of core-shell structure for Ni-Au bimetallic nanoparticles during CO 2 hydrogenation [J ] . Nature Catalysis , 2020 , 3 ( 4 ): 411 - 417 .

REDDY K P , KIM D , HONG S , et al . Tuning CO 2 hydrogenation selectivity through reaction-driven restructuring on Cu-Ni bimetal catalysts [J ] . ACS Applied Materials & Interfaces , 2023 , 15 ( 7 ): 9373 - 9381 .

NELSON N C , CHEN L , MEIRA D , et al . In situ dispersion of palladium on TiO 2 during reverse water-gas shift reaction: Formation of atomically dispersed palladium [J ] . Angewandte Chemie International Edition , 2020 , 59 ( 40 ): 17657 - 17663 .

LIU Y , ZHANG G H , LIU S D , et al . Promoting n -butane dehydrogenation over PtMn/SiO 2 through structural evolution induced by a reverse water-gas shift reaction [J ] . ACS Catalysis 2022 , 12 ( 21 ): 13506 - 13512 .

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