甲醇氧化羰基化用多孔炭负载纳米Cu催化剂研究进展

王佳君; 高新梅; 李婉君; 薛彦峰

doi:10.12434/j.issn.2097-2547.20250393

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甲醇氧化羰基化用多孔炭负载纳米Cu催化剂研究进展

更新时间：2026-03-23

- 甲醇氧化羰基化用多孔炭负载纳米Cu催化剂研究进展
- Research progress of nano-Cu catalysts supported on porous carbons for methanol oxidative carbonylation
- 低碳化学与化工 2026: 1-13.
- 作者机构：
  
  1.太原工业学院生物质绿色甲醇转化及氢能利用厅市共建山西省重点实验室培育基地，山西太原 030008
  2.太原工业学院化学与化工系，山西太原 030008
- 作者简介：
  
  王佳君（1992—），博士，讲师，研究方向为碳一化学与化工，E-mail：wangjiajun@tit.edu.cn。
- 基金信息：
  
  山西省基础研究计划（自由探索类）青年科学研究项目(202303021222302);山西省高等学校科技创新计划(2023L336)
- DOI：10.12434/j.issn.2097-2547.20250393
  中图分类号： TQ42
- 收稿：2025-10-10，
  
  修回：2025-11-26，
  
  网络首发：2026-03-13，
- 稿件说明：
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王佳君,高新梅,李婉君等.甲醇氧化羰基化用多孔炭负载纳米Cu催化剂研究进展[J].低碳化学与化工,

WANG Jiajun,GAO Xinmei,LI Wanjun,et al.Research progress of nano-Cu catalysts supported on porous carbons for methanol oxidative carbonylation[J].Low-Carbon Chemistry and Chemical Engineering,
王佳君,高新梅,李婉君等.甲醇氧化羰基化用多孔炭负载纳米Cu催化剂研究进展[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20250393.

WANG Jiajun,GAO Xinmei,LI Wanjun,et al.Research progress of nano-Cu catalysts supported on porous carbons for methanol oxidative carbonylation[J].Low-Carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20250393.

摘要

甲醇氧化羰基化合成碳酸二甲酯（DMC）是煤炭清洁高效利用的重要技术路线。基于多孔炭负载纳米Cu催化剂良好的催化性能，从多孔炭形貌及孔结构、缺陷结构和助剂等对催化性能的影响出发进行了综述，重点探讨了多孔炭纳米Cu催化剂高分散性、高纯度和缺电子性质与DMC高效合成之间的构效关系。目前，多孔炭纳米Cu催化剂仍面临若干关键挑战：在合成方面，难以有效克服Cu颗粒的本征团聚与氧化倾向；在结构调控方面，缺乏对Cu位点缺电子程度的定量界定与优化阈值。此外，现有研究在催化剂长效稳定性评估与反应机理深入解析方面仍存在明显不足。面向未来，多孔炭纳米Cu催化剂的发展应聚焦于精准调控，如通过前驱体工程与价态源头控制，实现活性位点的理性构建，结合电子结构描述符建立定量化构效关系；进一步借助反应气氛构建动态自稳定机制，并通过理论与实验的深度融合系统阐明真实反应路径，最终实现催化剂的高效稳定运行。

Abstract

The oxidative carbonylation of methanol to synthesize dimethyl carbonate (DMC) is an important technological route for the clean and efficient utilization of coal. Based on the excellent catalytic performance of nano-Cu catalysts supported on porous carbons

the effects of the morphologies and pore structures

defects and additives on the catalytic performance were reviewed. The structure-activity relationship between the high dispersion

high purity and electron-deficient property of nano-Cu catalysts and the efficient synthesis of DMC was mainly discussed. At present

the nano-Cu catalysts supported on porous carbons still face several key challenges: In terms of synthesis

it is difficult to effectively overcome the intrinsic agglomeration and oxidation tendency of Cu particles. In terms of structural regulation

there is a lack of quantitative definition and optimization threshold for the degree of electron deficiency of Cu sites. In addition

the existing research still has obvious deficiencies in the long-term stability assessment of catalysts and the in-depth analysis of reaction mechanisms. Looking to the future

the development of the nano-Cu catalysts supported on porous carbons should focus on precise regulation. For example

the rational construction of active sites can be achieved through precursor engineering and source control of valence states. And the quantitative structure-performance relationship can be established using electronic structure descriptors. Further

a dynamic self-stabilizing mechanism can be constructed in the reaction atmosphere

and the real reaction path should be systematically clarified through the deep integration of theory and experiment. Ultimately

the high efficiency and long-term stability of the catalysts can be achieved.

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references

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