二氧化碳加氢制甲醇铜基催化剂研究及工业化进展

吴子波; 李俊英; 郭继奎; 郑珩; 吴路平; 王雪峰; 胡志彪; 邓晋

doi:10.12434/j.issn.2097-2547.20250376

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二氧化碳加氢制甲醇铜基催化剂研究及工业化进展

更新时间：2026-04-17

- 二氧化碳加氢制甲醇铜基催化剂研究及工业化进展
- Research and industrialization progress of copper-based catalysts for CO₂ hydrogenation to methanol
- 低碳化学与化工 2026: 1-25.
- 作者机构：
  
  西南化工研究设计院有限公司多孔材料与分离转化全国重点实验室，国家碳一化学工程技术研究中心，四川成都 610225
- 作者简介：
  
  吴子波（1985—），硕士，高级工程师，研究方向为风电醇氨、CO2制甲醇和工业尾气高附加值利用（提氢、制醇、产LNG和合成氨）等碳一化工技术，E-mail：155338531@qq.com。
  李俊英（1998—），硕士，助理工程师，研究方向为碳一化工，E-mail：ljy13613404075@163.com。
- 基金信息：
  
  国家重点研发计划(2022YFA1504800)
- DOI：10.12434/j.issn.2097-2547.20250376
  中图分类号： TQ426
- 收稿：2025-10-07，
  
  修回：2025-11-23，
  
  网络首发：2026-04-17，
- 稿件说明：
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吴子波,李俊英,郭继奎等.二氧化碳加氢制甲醇铜基催化剂研究及工业化进展[J].低碳化学与化工,

WU Zibo,LI Junying,GUO Jikui,et al.Research and industrialization progress of copper-based catalysts for CO₂ hydrogenation to methanol[J].Low-Carbon Chemistry and Chemical Engineering,
吴子波,李俊英,郭继奎等.二氧化碳加氢制甲醇铜基催化剂研究及工业化进展[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20250376.

WU Zibo,LI Junying,GUO Jikui,et al.Research and industrialization progress of copper-based catalysts for CO₂ hydrogenation to methanol[J].Low-Carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20250376.

摘要

二氧化碳（CO

）加氢制甲醇技术可以实现对CO

的资源化利用，有望从根本上消除其对气候的不利影响。该技术与CO

捕集、风-光电制氢集成后，可以切实推动能源结构向低碳清洁能源方向转型。鉴于CO

稳定的化学性质，开发高效稳定的催化剂对于实现CO

加氢制甲醇技术的工业化突破至关重要。首先，通过对比CO

加氢制甲醇技术中不同催化剂的特点，明确了铜基催化剂良好的工业应用前景。然后，以反应机理、活性中心、载体和助剂为切入点，系统综述了国内外铜基催化剂的研究进展，并在此基础上总结了铜基催化剂催化性能的优化方向。最后，基于相关技术的中试及工业化进展，从工艺及技术经济性角度指出了铜基催化剂工业化过程中的技术瓶颈及其应对策略。铜基催化剂研究已进入机理指导下的催化剂设计阶段，尽管多数成果仍处于实验室阶段，但随着理论研究的深入、催化剂制备技术的发展，以及工业化手段的升级，在新的催化体系出现之前，铜基催化剂仍有望作为CO

加氢制甲醇技术实现大规模工业化所使用的主要催化剂。

Abstract

The catalytic hydrogenation of carbon dioxide (CO

) to methanol enables the resource utilization of CO

and has the potential to fundamentally eliminate its adverse impacts on the climate. When integrated with CO

capture technologies and wind- and solar-powered hydrogen production

this technology can effectively promote the transformation of the energy structure toward low-carbon and clean energy. Given the chemically stable nature of CO

the development of efficient and stable catalysts is crucial for achieving industrial breakthroughs in CO

hydrogenation to methanol. First

by comparing the characteristics of different catalysts used in CO

hydrogenation to methanol

the favorable prospects of copper-based catalysts for industrial application were clarified. Then

focusing on reaction mechanisms

active sites

supports and promoters

the research progress of copper-based catalysts reported both domestically and internationally was systematically reviewed

and on this basis

the directions for catalytic performance optimization of copper-based catalysts were summarized. Finally

based on the pilot-scale and industrialization progress of the related technologies

the technical bottlenecks encountered in the industrialization of copper-based catalysts and the corresponding countermeasures were identified from the perspectives of process

design and techno-economic analysis. Research on copper-based catalysts has entered a stage of mechanism-guided catalyst design. Although most studies are still at the laboratory scale

with the further advancement of theoretical research

the development of catalyst preparation technologies

and the upgrading of industrialization approaches

copper-based catalysts are still expected to serve as the primary catalysts for the large-scale industrialization of CO

hydrogenation to methanol before the emergence of new catalytic systems.

关键词

Keywords

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