重油浆态床加氢裂化催化剂及其原子尺度调控研究进展

孙广洵; 薛鹏; 田丰宇; 柳云骐; 潘原

doi:10.12434/j.issn.2097-2547.20250371

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重油浆态床加氢裂化催化剂及其原子尺度调控研究进展

更新时间：2026-03-06

- 重油浆态床加氢裂化催化剂及其原子尺度调控研究进展
- Research progress on heavy oil slurry phase hydrocracking catalysts and their atomic-scale regulation
- 低碳化学与化工 2026: 1-11.
- 作者机构：
  
  1.中国石油大学（华东）重质油全国重点实验室，山东青岛 266580
  2.安徽师范大学化学与材料科学学院，安徽芜湖 241002
- 作者简介：
  
  孙广洵（1997—），博士研究生，研究方向为重油浆态床加氢，E-mail：gxsun0124@163.com。
  柳云骐（1963—），博士，教授，研究方向为石油化工，E-mail：liuyq@upc.edu.cn；
  潘原（1989—），博士，教授，研究方向为工业催化，E-mail：panyuan@upc.edu.cn。
- 基金信息：
  
  国家自然科学基金(22478432;22522819);山东省自然科学基金(ZR2024JQ004);泰山学者科研项目(tstp20250527)
- DOI：10.12434/j.issn.2097-2547.20250371
  中图分类号： TK91
- 收稿：2025-09-16，
  
  修回：2025-10-28，
  
  网络首发：2026-03-04，
- 稿件说明：
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孙广洵,薛鹏,田丰宇等.重油浆态床加氢裂化催化剂及其原子尺度调控研究进展[J].低碳化学与化工,

SUN Guangxun,XUE Peng,TIAN Fengyu,et al.Research progress on heavy oil slurry phase hydrocracking catalysts and their atomic-scale regulation[J].Low-Carbon Chemistry and Chemical Engineering,
孙广洵,薛鹏,田丰宇等.重油浆态床加氢裂化催化剂及其原子尺度调控研究进展[J].低碳化学与化工, DOI：10.12434/j.issn.2097-2547.20250371.

SUN Guangxun,XUE Peng,TIAN Fengyu,et al.Research progress on heavy oil slurry phase hydrocracking catalysts and their atomic-scale regulation[J].Low-Carbon Chemistry and Chemical Engineering, DOI：10.12434/j.issn.2097-2547.20250371.

摘要

浆态床加氢裂化催化剂的设计和开发是重油高效转化的关键。传统过渡金属硫化物催化剂在加氢反应过程中易团聚，导致金属原子利用率低和加氢性能下降。单原子催化剂具有最大的金属原子利用率和可调的活性中心结构，表现出优异的加氢性能，为重油浆态床加氢裂化催化剂设计提供了新思路。综述了近年来重油浆态床加氢裂化催化剂的研究进展，重点介绍了纳米催化剂和单原子催化剂的结构特性与催化性能差异，进而从原子尺度提出了配位结构调控、双原子位点协同调控和单原子-硫化物耦合调控的浆态床加氢裂化催化剂的设计策略，并对单原子催化剂在重油浆态床加氢裂化反应体系中存在的问题与挑战进行了展望。

Abstract

The design and development of slurry phase hydrocracking catalysts are key to the efficient conversion of heavy oil. Traditional transition metal sulfide catalysts are prone to agglomerate during hydrogenation reactions

resulting in low metal atom utilization rate and decreased hydrogenation performance. Single-atom catalysts have the highest metal atom utilization rate and adjustable active center structure

which show excellent hydrogenation performance

providing new ideas for the design of heavy oil slurry phase hydrocracking catalysts. Research progress on heavy oil slurry phase hydrocracking catalysts in recent years was reviewed

with particular emphasis on the structural characteristics and catalytic performance differences between nano-scale catalysts and single-atom catalysts. At the atomic scale

design strategies for heavy oil hydrocracking catalysts were then proposed

including coordination structure regulation

dual-atom site cooperative regulation

and single-atom-sulfide coupling regulation. In addition

the issues and challenges of single-atom catalysts in heavy oil slurry phase hydrocracking were prospected.

关键词

Keywords

references

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