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上海交通大学 环境科学与工程学院,上海 200240
刘越(2004—),本科生,研究方向为化学工程与工艺,E-mail:knoxsasvile@sjtu.edu.cn。
钱旭芳(1983—),博士,研究员,研究方向为环境生态、污染控制和环境光(电)催化等,E-mail:qianxufang@sjtu.edu.cn。
收稿:2025-09-11,
修回:2025-10-14,
网络首发:2026-03-05,
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刘越,唐绍山,陈甜等.煤制乙二醇主要工艺单元催化剂研究进展[J].低碳化学与化工,
LIU Yue,TANG Shaoshan,CHEN Tian,et al.Research progress on catalysts for key process units in coal-to-ethylene glycol[J].Low-Carbon Chemistry and Chemical Engineering,
刘越,唐绍山,陈甜等.煤制乙二醇主要工艺单元催化剂研究进展[J].低碳化学与化工, DOI:10.12434/j.issn.2097-2547.20250368.
LIU Yue,TANG Shaoshan,CHEN Tian,et al.Research progress on catalysts for key process units in coal-to-ethylene glycol[J].Low-Carbon Chemistry and Chemical Engineering, DOI:10.12434/j.issn.2097-2547.20250368.
煤制乙二醇技术对保障我国乙二醇供应链安全及推动煤基化学品高质量发展具有重要战略意义。由于煤制乙二醇路线工业化时间较短,目前对其以催化剂为核心的工艺单元的发展趋势还缺乏系统认识,这制约了煤制乙二醇及其下游产业链的进一步拓展。根据煤制乙二醇系统各个单元相互关联的特点,综述了CO原料气净化、草酸二甲酯合成与加氢转化、乙二醇产品精制以及含硝酸废液高效回收等关键单元的催化剂研究进展,并对煤制乙二醇主要工艺单元催化剂的未来发展进行了展望。
Coal-to-ethylene glycol technology holds significant strategic importance for ensuring the security of China’s ethylene glycol supply chain and promoting the high-quality development of coal-based chemicals. Due to the relatively short industrialization history of coal-to-ethylene glycol route
there remains a lack of systematic understanding of the development trends of its catalyst-centered process units
which limits the further expansion of the coal-to-ethylene glycol industry and its downstream value chains. Based on the interconnected characteristics of the various units within the coal-to-ethylene glycol system
research progress on catalysts for key units was reviewed
including CO feed gas purification
dimethyl oxalate synthesis and hydrogenation
ethylene glycol product purification and efficient recovery of nitric acid-containing wastewater. And the future development of catalysts for key units in coal-to-ethylene glycol was prospected.
中国石化有机原料科技情报中心站 . 未来乙二醇市场将面临压力 [J ] . 石油化工技术与经济 , 2024 , 40 ( 5 ): 40 .
SINOPEC Organic Raw Materials Science and Technology Information Center Station . The ethylene glycol market will face pressure in the future [J ] . Technology & Economics in Petrochemicals , 2024 , 40 ( 5 ): 40 .
蔡丽娟 . 乙二醇生产技术的发展及比较分析 [J ] . 煤化工 , 2013 , 41 ( 5 ): 59 - 62 .
CAI L J . Development of the glycol production technology and comparison between different glycol production processes [J ] . Coal Chimical Industry , 2013 , 41 ( 5 ): 59 - 62 .
刘宗语 . 环氧乙烷/乙二醇生产技术进展 [J ] . 化工进展 , 2013 , 32 ( 6 ): 1214 - 1218 .
LIU Z Y . Advances in ethylene oxide and ethylene glycol technology [J ] . Chemical Industry and Engineering Progress , 2013 , 32 ( 6 ): 1214 - 1218 .
罗漫 , 阎建民 , 李学刚 , 等 . 煤制乙二醇主要工艺单元技术新进展 [J ] . 煤化工 , 2023 , 51 ( 2 ): 1 - 6 .
LUO M , YAN J M , LI X G , et al . Latest technological progresses of main process unit in coal to ethylene glycol [J ] . Coal Chimical Industry , 2023 , 51 ( 2 ): 1 - 6 .
陈艳 , 王永全 , 姚永邦 , 等 . 煤制乙二醇工艺技术及其生产装置运行分析 [J ] . 煤化工 , 2023 , 51 ( 1 ): 89 - 92 .
CHEN Y , WANG Y Q , YAO Y B , et al . Analysis on coal to ethylene glycol technology and operation of its production unit [J ] . Coal Chimical Industry , 2023 , 51 ( 1 ): 89 - 92 .
杨芊 , 魏江波 , 孙齐 , 等 . 煤制乙二醇废水处理关键技术研究进展 [J ] . 洁净煤技术 , 2022 , 28 ( 4 ): 86 - 93 .
YANG Q , WEI J B , SUN Q , et al . Key technologies for treatment of wastewater from coal-to-ethylene glycol [J ] . Clean Coal Technology , 2022 , 28 ( 4 ): 86 - 93 .
SONG H Y , JIN R H , KANG M R , et al . Progress in synthesis of ethylene glycol through C1 chemical industry routes [J ] . Chinese Journal of Catalysis , 2013 , 34 ( 6 ): 1035 - 1050 .
李代红 , 王洪波 . 合成气制乙二醇市场及技术进展 [J ] . 现代化工 , 2017 , 37 ( 1 ): 5 - 8+10 .
LI D H , WANG H B . Market and technology progress of syngas to ethylene glycol [J ] . Modern Chemical Industry , 2017 , 37 ( 1 ): 5 - 8+10 .
陈庆龄 , 杨为民 , 滕加伟 . 中国石化煤化工技术最新进展 [J ] . 催化学报 , 2013 , 34 ( 1 ): 217 - 224 .
CHEN Q L , YANG W M , TENG J W . Recent advances in coal to chemicals technology developed by SINOPEC [J ] . Chinese Journal of Catalysis , 2013 , 34 ( 1 ): 217 - 224 .
冯翀 , 俞金山 , 刘甜甜 , 等 . 基于限域效应的铜基草酸二甲酯加氢催化剂研究进展 [J ] . 天然气化工—C1化学与化工 , 2020 , 45 ( 3 ): 96 - 101 .
FENG C , YU J S , LIU T T , et al . Research progress in confinement Cu-based catalysts for hydrogenation of dimethyl oxalate to ethylene glycol [J ] . Natural Gas Chemical Industry , 2020 , 45 ( 3 ): 96 - 101 .
谷豹 , 刘刚 , 尹科科 , 等 . 草酸二甲酯的合成及应用研究进展 [J ] . 应用化工 , 2023 , 52 ( 4 ): 1248 - 1252 .
GU B , LIU G , YIN K K , et al . Advances in synthesis and application of dimethyl oxalate [J ] . Applied Chemical Industry , 2023 , 52 ( 4 ): 1248 - 1252 .
WANG C Z , LI X C , YUAN S C , et al . Oxidative coupling of carbon monoxide to dimethyl oxalate: Catalysts design, reaction mechanism and process intensification [J ] . Catalysis Reviews , 2025 , 67 ( 2 ): 323 - 370 .
吴彦丽 , 李文英 , 易群 , 等 . 中美洁净煤转化技术现状及发展趋势 [J ] . 中国工程科学 , 2015 , 17 ( 9 ): 133 - 139 .
WU Y L , LI W Y , YI Q , et al . Current status and development strategy on clean coal conversion technology in China and the United States of America [J ] . Strategic Study of CAE , 2015 , 17 ( 9 ): 133 - 139 .
孙国辉 , 许叶飞 . 煤制乙二醇生产技术现状及产业化进展 [J ] . 石化技术 , 2015 , 22 ( 10 ): 45 .
SUN G H , XU Y F . Present status and industrial development of coal to ethylene glycol [J ] . Petrochemical Industry Technology , 2015 , 22 ( 10 ): 45 .
YUE H R , ZHAO Y J , MA X B , et al . Ethylene glycol: Properties, synthesis, and applications [J ] . Chemical Society Reviews , 2012 , 41 ( 11 ): 4218 - 4244 .
戴珂琦 , 罗漫 , 肖文德 . H 2 对CO偶联制备草酸二甲酯反应影响的研究 [J ] . 天然气化工—C1化学与化工 , 2012 , 37 ( 3 ): 1 - 4 .
DAI K Q , LUO M , XIAO W D . Effect of H 2 on coupling of CO with methyl nitrite to dimethyl oxalate [J ] . Natural Gas Chemical Industry , 2012 , 37 ( 3 ): 1 - 4 .
OUYANG L K , TIAN P F , DA G J , et al . The origin of active sites for direct synthesis of H 2 O 2 on Pd/TiO 2 catalysts: Interfaces of Pd and PdO domains [J ] . Journal of Catalysis , 2015 , 321 : 70 - 80 .
QIAO L Y , LI Q H , ZHOU Z F , et al . Inert can be advantageous: Advisable reconstruction and application of palladium chloride for the preferential oxidation of the hydrogen impurity in carbon monoxide streams [J ] . ChemCatChem , 2016 , 8 ( 11 ): 1909 - 1914 .
周张锋 , 李兆基 , 潘鹏斌 , 等 . 煤制乙二醇技术进展 [J ] . 化工进展 , 2010 , 29 ( 11 ): 2003 - 2009 .
ZHOU Z F , LI Z J , PAN P B , et al . Progress in technologies of coal-based ethylene glycol synthesis [J ] . Chemical Industry and Engineering Progress , 2010 , 29 ( 11 ): 2003 - 2009 .
姚元根 , 周张锋 , 乔路阳 , 等 . 一种CO脱氢流化床反应用催化剂及其制备方法和应用 : 104667912A [P ] . 2014-07-10 .
YAO Y G , ZHOU Z F , QIAO L Y , et al . A catalyst for CO dehydrogenation fluidized bed reaction , its preparation method , and application: 104667912A [P ] . 2014-07-10 .
姚元根 , 崔国静 , 周张锋 , 等 . 一种CO原料气净化脱氢用催化剂及其制备方法 : 105080538B [P ] . 2018-07-20 .
YAO Y G , CUI G J , ZHOU Z F , et al . A catalyst for CO feed gas purification and dehydrogenation and its preparation method : 105080538B [P ] . 2018-07-20 .
姚元根 , 乔路阳 , 周张锋 , 等 . 一种CO脱氢净化用Pd‑Cl/CeOCl催化剂及制备方法 : 107308962B [P ] . 2019-03-08 .
YAO Y G , QIAO L Y , ZHOU Z F , et al . A Pd-Cl/CeOCl catalyst for CO dehydrogenation purification and its preparation method : 107308962B [P ] . 2019-03-08 .
徐卫 , 吴熠 , 杜霞茹 , 等 . 高浓度CO原料气脱H 2 催化剂H-846D的开发及研究 [J ] . 工业催化 , 2014 , 22 ( 2 ): 144 - 147 .
XU W , WU Y , DU X R , et al . Development of H-846D catalyst for selective oxidation of H 2 in CO-rich stream [J ] . Industrial Catalysis , 2014 , 22 ( 2 ): 144 - 147 .
姚元根 , 乔路阳 , 周张锋 , 等 . 一种CO氧化脱氢用非贵金属催化剂及其制备方法 : 105080537A [P ] . 2015-11-25 .
YAO Y G , QIAO L Y , ZHOU Z F , et al . A non-precious metal catalyst for CO oxidative dehydrogenation and its preparation method : 105080537A [P ] . 2015-11-25 .
姚元根 , 乔路阳 , 周张锋 , 等 . 一种CO脱氢净化用Mn基非贵金属催化剂及其制备方法 : 109046398B [P ] . 2021-02-19 .
YAO Y G , QIAO L Y , ZHOU Z F , et al . A Mn-based non-precious metal catalyst for CO dehydrogenation purification and its preparation method : 109046398B [P ] . 2021-02-19 .
黄开辉 , 万惠霖 . 催化原理 [M ] . 北京 : 科学出版社 , 1983 .
HUANG K H , WAN H L . Catalysis mechanism [M ] . Beijing : Science Press , 1983 .
JI Y , LIU G , LI W , et al . The mechanism of CO coupling reaction to form dimethyl oxalate over Pd/ α -Al 2 O 3 [J ] . Journal of Molecular Catalysis A: Chemical , 2009 , 314 ( 1 ): 63 - 70 .
林茜 , 计扬 , 谭俊青 , 等 . Pd/α-Al 2 O 3 催化CO偶联制草酸二甲酯的反应机理 [J ] . 催化学报 , 2008 , ( 4 ): 325 - 329 .
LIN Q , JI Y , TAN J Q , et al . Mechanism of CO coupling to dimethyl oxalate over Pd/ α -Al 2 O 3 [J ] . Chinese Journal of Catalysis , 2008 , ( 4 ): 325 - 329 .
LI Q H , ZHOU Z F , CHEN R P , et al . Insights into the reaction mechanism of CO oxidative coupling to dimethyl oxalate over palladium: A combined DFT and IR study [J ] . Physical Chemistry Chemical Physics , 2015 , 17 ( 14 ): 9126 - 9134 .
WANG C Z , CHEN P J , LI Y K , et al . In situ DRIFTS study of CO coupling to dimethyl oxalate over structured Al-fiber@ns-AlOOH@Pd catalyst [J ] . Journal of Catalysis , 2016 , 344 : 173 - 183 .
XU Z N , SUN J , LIN C S , et al . High-performance and long-lived Pd nanocatalyst directed by shape effect for CO oxidative coupling to dimethyl oxalate [J ] . ACS Catalysis , 2013 , 3 ( 2 ): 118 - 122 .
PENG S Y , XU Z N , CHEN Q S , et al . An ultra-low Pd loading nanocatalyst with high activity and stability for CO oxidative coupling to dimethyl oxalate [J ] . Chemical Communications , 2013 , 49 ( 51 ): 5718 - 5720 .
ZHAO T J , CHEN D , DAI Y C , et al . Synthesis of dimethyl oxalate from CO and CH 3 ONO on carbon nanofiber supported palladium catalysts [J ] . Industrial & Engineering Chemistry Research , 2004 , 43 ( 16 ): 4595 - 4601 .
PENG S Y , XU Z N , CHEN Q S , et al . Enhanced stability of Pd/ZnO catalyst for CO oxidative coupling to dimethyl oxalate: Effect of Mg 2+ doping [J ] . ACS Catalysis , 2015 , 5 ( 7 ): 4410 - 4417 .
高正虹 , 胡超权 , 李振花 , 等 . 一氧化碳偶联制草酸二乙酯用Pd-Fe/ α -Al 2 O 3 催化剂的表面结构 [J ] . 催化学报 , 2004 , ( 3 ): 205 - 209 .
GAO Z H , HU C Q , LI Z H , et al . Surface structure of Pd-Fe/ α -Al 2 O 3 catalyst for CO coupling to diethyl oxalate [J ] . Chinese Journal of Catalysis , 2004 , ( 3 ): 205 - 209 .
赵秀阁 , 吕兴龙 , 赵红钢 , 等 . 气相法CO与亚硝酸甲酯偶联合成草酸二甲酯用Pd/ α -Al 2 O 3 催化剂的研究 [J ] . 催化学报 , 2004 , ( 2 ): 125 - 128 .
ZHAO X G , LU X L , ZHAO H G , et al . Study on Pd/ α -Al 2 O 3 catalyst for vapor-phase coupling reaction of CO with CH 3 ONO to (CH 3 OOC) 2 [J ] . Chinese Journal of Catalysis , 2004 , ( 2 ): 125 - 128 .
穆仕芳 , 张鲁湘 , 宋军超 , 等 . CO气相偶联合成草酸二甲酯Pd/ α -Al 2 O 3 催化剂失活与再利用 [J ] . 工业催化 , 2019 , 27 ( 1 ): 1 - 5 .
MU S F , ZHANG L X , SONG J C , et al . Deactivation and recovery of Pd/ α -Al 2 O 3 catalyst for gas-phase CO coupling t o dimethyl oxalate [J ] . Industrial Catalysis , 2019 , 27 ( 1 ): 1 - 5 .
WANG C Z , HAN L P , CHEN P J , et al . High-performance, low Pd-loading microfibrous-structured Al-fiber@ns-AlOOH@Pd catalyst for CO coupling to dimethyl oxalate [J ] . Journal of Catalysis , 2016 , 337 : 145 - 156 .
ZHAO G F , LIU Y , LU Y . Foam/fiber-structured catalysts: Non-dip-coating fabrication strategy and applications in heterogeneous catalysis [J ] . Science Bulletin , 2016 , 61 ( 10 ): 745 - 748 .
PARRA-CABRERA C , ACHILLE C , KUHN S , et al . 3D printing in chemical engineering and catalytic technology: Structured catalysts, mixers and reactors [J ] . Chemical Society Reviews , 2018 , 47 ( 1 ): 209 - 230 .
YE R P , LIN L , WANG L C , et al . Perspectives on the active sites and catalyst design for the hydrogenation of dimethyl oxalate [J ] . ACS Catalysis , 2020 , 10 ( 8 ): 4465 - 4490 .
陈红梅 , 朱玉雷 , 郑洪岩 , 等 . Cu基催化剂上草酸二甲酯催化加氢合成乙二醇的研究 [J ] . 天然气化工—C1化学与化工 , 2010 , 35 ( 3 ): 1 - 6 .
CHEN H M , ZHU Y L , ZHENG H Y , et al . Study on hydrogenation of dimethyl oxalate to ethylene glycol over Cu-based catalysts [J ] . Natural Gas Chemical Industry , 2010 , 35 ( 3 ): 1 - 6 .
KAWABE K , MURATA K , FURUYA T . Ethylene glycol process : US 5763691 [P ] . 1998-06-09 .
CHEN L F , GUO P J , QIAO M H , et al . Cu/SiO 2 catalysts prepared by the ammonia-evaporation method: Texture, structure, and catalytic performance in hydrogenation of dimethyl oxalate to ethylene glycol [J ] . Journal of Catalysis , 2008 , 257 ( 1 ): 172 - 180 .
陈冲冲 , 委娇娇 , 杨红兵 , 等 . 草酸二甲酯高效低温加氢催化剂研究进展 [J ] . 石油学报(石油加工) , 2024 , 40 ( 5 ): 1223 - 1232 .
CHEN C C , WEI J J , YANG H B , et al . Advances in research of high-efficiency catalysts for low temperature hydrogenation of dimethyl oxalate [J ] . Acta Petrolei Sinica (Petroleump Rocessing Section) , 2024 , 40 ( 5 ): 1223 - 1232 .
HUI S G , ZHANG B , ZHANG S H , et al . In situ IR study of dimethyl oxalate hydrogenation to ethylene glycol over Cu/SiO 2 catalyst [J ] . Journal of Natural Gas Chemistry , 2012 , 21 ( 6 ): 753 - 758 .
GONG J L , YUE H R , ZHAO Y J , et al . Synthesis of ethanol via syngas on Cu/SiO 2 catalysts with balanced Cu 0 -Cu + sites [J ] . Journal of the American Chemical Society , 2012 , 134 ( 34 ): 13922 - 13925 .
WANG Y , SHEN Y L , ZHAO Y J , et al . Insight into the balancing effect of active Cu species for hydrogenation of carbon—oxygen bonds [J ] . ACS Catalysis , 2015 , 5 ( 10 ): 6200 - 6208 .
YUE H R , MA X B , GONG J L . An alternative synthetic approach for efficient catalytic conversion of syngas to ethanol [J ] . Accounts of Chemical Research , 2014 , 47 ( 5 ): 1483 - 1492 .
CUI G Q , MENG X Y , ZHANG X , et al . Low-temperature hydrogenation of dimethyl oxalate to ethylene glycol via ternary synergistic catalysis of Cu and acid-base sites [J ] . Applied Catalysis B: Environmental , 2019 , 248 : 394 - 404 .
尹安远 , 郭晓洋 , 戴维林 , 等 . 介孔氧化硅织构效应对Cu基催化剂在草酸二甲酯催化加氢合成乙二醇反应中的影响 [J ] . 化学学报 , 2010 , 68 ( 13 ): 1285 - 1290 .
YIN A Y , GUO X Y , DAI W L , et al . Textural structure effect of SiO 2 on the catalytic performance for hydrogenation of dimethyl oxalate to ethylene glycol over different Cu-based catalysts [J ] . Acta Chimica Sinica , 2010 , 68 ( 13 ): 1285 - 1290 .
毛金平 . 煤制乙二醇加氢催化剂稳定运行研究 [J ] . 安徽化工 , 2020 , 46 ( 4 ): 74 - 76 .
MAO J P . Study on the stable operation of coal to glycol hydrogenation catalyst [J ] . Anhui Chemical Industry , 2020 , 46 ( 4 ): 74 - 76 .
ZHENG J , HUANG L , CUI C H , et al . Ambient-pressure synthesis of ethylene glycol catalyzed by C 60 -buffered Cu/SiO 2 [J ] . Science , 2022 , 376 ( 6596 ): 288 - 292 .
YAO D W , WANG Y , LI Y , et al . A high-performance nanoreactor for carbon—oxygen bonds hydrogenation reactions achieved by the morphology of nanotube-assembled hollow sphere [J ] . ACS Catalysis , 2018 , 8 ( 2 ): 1218 - 1226 .
赵鹬 , 王世栋 , 贠宏飞 , 等 . 草酸二甲酯加氢反应中铜催化剂稳定性的研究进展 [J ] . 化工进展 , 2018 , 37 ( 9 ): 3393 - 3400 .
ZHAO Y , WANG S D , YUN H F , et al . Recent progress on the stabilization of copper catalysts for the hydrogenation of dimethyl oxalate [J ] . Chemical Industry and Engineering Progress , 2018 , 37 ( 9 ): 3393 - 3400 .
LIU L J , LU J Y , YANG Y H , et al . Dealuminated beta zeolite reverses Ostwald ripening for durable copper nanoparticle catalysts [J ] . Science , 2024 , 383 ( 6678 ): 94 - 101 .
孔祥鹏 , 游新明 , 元培红 , 等 . 助剂对于Cu/ZnO催化剂结构特征及催化草酸二甲酯加氢合成乙二醇反应性能的影响 [J ] . 燃料化学学报(中英文) , 2023 , 51 ( 6 ): 794 - 803 .
KONG X P , YOU X M , YUAN P H , et al . Influence of dopants on the structure and catalytic features of the Cu/ZnO catalyst for dimethyl oxalate hydrogenation to ethylene glycol [J ] . Journal of Fuel Chemistry and Technology , 2023 , 51 ( 6 ): 794 - 803 .
YUN H F , ZHAO Y , KAN X , et al . Effect of surface hydroxyl content of support on the activity of Cu/ZSM-5 catalyst for low-temperature hydrogenation of dimethyl oxalate to ethylene glycol [J ] . Catalysis Letters , 2023 , 153 ( 2 ): 364 - 377 .
赵丽娜 , 张慧丹 , 赵金仙 , 等 . Zr助剂含量对Cu/SiO 2 纳米管催化草酸二甲酯加 氢制乙二醇反应性能的影响 [J ] . 低碳化学与化工 , 2025 , 50 ( 2 ): 61 - 68 .
ZHAO L N , ZHANG H D , ZHAO J X , et al . Effects of Zr additive contents on catalytic performances of Cu/SiO 2 nanotubecatalysts for dimethyl oxalate hydrogenation to ethylene glycol [J ] . Low-Carbon Chemistry and Chemical Engineering , 2025 , 50 ( 2 ): 61 - 68 .
陈群 , 许平 , 崔爱军 . 煤基聚乙醇酸技术进展 [J ] . 化工进展 , 2011 , 30 ( 1 ): 172 - 180 .
CHEN Q , XU P , CUI A J . Technology progress of polyarglycolic acid on coal based [J ] . Chemical Industry and Engineering Progress , 2011 , 30 ( 1 ): 172 - 180 .
黄谢君 , 刘俊涛 . Cs 2 CO 3 催化草酸二甲酯脱羰基合成碳酸二甲酯 [J ] . 工业催化 , 2021 , 29 ( 12 ): 71 - 74 .
HUANG X J , LIU J T . Synthesis of dimethyl carbonate by decarbonylation of dimethyl oxalate over Cs 2 CO 3 catalyst [J ] . Industrial Catalysis , 2021 , 29 ( 12 ): 71 - 74 .
马新宾 , 王悦 , 杨有为 , 等 . 一种用于酯加氢的碳氮掺杂的介孔氧化硅负载的Cu基催化剂及其制备方法与使用方法 : 118106009A [P ] . 2024-05-31 .
MA X B , WANG Y , YANG Y W , et al . A copper-based catalyst supported on carbon-nitrogen-doped mesoporous silica for ester hydrogenation and its preparation method and use method : 118106009A [P ] . 2024-05-31 .
毛顺聪 , 吉本亮介 , 郝新宇 , 等 . 铟-铜双金属/SiO-ZrO催化剂及其制备方法和使用该催化剂制备乙二醇的方法 : 118663266A [P ] . 2024-09-20 .
MAO S C , YOSHIMOTO R , HAO X Y , et al . Indium-copper bimetal/SiO-ZrO catalyst and its preparation method and method for preparing ethylene glycol using the catalyst : 118663266A [P ] . 2024-09-20 .
李小虎 , 熊宇聪 , 马晓云 , 等 . 一种草酸二甲酯加氢制备乙二醇的催化剂及其制备方法与应用 : 115709065B [P ] . 2024-06-07 .
LI X H , XIONG Y C , MA X Y , et al . A catalyst for preparing ethylene glycol by dimethyl oxalate hydrogenation and its preparation method and application : 115709065B [P ] . 2024-06-07 .
王庆吉 , 王蕊 , 李进 , 等 . 一种草酸二甲酯加氢催化剂及其制备方法和应用 : 114054024B [P ] . 2024-06-11 .
WANG J Q , WANG R , LI J , et al . A dimethyl oxalate hydrogenation catalyst and its preparation method and application : 114054024B [P ] . 2024-06-11 .
姚元根 , 杨锦霞 , 林凌 , 等 . 一种草酸酯加氢制乙二醇用Cu基催化剂及其制备方法 : 112588290B [P ] . 2021-12-14 .
YAO Y G , YANG J X , LIN L , et al . A copper-based catalyst for ethylene glycol production by oxalate ester hydrogenation and its preparation method : 112588290B [P ] . 2021-12-14 .
钟源 , 龚海燕 , 张旭 . 草酸酯加氢制乙二醇用催化剂及其制备方法和应用以及制备乙二醇的方法 : 112642469B [P ] . 2023-06-06 .
ZHONG Y , GONG H Y , ZHANG X . A catalyst for ethylene glycol production by oxalate ester hydrogenation and its preparation method and application as well as method for preparing ethylene glycol : 112642469B [P ] . 2023-06-06 .
周佳 , 夏锐 , 王伟 , 等 . 一种草酸二甲酯气相加氢合成乙二醇的催化剂及其制备方法 : 108722408B [P ] . 2021-06-04 .
ZHOU J , XIA Y , WANG W , et al . A catalyst for synthesis of ethylene glycol by vapor-phase hydrogenation of dimethyl oxalate and its preparation method : 108722408B [P ] . 2021-06-04 .
戴维林 , 崔园园 , 温超 . 由草酸二甲酯加氢制乙二醇及乙二醇单甲醚的Cu基催化剂及其制备方法 : 103566949B [P ] . 2015-12-12 .
DAI W L , CUI Y Y , WEN C . A copper-based catalyst for preparing ethylene glycol and ethylene glycol monomethyl ether by dimethyl oxalate hydrogenation and its preparation method : 103566949B [P ] . 2015-12-12 .
王瑞璞 , 曾佳 , 谢伦嘉 , 等 . 一种草酸酯加氢制乙二醇的催化剂及其制备方法 : 104248952B [P ] . 2017-02-15 .
WANG R P , ZENG J , XIE L J , et al . A catalyst for ethylene glycol production by oxalate ester hydrogenation and its preparation method : 104248952B [P ] . 2017-02-15 .
张博 , 计扬 , 骆念军 , 等 . 草酸烷基酯加氢合成乙二醇用复合载体催化剂及制备方法 : 102225338B [P ] . 2013-04-24 .
ZHANG B , JI Y , LUO N J , et al . A composite carrier catalyst for ethylene glycol synthesis by alkyl oxalate ester hydrogenation and its preparation method : 102225338B [P ] . 2013-04-24 .
高翔 , 任鹏 , 韩濛 . 乙二醇生产和精制技术研究进展 [J ] . 聚酯工业 , 2024 , 37 ( 5 ): 64 - 66 .
GAO X , REN P , HAN M . Research progress on production and refining technology of ethylene glycol [J ] . Polyester Industry , 2024 , 37 ( 5 ): 64 - 66 .
贾未鸣 , 张会成 , 吕清林 , 等 . 煤基乙二醇中痕量杂质对UV值的影响 [J ] . 石油化工 , 2021 , 50 ( 6 ): 541 - 546 .
JIA W M , ZHANG H C , LV Q L , et al . Influence of trace impurities in coal-based ethylene glycol on UV light transmittance [J ] . Petrochemical Technology , 2021 , 50 ( 6 ): 541 - 546 .
孔会娜 , 郑卫 . 液相加氢提高聚酯级煤制乙二醇产率的工业化应用 [J ] . 现代化工 , 2020 , 40 ( 8 ): 200 - 204 .
KONG H N , ZHENG W . Industrial application of liquid phase hydrogenation technology to improve yield of coal-based polyester grade ethylene glycol [J ] . Modern Chemical Industry , 2020 , 40 ( 8 ): 200 - 204 .
林晓霞 , 刘景刚 , 王建平 . 乙二醇产品塔全回流和侧采产品液相加氢的工业化应用 [J ] . 现代化工 , 2025 , 45 ( 2 ): 243 - 248+254 .
LIN X X , LIU J G , WANG J P . Industrial application of liquid-phase hydrogenation for total reflux and side withdrawal in ethylene glycol product tower [J ] . Modern Chemical Industry , 2025 , 45 ( 2 ): 243 - 248+254 .
龚海燕 , 王誉蓉 , 刘俊涛 . Pd催化剂上乙二醇加氢提高紫外透光率的研究 [J ] . 工业催化 , 2021 , 29 ( 4 ): 73 - 76 .
GONG H Y , WANG Y R , LIU J T . Upgrading the ultraviolet transmittance of monoethylene glycol on Pd-based catalyst [J ] . Industrial Catalysis , 2021 , 29 ( 4 ): 73 - 76 .
吕清林 , 李澜鹏 , 贾未鸣 , 等 . 煤基乙二醇加氢精制技术探究 [J ] . 石油化工 , 2024 , 53 ( 2 ): 182 - 187 .
LV Q L , LI L P , JIA W M , et al . Study on coal-based ethylene glycol hydrofining technology [J ] . Petrochemical Technology , 2024 , 53 ( 2 ): 182 - 187 .
钱俊峰 , 季伟 , 孙中华 , 等 . 镍系加氢催化剂及其制备方法和应用 : 113952957A [P ] . 2022-01-21 .
QIAN J F , JI W , SUN Z H , et al . A nickel-based hydrogenation catalyst and its preparation method and application : 113952957A [P ] . 2022-01-21 .
杨鹏举 , 王士钦 , 包世龙 . 脱酯脱醛工艺在煤制乙二醇装置中的应用问题分析及解决措施 [J ] . 化肥设计 , 2023 , 61 ( 3 ): 35 - 38 .
YANG P J , WANG S Q , BAO S L . Analysis on application problems of de-ester and de-aldehyde process in coal to ethylene glycol plants and the countermeasures [J ] . Chemical Fertilizer Design , 2023 , 61 ( 3 ): 35 - 38 .
WANG X B , ZHANG X X , GUO N , et al . Enhancing effect of Cu and Sn doping on low-temperature catalytic activity and operating temperature window of γ -Fe 2 O 3 in NH 3 -SCR of NO x [J ] . New Journal of Chemistry , 2024 , 48 ( 31 ): 13957 - 13966 .
ZHANG S W , DING J J , SHEN Y L , et al . Investigation of Co-Mn-Ce ternary composite oxide catalyst for low-temperature selective catalytic reduction of NO x with NH 3 [J ] . Topics in Catalysis , 2024 , 67 ( 13 ): 944 - 957 .
ZHANG Y Y , ZENG H , JIA B , et al . Selective catalytic reduction of NO x by H 2 over Pd/TiO 2 catalyst [J ] . Chinese Journal of Catalysis , 2019 , 40 ( 6 ): 849 - 855 .
任丽萍 , 滕加伟 , 李斌 , 等 . CuO/Al 2 O 3 催化剂上CO还原NO反应条件的研究 [J ] . 工业催化 , 2014 , 22 ( 9 ): 725 - 728 .
REN L P , TENG J W , LI B , et al . Research o n reaction condition of catalytic reduction of NO by CO on CuO/Al 2 O 3 catalyst [J ] . Industrial Catalysis , 2014 , 22 ( 9 ): 725 - 728 .
宋庆英 , 滕加伟 . AgCl/H-ZSM-5催化分解NO反应及失活机理 [J ] . 工业催化 , 2003 , ( 1 ): 37 - 39 .
SONG Q Y , TENG J W . Nitrous oxide catalytic decomposition over AgCl/H-ZSM-5 and deactivation mechanism of the catalyst [J ] . Industrial Catalysis , 2003 , ( 1 ): 37 - 39 .
张彦民 , 沈小炎 . 通过稀硝酸补充氮元素在煤制乙二醇生产中的应用 [J ] . 化肥设计 , 2024 , 62 ( 6 ): 17 - 19 .
ZHANG Y M , SHEN X Y . Application of supplementing nitrogen with dilute nitric acid in coal to glycol projects [J ] . Chemical Fertilizer Design , 2024 , 62 ( 6 ): 17 - 19 .
朱涛 . 合成气制乙二醇装置中的硝酸催化还原技术应用和探讨 [J ] . 化肥设计 , 2020 , 58 ( 3 ): 47 - 49 .
ZHU T . Application and discussion of catalytic reduction of nitric acid in syngas-to-ethylene-glycol unit [J ] . Chemical Fertilizer Design , 2020 , 58 ( 3 ): 47 - 49 .
郑敏 , 徐垒 , 陈晨 , 等 . 稀硝酸催化还原工艺中Pd/AC制备条件优化 [J ] . 化工进展 , 2022 , 41 ( 7 ): 3938 - 3946 .
ZHENG M , XU L , CHEN C , et al . Optimization of Pd/AC preparation conditions for catalytic reduction of dilute nitric acid [J ] . Chemical Industry and Engineering Progress , 2022 , 41 ( 7 ): 3938 - 3946 .
苏和平 , 朱云飞 , 王俊晓 . 无催化剂硝酸回收技术在合成气制乙二醇工艺中的应用分析 [J ] . 煤化工 , 2023 , 51 ( 2 ): 12 - 15 .
SU H P , ZHU Y F , WANG J X . Analysis of catalyst-free nitric acid recovery technology used in syngas-to-ethylene glycol process [J ] . Coal Chimical Industry , 2023 , 51 ( 2 ): 12 - 15 .
李文龙 , 宋元江 , 李扬 , 等 . 用于催化稀硝酸还原反应的贵金属催化剂研究 [J ] . 天然气化工—C1化学与化工 , 2019 , 44 ( 5 ): 32 - 36 .
LI W L , SONG Y J , LI Y , et al . Noble metal catalysts for dilute nitric acid reduction [J ] . Natural Gas Chemical Industry , 2019 , 44 ( 5 ): 32 - 36 .
马继平 , 徐杰 , 高进 , 等 . 用于甲醇还原稀硝酸制备亚硝酸甲酯的催化剂及其制备 : 104941619B [P ] . 2017-02-15 .
MA J P , XU J , GAO J , et al . A catalyst for preparing methyl nitrite by methanol reduction of dilute nitric acid and its preparation : 104941619B [P ] . 2017-02-15 .
刘越 , 钱旭芳 . 生物炭改性及其对稀硝酸吸附性能研究 [J/OL ] . 工业水处理 [ 2025-09-14 ] . DOI: 10.19965/j.cnki.iwt.2025-0443 http://dx.doi.org/10.19965/j.cnki.iwt.2025-0443 .
LIU Y , QIAN X F . Study on modification of biochar and its adsorption performance for dilute nitric acid [J/OL ] . Industrial Water Treatment [ 2025-09-14 ] . DOI: 10.19965/j.cnki.iwt.2025-0443 http://dx.doi.org/10.19965/j.cnki.iwt.2025-0443 .
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